Dynamical model of the dielectric screening of conjugated polymers

A dynamical model of the dielectric screening of conjugated polymers is introduced and solved using the density matrix renormalization group method. The model consists of a line of quantized dipoles interacting with a polymer chain. The polymer is modelled by the Pariser-Parr-Pople (P-P-P) model. It is found that: (1) Compared to isolated, unscreened single chains, the screened 1Bu- exciton binding energy is typically reduced by ca. 1 eV to just over 1 eV; (2) Covalent (magnon and bi-magnon) states are very weakly screened compared to ionic (exciton) states; (3) Screening of the 1Bu- exciton is closer to the dispersion than solvation limit.Comment: 12 pages, 2 figure

Microbial use of recycled urea is dependent on the level and frequency of degradable intake protein supplementation

Protein supplementation increases utilization (intake and digestion) of low-quality forage and ultimately animal performance. Despite its effectiveness, protein supplementation is often expensive. One strategy to reduce the cost of supplementation is to supplement less frequently than daily, generally every other day or every third day. By reducing the frequency of supplementation, the cost of delivering the supplement is reduced. Reducing the frequency of supplementation is an effective strategy for reducing cost, and it only minimally impacts animal performance, with less frequent supplementation resulting in slightly greater losses of body condition score and body weight during the winter supplementation period. Urea recycling, the transfer of urea from the animal’s body to the gastrointestinal tract, has been suggested as a mechanism that allows infrequently supplemented cattle to perform similarly to cattle supplemented daily. However, little data is available to substantiate this claim, and such data would be useful in helping nutritionists better understand nitrogen metabolism in infrequently supplemented ruminants. Our objective was determine the role of urea recycling in meeting ruminal nitrogen requirements in infrequently supplemented cattle fed low-quality forage

Microbial use of recycled urea is dependent on the level and frequency of degradable intake protein supplementation

Protein supplementation increases utilization (intake and digestion) of low-quality forage and ultimately animal performance. Despite its effectiveness, protein supplementation is often expensive. One strategy to reduce the cost of supplementation is to supplement less frequently than daily, generally every other day or every third day. By reducing the frequency of supplementation, the cost of delivering the supplement is reduced. Reducing the frequency of supplementation is an effective strategy for reducing cost, and it only minimally impacts animal performance, with less frequent supplementation resulting in slightly greater losses of body condition score and body weight during the winter supplementation period. Urea recycling, the transfer of urea from the animal\u27s body to the gastrointestinal tract, has been suggested as a mechanism that allows infrequently supplemented cattle to perform similarly to cattle supplemented daily. However, little data is available to substantiate this claim, and such data would be useful in helping nutritionists better understand nitrogen metabolism in infrequently supplemented ruminants. Our objective was determine the role of urea recycling in meeting ruminal nitrogen requirements in infrequently supplemented cattle fed low-quality forage

Serum antioxidants as predictors of the adult respiratory distress syndrome in septic patients

Adult respiratory distress syndrome (ARDS) can develop as a complication of various disorders, including sepsis, but it has not been possible to identify which of the patients at risk will develop this serious disorder. We have investigated the ability of six markers, measured sequentially in blood, to predict development of ARDS in 26 patients with sepsis. At the initial diagnosis of sepsis (6-24 h before the development of ARDS), serum manganese superoxide dismutase concentration and catalase activity were higher in the 6 patients who subsequently developed ARDS than in 20 patients who did not develop ARDS. These changes in antioxidant enzymes predicted the development of ARDS in septic patients with the same sensitivity, specificity, and efficiency as simultaneous assessments of serum lactate dehydrogenase activity and factor VIII concentration. By contrast, serum glutathione peroxidase activity and α1Pi-elastase complex concentration did not differ at the initial diagnosis of sepsis between patients who did and did not subsequently develop ARDS, and were not as effective in predicting the development of ARDS. Measurement of manganese superoxide dismutase and catalase, in addition to the other markers, should facilitate identification of patients at highest risk of ARDS and allow prospective treatment

Challenges of open innovation: the paradox of firm investment in open-source software

Open innovation is a powerful framework encompassing the generation, capture, and employment of intellectual property at the firm level. We identify three fundamental challenges for firms in applying the concept of open innovation: finding creative ways to exploit internal innovation, incorporating external innovation into internal development, and motivating outsiders to supply an ongoing stream of external innovations. This latter challenge involves a paradox, why would firms spend money on R&D efforts if the results of these efforts are available to rival firms? To explore these challenges, we examine the activity of firms in opensource software to support their innovation strategies. Firms involved in open-source software often make investments that will be shared with real and potential rivals. We identify four strategies firms employ – pooled R&D/product development, spinouts, selling complements and attracting donated complements – and discuss how they address the three key challenges of open innovation. We conclude with suggestions for how similar strategies may apply in other industries and offer some possible avenues for future research on open innovation

Antimicrobials: a global alliance for optimizing their rational use in intra-abdominal infections (agora)

Intra-abdominal infections (IAI) are an important cause of morbidity and are frequently associated with poor prognosis, particularly in high-risk patients. The cornerstones in the management of complicated IAIs are timely effective source control with app1133132sem informaçãosem informaçã

Iroa: the international register of open abdomen. an international effort to better understand the open abdomen: call for participants

Actually the most common indications for Open Abdomen (OA) are trauma, abdominal sepsis, severe acute pancreatitis and more in general all those situations in which an intra-abdominal hypertension condition is present, in order to prevent the development of an abdominal compartment syndrome. The mortality and morbidity rate in patients undergone to OA procedures is still high. At present many studies have been published about the OA management and the progresses in survival rate of critically ill trauma and septic surgical patients. However several issues are still unclear and need more extensive studies. The definitions of indications, applications and methods to close the OA are still matter of debate. To overcome this lack of high level of evidence data about the OA indications, management, definitive closure and follow-up, the World Society of Emergency Surgery (WSES) promoted the International Register of Open Abdomen (IROA). The register will be held on a web platform (Clinical Registers (R)) through a dedicated web site: www. clinicalregisters. org. This will allow to all surgeons and physicians to participate from all around the world only by having a computer and a web connection. The IROA protocol has been approved by the coordinating center Ethical Committee (Papa Giovanni XXIII hospital, Bergamo, Italy).Actually the most common indications for Open Abdomen (OA) are trauma, abdominal sepsis, severe acute pancreatitis and more in general all those situations in which an intra-abdominal hypertension condition is present, in order to prevent the development103713sem informaçãosem informaçã

Large scale numerical investigation of excited states in poly(phenylene)

A density matrix renormalisation group scheme is developed, allowing for the first time essentially exact numerical solutions for the important excited states of a realistic semi-empirical model for oligo-phenylenes. By monitoring the evolution of the energies with chain length and comparing them to the experimental absorption peaks of oligomers and thin films, we assign the four characteristic absorption peaks of phenyl-based polymers. We also determine the position and nature of the nonlinear optical states in this model.Comment: RevTeX, 10 pages, 4 eps figures included using eps

Caustic ingestion management: world society of emergency surgery preliminary survey of expert opinion

[This corrects the article DOI: 10.1186/s13017-015-0043-4.].sem informação1056sem informaçãosem informaçã