Kinetic energy release in electron-induced decay reactions of molecular ions: C3H8+ and C3H7+

We have measured the kinetic energy release (KER) distributions for electron-induced dissociation of mass-selected molecular parent and fragment ions of propane. They are compared with distributions determined for spontaneous (metastable) dissociation. The average KER for induced dissociation of C3H8+ into C3H7+ is 13.2 +/- 1.2 meV, about 42% larger than for the spontaneous reaction. This large difference is attributed to the dramatically reduced time at which the induced reaction can be sampled. In contrast, the KER for dissociation of C3H7+ into C3H5+, which is characterized by a large reverse activation energy, is hardly affected by the experimental time scale. (C) 2000 American Institute of Physics. [S0021-9606(00)00826-6]

High-resolution kinetic energy release distributions and dissociation energies for fullerene ions C(n)(+), 42 \u3c= n \u3c= 90

We have measured the kinetic energy released in the unimolecular dissociation of fullerene ions, C(n)(+)--\u3eC(n-2)(+)+C(2), for sizes 42less than or equal tonless than or equal to90. A three-sector-field mass spectrometer equipped with two electric sectors has been used in order to ensure that contributions from isotopomers of different masses do not distort the experimental kinetic energy release distributions. We apply the concept of microcanonical temperature to derive from these data the dissociation energies of fullerene cations. They are converted to dissociation energies of neutral fullerenes with help of published adiabatic ionization energies. The results are compared with literature values. (C) 2004 American Institute of Physics

Exercise Prescribing: Computer Application in Older Adults

Purpose: The purpose of this study was to determine if older adults are capable and willing to interact with a computerized exercise promotion interface and to determine to what extent they accept computer-generated exercise recommendations. Design and Methods: Time and requests for assistance were recorded while 34 college-educated volunteers, equal numbers of men and women, ranging in age from 60 to 87, interfaced with a health promotion tool. The computerized exercise promotion tool's ease of use and the acceptability of the exercise recommendations made were rated by the participants. Results:On average, completion of the items on the computer took 33 min and each participant made 3 requests for assistance, of which only 22% were mouse related. The system's ease of use and the exercise prescription acceptability ratings were high and independent of prior experience with computers. Implications: User friendliness of computerized health promotion tools will determine if, and how, health providers integrate these new technologies into daily practice. The participants in the study were able to complete the computerized items within a reasonable amount of time and with minimal assistance from the provider. These data support the potential of interactive technology in health promotion among the expanding older populatio

High resolution measurements of kinetic energy release distributions of neon, argon, and krypton cluster ions using a three sector field mass spectrometer

Using a newly constructed three sector field mass spectrometer (resulting in a BE1E2 field configuration) we have measured the kinetic energy release distributions of neon, argon, and krypton cluster ions. In the present study we used the first two sectors, B and E1, constituting a high resolution mass spectrometer, to select the parent ions in terms of mass, charge, and energy, and studied the decay of those ions in the third field free region. Due to the improved mass resolution we were able to extend earlier studies carried out with a two sector field machine, where an upper size limit arose from the fact that several isotopomers contribute to a decaying parent ion beam when the cluster size exceeds a certain value. Furthermore we developed a new data analysis. It allows us to model also fragment ion peaks that are a superposition of different decay reactions and thus we can determine the average kinetic energy release for all decay reactions of a given cluster ion. In a further step we used these results to determine the binding energies of cluster ions Rg(n) (ngreater than or equal to10) by applying finite heat bath theory. The smaller sizes have not been included in this analysis, because the validity of finite heat bath theory becomes questionable below napproximate to10. The present average kinetic energy releases and binding energies are compared with other experiments and various calculations. (C) 2004 American Institute of Physics

Mechanisms and dynamics of the metastable decay in Ar-2(+)

A detailed experimental as well as theoretical investigation of the properties of the metastable dissociation Ar-2(+)--\u3eAr++Ar is presented. The mass-analyzed ion kinetic energy (MIKE) scan technique has been performed using a three sector field mass spectrometer. The possible mechanisms of the metastability of Ar-2(+) have been examined and the observed decay process is assigned to the II(1/2)(u)--\u3eI(1/2)(g) bound to continuum radiative transition, in agreement with earlier work. The calculation of the theoretical shape of the kinetic energy release distribution of fragment ions allowed us to construct the theoretical MIKE peak and compare it with the raw experimental data. The accuracy of various sets of potential energy curves for Ar-2(+) is discussed, as well as the way of production of the metastable Ar-2(+)[II(1/2)(u)] electronic state by electron impact. Excellent agreement between the experimental data and theoretical model has been observed. (C) 2004 American Institute of Physics

Kinetic-energy release in Coulomb explosion of metastable C3H52+

C3H52+, formed by electron impact ionization of propane, undergoes metastable decay into C2H2++CH3+. We have monitored this reaction in a magnetic mass spectrometer of reversed geometry that is equipped with two electric sectors (BEE geometry). Three different techniques were applied to identify the fragment ions and determine the kinetic-energy release (KER) of spontaneous Coulomb explosion of C3H52+ in the second and third field free regions of the mass spectrometer. The KER distribution is very narrow, with a width of about 3% [root-mean square standard deviation]. An average KER of 4.58+/-0.15 eV is derived from the distribution. High level ab initio quantum-chemical calculations of the structure and energetics of C3H52+ are reported. The activation barrier of the reverse reaction, CH3++C2H2+ (vinylidene), is computed. The value closely agrees with the experimental average KER, thus indicating that essentially all energy available in the reaction is partitioned into kinetic energy. (C) 2003 American Institute of Physics

¿Están los programas sociales en condiciones de ser evaluados? : la aplicación de un protocolo de evaluabilidad a una muestra de programas sociales implementados en Argentina

Fil: Aquilino, Natalia. Centro de Implementación de Políticas Públicas para la Equidad y el CrecimientoFil: Echt, Leandro. Centro de Implementación de Políticas Públicas para la Equidad y el CrecimientoFil: Estévez, Sofía. Centro de Implementación de Políticas Públicas para la Equidad y el CrecimientoFil: Arias, Eva. Centro de Implementación de Políticas Públicas para la Equidad y el Crecimient

Adsorption of Sodium and Cesium on Aggregates of C60

We explore the formation of C60 sodium and C60 cesium complexes in superfluid helium nanodroplets. Anomalies in mass spectra of these doped droplets reveal anomalies in the stability of ions. (C60) m Cs+ n ions ( m ≤ 6) are particularly abundant if they contain n = 6m + 1 cesium atoms; (C60) m Cs2+ n dications ( m ≤ 3 or 5) are abundant if n = 6m + 2. These findings are consistent with the notion that alkali metal atoms (A) transfer their valence electrons into the three-fold degenerate lowest unoccupied orbital of C60, resulting in particularly stable C60A6 building blocks. However, (C60) 4CsCs2+ n dications display an entirely different pattern; instead of an expected anomaly at n = 6 × 4 + 2 = 26 we observe a strong odd-even alternation starting at n = 6. Also surprising is the effect of adding one H2O or CO2 molecule to (C60) m Cs n mono- or dications; anomalies shift by two units as if the impurity were acting as an acceptor for two valence electrons from the alkali metal atoms

Doubly Charged CO2 Clusters Formed by Ionization of Doped Helium Nanodroplets

Helium nanodroplets are doped with carbon dioxide and ionized by electrons. Doubly charged cluster ions are, for the first time, identified based on their characteristic patterns of isotopologues. Thanks to the high mass resolution, large dynamic range, and a novel method to eliminate contributions from singly charged ions from the mass spectra, we are able to observe doubly charged cluster ions that are smaller than the ones reported in the past. The likely mechanism by which doubly charged ions are formed in doped helium droplets is discussed