Spin-orbit coupling and broken spin degeneracy in multilayer graphene

Since the lattices of ABA-stacked graphene multilayers with an even number of layers, as well as that of monolayer graphene, satisfy spatial-inversion symmetry, their electronic bands must be spin degenerate in the presence of time-inversion symmetry. In intrinsic monolayer and bilayer graphene, when symmetry is not broken by external fields, the only spin-orbit coupling present at low energy near the corner of the Brillouin zone is the Kane-Mele term, that opens a bulk energy gap but does not break the spin degeneracy of the energy bands [C. L. Kane and E. J. Mele, Phys. Rev. Lett. 95, 226801 (2005)]. However, spin splitting is allowed in multilayers with an odd number of layers (greater than or equal to 3) because their lattices do not satisfy spatial inversion symmetry. We show that, in trilayer graphene, in addition to the Kane-Mele term, there is a second type of intrinsic spin-orbit coupling present at low energy near the corner of the Brillouin zone. It introduces a Zeeman-like spin splitting of the energy bands at each valley, with an opposite sign of the effective magnetic field in the two valleys. We estimate the magnitude of the effective field to be ~2T.Comment: 4 pages, 1 figur

Landau level spectra and the quantum Hall effect of multilayer graphene

The Landau level spectra and the quantum Hall effect of ABA-stacked multilayer graphenes are studied in the effective mass approximation. The low-energy effective mass Hamiltonian may be partially diagonalized into an approximate block-diagonal form, with each diagonal block contributing parabolic bands except, in a multilayer with an odd number of layers, for an additional block describing Dirac-like bands with a linear dispersion. We fully include the band parameters and, taking into account the symmetry of the lattice, we analyze their affect on the block-diagonal Hamiltonian. Next-nearest layer couplings are shown to be particularly important in determining the low-energy spectrum and the phase diagram of the quantum Hall conductivity, by causing energy shifts, level anti-crossings, and valley splitting of the low-lying Landau levels.Comment: 9 pages, 4 figure

Magnetothermopower and magnon-assisted transport in ferromagnetic tunnel junctions

We present a model of the thermopower in a mesoscopic tunnel junction between two ferromagnetic metals based upon magnon-assisted tunneling processes. In our model, the thermopower is generated in the course of thermal equilibration between two baths of magnons, mediated by electrons. We predict a particularly large thermopower effect in the case of a junction between two half-metallic ferromagnets with antiparallel polarizations, $S_{AP} \sim - (k_B/e)$, in contrast to $S_{P} \approx 0$ for a parallel configuration.Comment: 3 pages, 1 eps figur

Asymmetry gap in the electronic band structure of bilayer graphene.

A tight binding model is used to calculate the band structure of bilayer graphene in the presence of a potential difference between the layers that opens a gap U between the conduction and valence bands. In particular, a self consistent Hartree approximation is used to describe imperfect screening of an external gate, employed primarily to control the density n of electrons on the bilayer, resulting in a potential difference between the layers and a density dependent gap U(n). We discuss the influence of a finite asymmetry gap U(0) at zero excess density, caused by the screening of an additional transverse electric field, on observations of the quantum Hall effect

Degeneracy breaking and intervalley scattering due to short-ranged impurities in finite single-wall carbon nanotubes

We present a theoretical study of degeneracy breaking due to short-ranged impurities in finite, single-wall, metallic carbon nanotubes. The effective mass model is used to describe the slowly varying spatial envelope wavefunctions of spinless electrons near the Fermi level at two inequivalent valleys (K-points) in terms of the four component Dirac equation for massless fermions, with the role of spin assumed by pseudospin due to the relative amplitude of the wave function on the sublattice atoms (``A'' and ``B''). Using boundary conditions at the ends of the tube that neither break valley degeneracy nor mix pseudospin eigenvectors, we use degenerate perturbation theory to show that the presence of impurities has two effects. Firstly, the position of the impurity with respect to the spatial variation of the envelope standing waves results in a sinusoidal oscillation of energy level shift as a function of energy. Secondly, the position of the impurity within the hexagonal graphite unit cell produces a particular 4 by 4 matrix structure of the corresponding effective Hamiltonian. The symmetry of this Hamiltonian with respect to pseudospin flip is related to degeneracy breaking and, for an armchair tube, the symmetry with respect to mirror reflection in the nanotube axis is related to pseudospin mixing.Comment: 20 pages, 10 eps figure

Parity and valley degeneracy in multilayer graphene

We study spatial symmetry in general ABA-stacked multilayer graphene to illustrate how electronic spectra at the two valleys are related in a magnetic field. We show that the lattice of multilayers with an even number of layers, as well as that of monolayer graphene, satisfy spatial inversion symmetry, which rigorously guarantees valley degeneracy in the absence of time-reversal symmetry. A multilayer with an odd number of layers (three or more) lacks inversion symmetry, but there is another transformation imposing an approximate valley degeneracy, which arises because the low-energy Hamiltonian consists of separate monolayerlike and bilayerlike parts. We show that an external electrostatic potential generally breaks valley degeneracy in a magnetic field, in a markedly different manner in odd and even multilayers.Comment: 6 pages, 3 figure

Catalog of noninteracting tight-binding models with two energy bands in one dimension

We classify Hermitian tight-binding models describing noninteracting electrons on a one-dimensional periodic lattice with two energy bands. To do this, we write a generalized Rice-Mele model with two orbitals per unit cell, including all possible complex-valued long-range hoppings consistent with Hermicity. We then apply different forms of time-reversal, charge-conjugation and chiral symmetry in order to constrain the parameters, resulting in an array of possible models in different symmetry classes. For each symmetry class, we define a single, canonical form of the Hamiltonian and identify models that are related to the canonical form by an off-diagonal unitary transformation in the atomic basis. The models have either symmorphic or nonsymmorphic nonspatial symmetries (time $T$, chiral and charge-conjugation). The nonsymmorphic category separates into two types of state of matter: an insulator with a $\mathbb{Z}_2$ topological index in the absence of nonsymmorphic time-reversal symmetry or, in the presence of nonsymmorphic time-reversal symmetry, a metallic state. The latter is an instance of Kramer's degeneracy with one degeneracy point in the Brillouin zone as opposed to no degeneracy points in symmorphic systems with $T^2 = 1$ and two in symmorphic systems with $T^2 = - 1$.Comment: 27 pages, 12 figure

Gate-induced interlayer asymmetry in ABA-stacked trilayer graphene

We calculate the electronic band structure of ABA-stacked trilayer graphene in the presence of external gates, using a self-consistent Hartree approximation to take account of screening. In the absence of a gate potential, there are separate pairs of linear and parabolic bands at low energy. A gate field perpendicular to the layers breaks mirror reflection symmetry with respect to the central layer and hybridizes the linear and parabolic low-energy bands, leaving a chiral Hamiltonian essentially different from that of monolayer or bilayer graphene. Using the self-consistent Born approximation, we find that the density of states and the minimal conductivity in the presence of disorder generally increase as the gate field increases, in sharp contrast with bilayer graphene.Comment: 5 pages, 3 figure

Trigonal warping and Berry’s phase Npi in ABC-stacked multilayer graphene.

The electronic band structure of ABC-stacked multilayer graphene is studied within an effective mass approximation. The electron and hole bands touching at zero energy support chiral quasiparticles characterized by Berry’s phase Nπ for N-layers, generalizing the low-energy band structure of monolayer and bilayer graphene. We investigate the trigonal-warping deformation of the energy bands and show that the Lifshitz transition, in which the Fermi circle breaks up into separate parts at low energy, reflects Berry’s phase Nπ. It is particularly prominent in trilayers, N = 3, with the Fermi circle breaking into three parts at a relatively large energy that is related to next-nearestlayer coupling. For N = 3, we study the effects of electrostatic potentials which vary in the stacking direction, and find that a perpendicular electric field, as well as opening an energy gap, strongly enhances the trigonal-warping effect. In magnetic fields, the N = 3 Lifshitz transition is manifested as a coalescence of Landau levels into triply-degenerate levels