Deuteron and proton NMR study of D₂, p-dichlorobenzene and 1,3,5-trichlorobenzene in bimesogenic liquid crystals with two nematic phases

The solutes dideuterium, 1,3,5-trichlorobenzene and p-dichlorobenzene (pdcb) are co-dissolved in a 61/39 wt% mixture of CBC9CB/5CB, a bimesogenic liquid crystal with two nematic phases. NMR spectra are collected for each solute. The local electric field gradient (FZZ) is obtained from the dideuterium spectrum. A double Maier-Saupe potential (MSMS) is used to rationalize the order parameters of pdcb. The liquid-crystal fields G₁ and G₂ are taken to be due to size and shape interactions and interactions between the solute molecular quadrupole and the mean FZZ of the medium. The FZZ’s obtained from D₂ and G₂ (from pdcb) are compared and discussed

Origin of Superconductivity in Boron-doped Diamond

Superconductivity of boron-doped diamond, reported recently at T_c=4 K, is investigated exploiting its electronic and vibrational analogies to MgB2. The deformation potential of the hole states arising from the C-C bond stretch mode is 60% larger than the corresponding quantity in MgB2 that drives its high Tc, leading to very large electron-phonon matrix elements. The calculated coupling strength \lambda ~ 0.5 leads to T_c in the 5-10 K range and makes phonon coupling the likely mechanism. Higher doping should increase T_c somewhat, but effects of three dimensionality primarily on the density of states keep doped diamond from having a T_c closer to that of MgB2.Comment: Four pages with two embedded figures, corrected fig1. (To appear in Physical Review Letters(2004)

The stabilisation of the Nx phase in mixtures

The phase behaviour of mixtures between two symmetric dimers, CBC9CB and the ether-linked analogue CBOC9OCB was investigated by Polarizing Optical Microscopy (POM), Differential Scanning Calorimetry (DSC) and X-Ray Diffraction (XRD) studies. The dimeric constituents are fully miscible and the construction of a temperature-composition phase diagram reveals a surprising amplification of the stability of the Nx phase in compositions of up to 37 wt% of CBOC9OCB in CBC9CB. The origin for this enhancement of stability is discussed and an explanation based on chiral recognition is developed

NMR study of a bimesogenic liquid crystal with two nematic phases

Recent interest in bimesogenic liquid crystals showing two nematic phases has led us to investigate the nematic mean-field interactions in these nematic phases by using rigid solutes as probes. The nematic potential that is modelled by two independent Maier-Saupe terms is successful in fitting the observed dipolar couplings (order parameters) of para-, meta- and ortho-dichlorobenzene solutes in both the nematic phases of 39 wt% of 4-n-pentyl-4′-cyanobiphenyl (5CB) in α,ω-bis(4-4′-cyanobiphenyl)nonane (CB_C9_CB) to better than the 5% level. The derived liquid-crystal potential parameters G₁ and G₂ for each solute in the N and Ntb phases will be discussed. The most interesting observation is that G1 (associated with size and shape interactions) is almost constant in the Ntb phase, whereas G₂ (associated with longer-range electrostatic interactions) has large variation, even changing sign

Late Glacial–Holocene climatic transition record at the Argentinian Andean piedmont between 33 and 34° S

The Arroyo La Estacada (~ 33°28' S, 69°02' W), eastern Andean piedmont of Argentina, cuts through an extensive piedmont aggradational unit composed of a dominant Late Pleistocene–early Holocene (LP–EH) alluvial sequence that includes several paleosols. <br><br> One of these paleosols developed affecting the topmost part of likely Late Glacial aeolian deposits aggraded into a floodplain environment by the end of the Late Pleistocene. The paleosol shows variable grade of development along the arroyo outcrops. Organic matter humification, carbonate accumulation and redox processes were the dominant processes associated with paleosol formation. By the early Holocene, when the formation of the paleosol ended, renewed alluvial aggradation and high magnitude flooding events affected the arroyo's floodplain environment. Accordignly, a period of relative landscape stability in the Arroyo La Estacada basin is inferred from the paleosol developed by the LP–EH transition in response to the climatic conditions in the Andes cordillera piedmont after the Late Glacial arid conditions. The analyzed Late Glacial–Holocene alluvial record of the Andean piedmont constitutes a suitable record of the LP–EH climatic transition in the extra-Andean region of Argentina. It is in agreement with regional paleoclimatic evidence along the southern tip of the South American continent, where other pedosedimentary sequences record similar late Quaternary paleoenvironmental changes over both fluvial and interfluvial areas

Noninvasive Measurement of Dissipation in Colloidal Systems

According to Harada and Sasa [Phys. Rev. Lett. 95, 130602 (2005)], heat production generated in a non-equilibrium steady state can be inferred from measuring response and correlation functions. In many colloidal systems, however, it is a nontrivial task to determine response functions, whereas details about spatial steady state trajectories are easily accessible. Using a simple conditional averaging procedure, we show how this fact can be exploited to reliably evaluate average heat production. We test this method using Brownian dynamics simulations, and apply it to experimental data of an interacting driven colloidal system

Solving singular generalized eigenvalue problems. Part II: projection and augmentation

Generalized eigenvalue problems involving a singular pencil may be very challenging to solve, both with respect to accuracy and efficiency. While Part I presented a rank-completing addition to a singular pencil, we now develop two alternative methods. The first technique is based on a projection onto subspaces with dimension equal to the normal rank of the pencil while the second approach exploits an augmented matrix pencil. The projection approach seems to be the most attractive version for generic singular pencils because of its efficiency, while the augmented pencil approach may be suitable for applications where a linear system with the augmented pencil can be solved efficiently

Produção de biomassa e padrão de decomposição de adubos verdes cultivados nas entrelinhas de acerola orgânica.

A utilização de adubos verdes constitui uma opção para o adequado aporte de matéria orgânica em solos arenosos sujeitos a um alto grau de degradação. O objetivo deste trabalho foi quantificar a produção e o padrão de decomposição de biomassa de seis espécies de adubos verdes e da vegetação espontânea