Temperature-dependent photoemission spectral weight transfer and chemical potential shift in Pr1−x_{1-x}Cax_xMnO3_3 : Implications for charge density modulation

We have studied the temperature dependence of the photoemission spectra of Pr$_{1-x}$Ca$_x$MnO$_3$ (PCMO) with $x=0.25$, 0.3 and 0.5. For $x=0.3$ and 0.5, we observed a gap in the low-temperature CE-type charge-ordered (CO) phase and a pseudogap with a finite intensity at the Fermi level ($E_F$) in the high-temperature paramagnetic insulating (PI) phase. Within the CO phase, the spectral intensity near $E_F$ gradually increased with temperature. These observations are consistent with the results of Monte Carlo simulations on a model including charge ordering and ferromagnetic fluctuations [H. Aliaga {\it et al.} Phys. Rev. B {\bf 68}, 104405 (2003)]. For $x=0.25$, on the other hand, little temperature dependence was observed within the low-temperature ferromagnetic insulating (FI) phase and the intensity at $E_F$ remained low in the high-temperature PI phase. We attribute the difference in the temperature dependence near $E_F$ between the CO and FI phases to the different correlation lengths of orbital order between both phases. Furthermore, we observed a chemical potential shift with temperature due to the opening of the gap in the FI and CO phases. The doping dependent chemical potential shift was recovered at low temperatures, corresponding to the disappearance of the doping dependent change of the modulation wave vector. Spectral weight transfer with hole concentration was clearly observed at high temperatures but was suppressed at low temperatures. We attribute this observation to the fixed periodicity with hole doping in PCMO at low temperatures.Comment: 5pages, 7figure

Military Children’s Difficulty with Reintegration after Deployment: A Relational Turbulence Model Perspective

This study drew on the relational turbulence model to investigate how the interpersonal dynamics of military couples predict parents’ reports of the reintegration difficulty of military children upon homecoming after deployment. Longitudinal data were collected from 118 military couples once per month for 3 consecutive months after reunion. Military couples reported on their depressive symptoms, characteristics of their romantic relationship, and the reintegration difficulty of their oldest child. Results of dyadic growth curve models indicated that the mean levels of parents’ depressive symptoms (H1), relationship uncertainty (H2), and interference from a partner (H3) were positively associated with parents’ reports of military children’s reintegration difficulty. These findings suggest that the relational turbulence model has utility for illuminating the reintegration difficulty of military children during the postdeployment transition

Chemical potential shift induced by double-exchange and polaronic effects in Nd_{1-x}Sr_xMnO_3

We have studied the chemical potential shift as a function of temperature in Nd$_{1-x}$Sr$_x$MnO$_3$ (NSMO) by measurements of core-level photoemission spectra. For ferromagnetic samples ($x=0.4$ and 0.45), we observed an unusually large upward chemical potential shift with decreasing temperature in the low-temperature region of the ferromagnetic metallic (FM) phase. This can be explained by the double-exchange (DE) mechanism if the $e_g$ band is split by dynamical/local Jahn-Teller effect. The shift was suppressed near the Curie temperature ($T_C$), which we attribute to the crossover from the DE to lattice-polaron regimes.Comment: 5 pages, 6 figure

Chemical potential shift and spectral weight transfer in Pr1−x_{1-x}Cax_xMnO3_3 revealed by photoemission spectroscopy

We have studied the chemical potential shift and changes in the electronic density of states near the Fermi level ($E_F$) as a function of carrier concentration in Pr$_{1-x}$Ca$_x$MnO$_3$ (PCMO, $0.2 \le x \le 0.65$) through the measurements of photoemission spectra. The results showed that the chemical potential shift was suppressed for x \agt 0.3, where the charge exchange (CE)-type antiferromagnetic charge-ordered state appears at low temperatures. We consider this observation to be related to charge self-organization such as stripe formation on a microscopic scale in this composition range. Together with the previous observation of monotonous chemical potential shift in La$_{1-x}$Sr$_x$MnO$_3$, we conclude that the tendency toward the charge self-organization increases with decreasing bandwidth. In the valence band, spectral weight of the Mn 3$d$ $e_g$ electrons in PCMO was transferred from $\sim$ 1 eV below $E_F$ to the region near $E_F$ with hole doping, leading to a finite intensity at $E_F$ even in the paramagnetic insulating phase for x \agt 0.3, probably related with the tendency toward charge self-organization. The finite intensity at $E_F$ in spite of the insulating transport behavior is consistent with fluctuations involving ferromagnetic metallic states.Comment: 6 pages, 5 figure

Depth profile photoemission study of thermally diffused Mn/GaAs (001) interfaces

We have performed a depth profile study of thermally diffused Mn/GaAs (001) interfaces using photoemission spectroscopy combined with Ar$^+$-ion sputtering. We found that Mn ion was thermally diffused into the deep region of the GaAs substrate and completely reacted with GaAs. In the deep region, the Mn 2$p$ core-level and Mn 3$d$ valence-band spectra of the Mn/GaAs (001) sample heated to 600 $^{\circ}$C were similar to those of Ga$_{1-x}$Mn$_x$As, zinc-blende-type MnAs dots, and/or interstitial Mn in tetrahedrally coordinated by As atoms, suggesting that the Mn 3$d$ states were essentially localized but were hybridized with the electronic states of the host GaAs. Ferromagnetism was observed in the dilute Mn phase.Comment: 5 pages, 4 figure

Chemical potential landscape in band filling and bandwidth-control of manganites: Photoemission spectroscopy measurements

We have studied the effects of band filling and bandwidth control on the chemical potential in perovskite manganites $R_{1-x}A_x$MnO$_3$ ($R$ : rare earth, $A$ : alkaline earth) by measurements of core-level photoemission spectra. A suppression of the doping-dependent chemical potential shift was observed in and around the CE-type charge-ordered composition range, indicating that there is charge self-organization such as stripe formation or its fluctuations. As a function of bandwidth, we observed a downward chemical potential shift with increasing bandwidth due to the reduction of the orthorhombic distortion. After subtracting the latter contribution, we found an upward chemical potential shift in the ferromagnetic metallic region $0.3<x<0.5$, which we attribute to the enhancement of double-exchange interaction involving the Jahn-Teller-split $e_g$ band.Comment: 5 pages, 4 figure

S1 excited-state dynamics of OMpCA and its hydrogen-bonded complexes

第30回化学反応討論会, 2014年6月4日-6日, イーグレひめじ(姫路

Cold SO_2 molecules by Stark deceleration

We produce SO_2 molecules with a centre of mass velocity near zero using a Stark decelerator. Since the initial kinetic energy of the supersonic SO_2 molecular beam is high, and the removed kinetic energy per stage is small, 326 deceleration stages are necessary to bring SO_2 to a complete standstill, significantly more than in other experiments. We show that in such a decelerator possible loss due to coupling between the motional degrees of freedom must be considered. Experimental results are compared with 3D Monte-Carlo simulations and the quantum state selectivity of the Stark decelerator is demonstrated.Comment: 7 pages, 5 figure

Folding catastrophes due to viscosity in multiferroic domains : implications for room-temperature multiferroic switching

Unusual domains with curved walls and failure to satisfy the Landau–Lifshitz-Kittel Law are modeled as folding catastrophes (saddle-node bifurcations). This description of ballistic motion in a viscous medium is based upon early work by Dawber et al 2003 Appl. Phys. Lett . 82 436. It suggests that ferroelectric films can exhibit folds or vortex patterns but not both.Publisher PDFPeer reviewe

Conformation of Alkali Metal Ion−Benzo-12-Crown‑4 Complexes Investigated by UV Photodissociation and UV−UV Hole-Burning Spectroscopy

We measure UV photodissociation (UVPD) spectra of benzo-12-crown-4 (B12C4) complexes with alkali metal ions, M+·B12C4 (M = Li, Na, K, Rb, and Cs), in the 36300−37600 cm−1 region. Thanks to the cooling of ions to ∼10 K, all the M+·B12C4 complexes show sharp vibronic bands in this region. For UV−UV hole-burning (HB) spectroscopy, we first check if our experimental system works well by observing UV−UV HB spectra of the K+ complex with benzo-18-crown-6 (B18C6), K+·B18C6. In the UV−UV HB spectra of the K+·B18C6 complex, gain signals are also observed; these are due to vibrationally hot K+·B18C6 complex produced by the UV excitation of cold K+·B18C6 complex. Then we apply UV−UV HB spectroscopy to the M+·B12C4 complexes, and only one conformer is found for each complex except for the Li+ complex, which has two conformers. The vibronic structure around the origin band of the UVPD spectra is quite similar for all the complexes, indicating close resemblance of the complex structure. The most stable structures calculated for the M+·B12C4 (M = Li, Na, K, Rb, and Cs) complexes also have a similar conformation among them, which coincides with the UVPD results. In these conformers the metal ions are too big to be included in the B12C4 cavity, even for the Li+ ion. In solution, it was reported that 12-crown-4 (12C4) shows the preference of Na+ ion among alkali metal ions. From the similarity of the structure for the M+·B12C4 complexes, it is suggested that the solvation of free metal ions, not of the M+·12C4 complexes, may lead to the selectivity of Na+ ion for 12C4 in solution.This work was partly supported by JSPS KAKENHI Grant Number 16H04098