1,904 research outputs found
Lamp reliability studies for improved satellite rubidium frequency standard
In response to the premature failure of Rb lamps used in Rb atomic clocks onboard NAVSTAR GPS satellites experimental and theoretical investigations into their failure mechanism were initiated. The primary goal of these studies is the development of an accelerated life test for future GPS lamps. The primary failure mechanism was identified as consumption of the lamp's Rb charge via direct interaction between Rb and the lamp's glass surface. The most effective parameters to accelerate the interaction between the Rb and the glass are felt to be RF excitation power and lamp temperature. Differential scanning calorimetry is used to monitor the consumption of Rb within a lamp as a function of operation time. This technique yielded base line Rb consumption data for GPS lamps operating under normal conditions
Critical properties of the double exchange ferromagnet Nd0.4Pb0.4MnO3
Results of a study of dc-magnetization M(T, H), performed on a Nd0.6Pb0.4MnO3
single crystal in the temperature range around T_C (Curie temperature) which
embraces the critical region | epsilon | = |T -T_C |/T_C <= 0.05 are reported.
The magnetic data analyzed in the critical region using the Kouvel-Fisher
method give the values for the T_C =156.47 +/- 0.06 K and the critical
exponents, beta = 0.374 +/- 0.006 (from the temperature dependence of
magnetization), and gamma = 1.329 +/- 0.003 (from the temperature dependence of
initial susceptibility). The critical isotherm M(T_C, H) gives delta = 4.547
+/- 0.1. Thus the scaling law gamma+beta=delta beta is fulfilled. The critical
exponents obey the single scaling-equation of state M(H, epsilon) = epsilon^b
f_+/- (H/epsilon^(beta + gamma)) where, f_+ for T > T_C and f_- for T< T_C. The
exponent values are very close to those expected for the universality class of
3D Heisenberg ferromagnets with short-range interactions.Comment: 19 pages, including 6 figure
Origin of non-exponential relaxation in a crystalline ionic conductor: a multi-dimensional 109Ag NMR study
The origin of the non-exponential relaxation of silver ions in the
crystalline ion conductor Ag7P3S11 is analyzed by comparing appropriate
two-time and three-time 109Ag NMR correlation functions. The non-exponentiality
is due to a rate distribution, i.e., dynamic heterogeneities, rather than to an
intrinsic non-exponentiality. Thus, the data give no evidence for the relevance
of correlated back-and-forth jumps on the timescale of the silver relaxation.Comment: 4 pages, 3 figure
Dynamics in Colloidal Liquids near a Crossing of Glass- and Gel-Transition Lines
Within the mode-coupling theory for ideal glass-transitions, the mean-squared
displacement and the correlation function for density fluctuations are
evaluated for a colloidal liquid of particles interacting with a square-well
potential for states near the crossing of the line for transitions to a gel
with the line for transitions to a glass. It is demonstrated how the dynamics
is ruled by the interplay of the mechanisms of arrest due to hard-core
repulsion and due to attraction-induced bond formation as well as by a nearby
higher-order glass-transition singularity. Application of the universal
relaxation laws for the slow dynamics near glass-transition singularities
explains the qualitative features of the calculated time dependence of the
mean-squared displacement, which are in accord with the findings obtained in
molecular-dynamics simulation studies by Zaccarelli et. al [Phys. Rev. E 66,
041402 (2002)]. Correlation functions found by photon-correlation spectroscopy
in a micellar system by Mallamace et. al [Phys. Rev. Lett. 84, 5431 2000)] can
be interpreted qualitatively as a crossover from gel to glass dynamics.Comment: 13 pages, 12 figure
Research Proposal for an Experiment to Search for the Decay {\mu} -> eee
We propose an experiment (Mu3e) to search for the lepton flavour violating
decay mu+ -> e+e-e+. We aim for an ultimate sensitivity of one in 10^16
mu-decays, four orders of magnitude better than previous searches. This
sensitivity is made possible by exploiting modern silicon pixel detectors
providing high spatial resolution and hodoscopes using scintillating fibres and
tiles providing precise timing information at high particle rates.Comment: Research proposal submitted to the Paul Scherrer Institute Research
Committee for Particle Physics at the Ring Cyclotron, 104 page
Theoretical Studies of the Solvent Effect on the Stability of the Ascorbic Acid Tautomers
AMI calculations on three conformers of each of the four tautomeric forms of ascorbic acid are reported. According to the results for isolated molecules, tautomer 3 should be lowest in energy, whereas experimentally only tautomer 1 is observed in the crystal as well as in solution. Solvent effects on the relative stability of the various structures are assessed by applying a combined quantum chemical and force field approach. It turned out to be very important to fully optimize both the water environment and the solute, which was achieved iteratively by means of a suitably modified AMI Hamiltonian taking into account the charge polarization due to the solvent. Inclusion of the solvent effects reduces appreciably the energy difference between tautomers 1 and 3, but does not change their energetic ordering. Cl calculations indicate that the AMI method tends to underestimate the bond delocalization effects in the enone substructure of 1 so that correlation effects are important to describe the relative stability of 1 and 3
Ti-Al composite wires with high specific strength
An alternative deformation technique was applied to a composite made of titanium and an aluminium alloy in order to achieve severe plastic deformation. This involves accumulative swaging and bundling. Furthermore, it allows uniform deformation of a composite material while producing a wire which can be further used easily. Detailed analysis concerning the control of the deformation process, mesostructural and microstructural features and tensile testing was carried out on the as produced wires. A strong grain refinement to a grain size of 250–500 nm accompanied by a decrease in h111i fibre texture component and a change from low angle to high angle grain boundary characteristics is observed in the Al alloy. A strong increase in the mechanical properties in terms of ultimate tensile strength ranging from 600 to 930 MPa being equivalent to a specific strength of up to 223 MPa/g/cm3 was achieved
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