Non-analytic microscopic phase transitions and temperature oscillations in the microcanonical ensemble: An exactly solvable 1d-model for evaporation

We calculate exactly both the microcanonical and canonical thermodynamic functions (TDFs) for a one-dimensional model system with piecewise constant Lennard-Jones type pair interactions. In the case of an isolated $N$-particle system, the microcanonical TDFs exhibit (N-1) singular (non-analytic) microscopic phase transitions of the formal order N/2, separating N energetically different evaporation (dissociation) states. In a suitably designed evaporation experiment, these types of phase transitions should manifest themselves in the form of pressure and temperature oscillations, indicating cooling by evaporation. In the presence of a heat bath (thermostat), such oscillations are absent, but the canonical heat capacity shows a characteristic peak, indicating the temperature-induced dissociation of the one-dimensional chain. The distribution of complex zeros (DOZ) of the canonical partition may be used to identify different degrees of dissociation in the canonical ensemble.Comment: version accepted for publication in PRE, minor additions in the text, references adde

Adiabatic Fidelity for Atom-Molecule Conversion in a Nonlinear Three-Level \Lambda-system

We investigate the dynamics of the population transfer for atom-molecule three-level $\Lambda$-system on stimulated Raman adiabatic passage(STIRAP). We find that the adiabatic fidelity for the coherent population trapping(CPT) state or dark state, as the function of the adiabatic parameter, approaches to unit in a power law. The power exponent however is much less than the prediction of linear adiabatic theorem. We further discuss how to achieve higher adiabatic fidelity for the dark state through optimizing the external parameters of STIRAP. Our discussions are helpful to gain higher atom-molecule conversion yield in practical experiments.Comment: 4 pages, 5 figure

Einstein's quantum theory of the monatomic ideal gas: non-statistical arguments for a new statistics

In this article, we analyze the third of three papers, in which Einstein presented his quantum theory of the ideal gas of 1924-1925. Although it failed to attract the attention of Einstein's contemporaries and although also today very few commentators refer to it, we argue for its significance in the context of Einstein's quantum researches. It contains an attempt to extend and exhaust the characterization of the monatomic ideal gas without appealing to combinatorics. Its ambiguities illustrate Einstein's confusion with his initial success in extending Bose's results and in realizing the consequences of what later became to be called Bose-Einstein statistics. We discuss Einstein's motivation for writing a non-combinatorial paper, partly in response to criticism by his friend Ehrenfest, and we paraphrase its content. Its arguments are based on Einstein's belief in the complete analogy between the thermodynamics of light quanta and of material particles and invoke considerations of adiabatic transformations as well as of dimensional analysis. These techniques were well-known to Einstein from earlier work on Wien's displacement law, Planck's radiation theory, and the specific heat of solids. We also investigate the possible role of Ehrenfest in the gestation of the theory.Comment: 57 pp

Microscopic chaos from Brownian motion?

A recent experiment on Brownian motion has been interpreted to exhibit direct evidence for microscopic chaos. In this note we demonstrate that virtually identical results can be obtained numerically using a manifestly microscopically nonchaotic system.Comment: 3 pages, 1 figure, Comment on P. Gaspard et al, Nature vol 394, 865 (1998); rewritten in a more popular styl

Proof of the Ergodic Theorem and the H-Theorem in Quantum Mechanics

It is shown how to resolve the apparent contradiction between the macroscopic approach of phase space and the validity of the uncertainty relations. The main notions of statistical mechanics are re-interpreted in a quantum-mechanical way, the ergodic theorem and the H-theorem are formulated and proven (without "assumptions of disorder"), followed by a discussion of the physical meaning of the mathematical conditions characterizing their domain of validity.Comment: English translation by Roderich Tumulka of J. von Neumann: Beweis des Ergodensatzes und des H-Theorems. 41 pages LaTeX, no figures; v2: typos corrected. See also the accompanying commentary by S. Goldstein, J. L. Lebowitz, R. Tumulka, N. Zanghi, arXiv:1003.212

Charged Particles and the Electro-Magnetic Field in Non-Inertial Frames of Minkowski Spacetime: II. Applications: Rotating Frames, Sagnac Effect, Faraday Rotation, Wrap-up Effect

We apply the theory of non-inertial frames in Minkowski space-time, developed in the previous paper, to various relevant physical systems. We give the 3+1 description without coordinate-singularities of the rotating disk and the Sagnac effect, with added comments on pulsar magnetosphere and on a relativistic extension of the Earth-fixed coordinate system. Then we study properties of Maxwell equations in non-inertial frames like the wrap-up effect and the Faraday rotation in astrophysics.Comment: This paper and the second one are an adaptation of arXiv 0812.3057 for publication on Int.J.Geom. Methods in Modern Phys. 36

Estimating errors reliably in Monte Carlo simulations of the Ehrenfest model

Using the Ehrenfest urn model we illustrate the subtleties of error estimation in Monte Carlo simulations. We discuss how the smooth results of correlated sampling in Markov chains can fool one's perception of the accuracy of the data, and show (via numerical and analytical methods) how to obtain reliable error estimates from correlated samples

Circular Orbits in Einstein-Gauss-Bonnet Gravity

The stability under radial and vertical perturbations of circular orbits associated to particles orbiting a spherically symmetric center of attraction is study in the context of the n-dimensional: Newtonian theory of gravitation, Einstein's general relativity, and Einstein-Gauss-Bonnet theory of gravitation. The presence of a cosmological constant is also considered. We find that this constant as well as the Gauss-Bonnet coupling constant are crucial to have stability for $n>4$.Comment: 11 pages, 4 figs, RevTex, Phys. Rev. D, in pres

Analysis of return distributions in the coherent noise model

The return distributions of the coherent noise model are studied for the system size independent case. It is shown that, in this case, these distributions are in the shape of q-Gaussians, which are the standard distributions obtained in nonextensive statistical mechanics. Moreover, an exact relation connecting the exponent $\tau$ of avalanche size distribution and the q value of appropriate q-Gaussian has been obtained as q=(tau+2)/tau. Making use of this relation one can easily determine the q parameter values of the appropriate q-Gaussians a priori from one of the well-known exponents of the system. Since the coherent noise model has the advantage of producing different tau values by varying a model parameter \sigma, clear numerical evidences on the validity of the proposed relation have been achieved for different cases. Finally, the effect of the system size has also been analysed and an analytical expression has been proposed, which is corroborated by the numerical results.Comment: 14 pages, 3 fig

Classical invariants and the quantization of chaotic systems

Long periodic orbits constitute a serious drawback in Gutzwiller's theory of chaotic systems, and then it would be desirable that other classical invariants, not suffering from the same problem, could be used in the quantization of such systems. In this respect, we demonstrate how a suitable dynamical analysis of chaotic quantum spectra unveils the fundamental role played by classical invariant areas related to the stable and unstable manifolds of short periodic orbits.Comment: 4 pages, 3 postscript figure