51 research outputs found
Estudio de reacciones de esterificación usando como catalizadores materiales híbridos orgánico-inorgánicos funcionalizados con grupos ácido sulfónico
Magnetic Field Measurement with Ground State Alignment
Observational studies of magnetic fields are crucial. We introduce a process
"ground state alignment" as a new way to determine the magnetic field direction
in diffuse medium. The alignment is due to anisotropic radiation impinging on
the atom/ion. The consequence of the process is the polarization of spectral
lines resulting from scattering and absorption from aligned atomic/ionic
species with fine or hyperfine structure. The magnetic field induces precession
and realign the atom/ion and therefore the polarization of the emitted or
absorbed radiation reflects the direction of the magnetic field. The atoms get
aligned at their low levels and, as the life-time of the atoms/ions we deal
with is long, the alignment induced by anisotropic radiation is susceptible to
extremely weak magnetic fields (G). In fact,
the effects of atomic/ionic alignment were studied in the laboratory decades
ago, mostly in relation to the maser research. Recently, the atomic effect has
been already detected in observations from circumstellar medium and this is a
harbinger of future extensive magnetic field studies. A unique feature of the
atomic realignment is that they can reveal the 3D orientation of magnetic
field. In this article, we shall review the basic physical processes involved
in atomic realignment. We shall also discuss its applications to
interplanetary, circumstellar and interstellar magnetic fields. In addition,
our research reveals that the polarization of the radiation arising from the
transitions between fine and hyperfine states of the ground level can provide a
unique diagnostics of magnetic fields in the Epoch of Reionization.Comment: 30 pages, 12 figures, chapter in Lecture Notes in Physics "Magnetic
Fields in Diffuse Media". arXiv admin note: substantial text overlap with
arXiv:1203.557
Black hole thermodynamical entropy
As early as 1902, Gibbs pointed out that systems whose partition function
diverges, e.g. gravitation, lie outside the validity of the Boltzmann-Gibbs
(BG) theory. Consistently, since the pioneering Bekenstein-Hawking results,
physically meaningful evidence (e.g., the holographic principle) has
accumulated that the BG entropy of a black hole is
proportional to its area ( being a characteristic linear length), and
not to its volume . Similarly it exists the \emph{area law}, so named
because, for a wide class of strongly quantum-entangled -dimensional
systems, is proportional to if , and to if
, instead of being proportional to (). These results
violate the extensivity of the thermodynamical entropy of a -dimensional
system. This thermodynamical inconsistency disappears if we realize that the
thermodynamical entropy of such nonstandard systems is \emph{not} to be
identified with the BG {\it additive} entropy but with appropriately
generalized {\it nonadditive} entropies. Indeed, the celebrated usefulness of
the BG entropy is founded on hypothesis such as relatively weak probabilistic
correlations (and their connections to ergodicity, which by no means can be
assumed as a general rule of nature). Here we introduce a generalized entropy
which, for the Schwarzschild black hole and the area law, can solve the
thermodynamic puzzle.Comment: 7 pages, 2 figures. Accepted for publication in EPJ
A probabilistic compressive sensing framework with applications to ultrasound signal processing
The field of Compressive Sensing (CS) has provided algorithms to reconstruct signals from a much lower number of measurements than specified by the Nyquist-Shannon theorem. There are two fundamental concepts underpinning the field of CS. The first is the use of random transformations to project high-dimensional measurements onto a much lower-dimensional domain. The second is the use of sparse regression to reconstruct the original signal. This assumes that a sparse representation exists for this signal in some known domain, manifested by a dictionary. The original formulation for CS specifies the use of an penalised regression method, the Lasso. Whilst this has worked well in literature, it suffers from two main drawbacks. First, the level of sparsity must be specified by the user, or tuned using sub-optimal approaches. Secondly, and most importantly, the Lasso is not probabilistic; it cannot quantify uncertainty in the signal reconstruction. This paper aims to address these two issues; it presents a framework for performing compressive sensing based on sparse Bayesian learning. Specifically, the proposed framework introduces the use of the Relevance Vector Machine (RVM), an established sparse kernel regression method, as the signal reconstruction step within the standard CS methodology. This framework is developed within the context of ultrasound signal processing in mind, and so examples and results of compression and reconstruction of ultrasound pulses are presented. The dictionary learning strategy is key to the successful application of any CS framework and even more so in the probabilistic setting used here. Therefore, a detailed discussion of this step is also included in the paper. The key contributions of this paper are a framework for a Bayesian approach to compressive sensing which is computationally efficient, alongside a discussion of uncertainty quantification in CS and different strategies for dictionary learning. The methods are demonstrated on an example dataset from collected from an aerospace composite panel. Being able to quantify uncertainty on signal reconstruction reveals that this grows as the level of compression increases. This is key when deciding appropriate compression levels, or whether to trust a reconstructed signal in applications of engineering and scientific interest
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