239 research outputs found
Latitudinal pattern in community-wide herbivory does not match the pattern in herbivory averaged across common plant species
The latitudinal herbivory hypothesis (LHH) predicts that plant losses to herbivores decrease from low to high latitudes. Although the LHH is a community-level hypothesis, it has been rarely tested with data on community-wide herbivory, i.e. the percentage of annual production of foliar biomass consumed by insects from all plant species at a given site. Therefore, we asked whether community-wide leaf herbivory follows the same latitudinal pattern as observed for an unweighted average of herbivory across common plant species. We selected 10 study sites in boreal forests from 60 to 69 degrees N along a 1,000-km long latitudinal gradient in NW Russia. We measured relative foliar losses to insect herbivores in seven woody plant species (jointly comprising over 95% of the community-wide above-ground biomass) and estimated their current-year foliar biomass. We averaged leaf herbivory for all seven species and calculated community-wide leaf herbivory by weighting the relative foliar losses of each plant species against the contribution of that species to the annual foliar biomass production. Leaf herbivory was five-fold higher in deciduous species than in conifers. Latitudinal patterns in herbivory varied from a significant poleward decrease in all deciduous species to a significant poleward increase in Norway spruce. Herbivory values, averaged across seven plant species, decreased with latitude and followed the pattern observed in deciduous plants due to their higher foliar losses compared with conifers. By contrast, community-wide herbivory did not change with latitude. This discrepancy emerged because the proportion of deciduous plant foliage in the community increased with increasing latitude, and this increase counterbalanced the simultaneous poleward decrease in losses of these species to insects. Synthesis. The herbivory measured by averaging relative losses of individual plant species and community-wide herbivory is likely to show different latitudinal patterns in various plant communities. The contributions of plant species to the total foliar biomass production should be taken into account in studies of spatial patterns of herbivory which test community-level hypotheses. This approach may provide new insight into macroecological research on biotic interactions and improve our understanding of the role of insect herbivores in ecosystem-level processes
Orbitally induced hierarchy of exchange interactions in zigzag antiferromagnetic state of honeycomb silver delafossite Ag3Co2SbO6
We report the revised crystal structure, static and dynamic magnetic
properties of quasi-two dimensional honeycomb-lattice silver delafossite
Ag3Co2SbO6. The magnetic susceptibility and specific heat data are consistent
with the onset of antiferromagnetic long range order at low temperatures with
N\'eel temperature TN ~ 21.2 K. In addition, the magnetization curves revealed
a field-induced (spin-flop type) transition below TN in moderate magnetic
fields. The GGA+U calculations show the importance of the orbital degrees of
freedom, which maintain a hierarchy of exchange interaction in the system. The
strongest antiferromagnetic exchange coupling was found in the shortest Co-Co
pairs and is due to direct and superexchange interactions between the
half-filled xz+yz orbitals pointing directly to each other. The other four out
of six nearest neighbor exchanges within the cobalt hexagon are suppressed,
since for these bonds active half-filled orbitals turned out to be parallel and
do not overlap. The electron spin resonance (ESR) spectra reveal a Gaussian
shape line attributed to Co2+ ion in octahedral coordination with average
effective g-factor g=2.3+/-0.1 at room temperature and shows strong divergence
of ESR parameters below 120 K, which imply an extended region of short-range
correlations. Based on the results of magnetic and thermodynamic studies in
applied fields, we propose the magnetic phase diagram for the new
honeycomb-lattice delafossite
Molecular genetic methods for identifying raw materials in meat products: Diversity, opportunities and prospects
In the current economic situation, after easing the Covid pandemic restrictions, almost all laboratories, which are focused on evaluation of the conformity of food products, have faced issues in supplying for their laboratories. In this regard, in the last years many laboratories have been forced to validate new approaches and introduce new methods for assessing conformity of the food products. Very often it is not possible to use only one method to resolve the issue of the food product ingredients, especially for the purpose of traceability of their names and the used raw materials, listed on the label. Survey of the raw food materials to determine whether they correspond to the type name is a simpler task, in contrast to survey of the multicomponent food product. Many researchers have to estimate the opportunities and feasibility of application of various methodologies in their workplaces. Therefore, this review is relevant for the researchers in this field, as it focuses on aspects and special features of similar methodologies. The prospect of molecular genetic methods for identification of the raw materials used for manufacturing of meat products is presented below. This review also represents characteristics of methods for identification of the sources of raw materials used for the manufacturing of the meat products, based on the recognition of species-specific sections within the nucleic acids structures. The variety of methods (hybridization methods, polymerase chain reaction, different types of isothermal amplifications, methods using CRISPR/Cas systems), the principles of their implementation, and achieved analytical characteristics are considered. The capacities and competitive potential of various methods are discussed, as well as approaches being developed to overcome the existing limitations.In the current economic situation, after easing the Covid pandemic restrictions, almost all laboratories, which are focused on evaluation of the conformity of food products, have faced issues in supplying for their laboratories. In this regard, in the last years many laboratories have been forced to validate new approaches and introduce new methods for assessing conformity of the food products. Very often it is not possible to use only one method to resolve the issue of the food product ingredients, especially for the purpose of traceability of their names and the used raw materials, listed on the label. Survey of the raw food materials to determine whether they correspond to the type name is a simpler task, in contrast to survey of the multicomponent food product. Many researchers have to estimate the opportunities and feasibility of application of various methodologies in their workplaces. Therefore, this review is relevant for the researchers in this field, as it focuses on aspects and special features of similar methodologies. The prospect of molecular genetic methods for identification of the raw materials used for manufacturing of meat products is presented below. This review also represents characteristics of methods for identification of the sources of raw materials used for the manufacturing of the meat products, based on the recognition of species-specific sections within the nucleic acids structures. The variety of methods (hybridization methods, polymerase chain reaction, different types of isothermal amplifications, methods using CRISPR/Cas systems), the principles of their implementation, and achieved analytical characteristics are considered. The capacities and competitive potential of various methods are discussed, as well as approaches being developed to overcome the existing limitations
Study of composite coal-water fuel rheological properties
Β© Published under licence by IOP Publishing Ltd. The rheological characteristics of composite water-coal fuel, as well as the possibility of reducing the viscosity of composite water-coal fuel due to the use of nanomaterials, are studied. Improved rheological properties of composite fuel containing small additions of these substances: carbon nanomaterial at a concentration of 0.005 wt. % or 0.3 wt. % of the dehydrated carbonate slurry. Possible mechanisms for changing the viscosity properties of fuel are considered
Synthesis and characterization of MnCrO4, a new mixed-valence antiferromagnet
A new orthorhombic phase, MnCrO4, isostructural with MCrO 4 (M = Mg, Co, Ni, Cu, Cd) was prepared by evaporation of an aqueous solution, (NH4)2Cr2O7 + 2 Mn(NO 3)2, followed by calcination at 400 C. It is characterized by redox titration, Rietveld analysis of the X-ray diffraction pattern, Cr K edge and Mn K edge XANES, ESR, magnetic susceptibility, specific heat and resistivity measurements. In contrast to the high-pressure MnCrO4 phase where both cations are octahedral, the new phase contains Cr in a tetrahedral environment suggesting the charge balance Mn2+Cr 6+O4. However, the positions of both X-ray absorption K edges, the bond lengths and the ESR data suggest the occurrence of some mixed-valence character in which the mean oxidation state of Mn is higher than 2 and that of Cr is lower than 6. Both the magnetic susceptibility and the specific heat data indicate an onset of a three-dimensional antiferromagnetic order at TN β 42 K, which was confirmed also by calculating the spin exchange interactions on the basis of first principles density functional calculations. Dynamic magnetic studies (ESR) corroborate this scenario and indicate appreciable short-range correlations at temperatures far above T N. MnCrO4 is a semiconductor with activation energy of 0.27 eV; it loses oxygen on heating above 400 C to form first Cr 2O3 plus Mn3O4 and then Mn 1.5Cr1.5O4 spinel. Β© 2013 American Chemical Society
ΠΠΠΠΠ’ΠΠ€ΠΠΠΠ¦ΠΠ― Π ΠΠΠΠΠ§ΠΠ‘Π’ΠΠΠΠΠΠ ΠΠΠ ΠΠΠΠΠΠΠΠ ΠΠ«Π¨ΠΠ§ΠΠΠ Π’ΠΠΠΠ ΠΠ ΠΠ‘ΠΠΠΠ ΠΠΠΠ’Π ΠΠΠ― ΠΠ ΠΠ’ΠΠ’ΠΠΠΠ§ΠΠ‘ΠΠΠ₯ ΠΠΠΠ’ΠΠΠΠ Π‘ ΠΠ‘ΠΠΠΠ¬ΠΠΠΠΠΠΠΠ ΠΠΠ’ΠΠΠ ΠΠΠΠΠ’ΠΠ ΠΠΠΠ ΠΠΠΠΠΠΠ«Π₯ Π ΠΠΠΠ¦ΠΠ
One of the main problems of modern production of meat products is the quality of raw meat, which depends on various factors including genetic components, conditions of transportation, production and processing. The most important components of meat are proteins, the total content, structure and functional state of which in this complex biological system with many interacting components is constantly changing. In order to study the interspecific and intraspecific features of meat proteins, their transformations in the process of maturation and processing requires modern analytical technologies based on the systematic approach to the analysis. Proteomics, as a methodology for studying proteins in a certain system and at a certain time, opens wide opportunities in this direction, allowing to identify and develop accurate analytical methods for searching biomarkers and identifying unfair practices. Given the high added value and multicomponent composition, finished meat products are among the most susceptible to adulteration. Current paper presents a technique of high-performance liquid chromatography with mass spectrometric detector (HPLC-MS) adapted for the detection and quantification of two different types of meat (beef and pork) in a complex biological matrix such as structureless minced meat. After the protein isolation and trypsin cleavage, species-specific peptide markers were selected for each animal species for the quantification. The technique was tested on model samples of a mixture of muscle tissue of the two species of animals. A good sensitivity was established with the possibility of quantitative determination of muscle tissue of each animal species using special calibration graphs. The developed technique can find wide application at the supervising organizations aimed at counteracting the discrepancies in the hidden replacement of types of meat by cheaper or low-grade raw materials.Keywords: Biomarker, prototypical peptides, HPLC-MS, species identification(Russian)Β DOI: http://dx.doi.org/10.15826/analitika.2019.23.4.012D.V. Khvostov1, N.L. Vostrikova1, A.V. Zherdev2, E.A. Zvereva2, A.A. Kurzova1 Β 1V.M. Gorbatov Federal Research Center for Food Systems of Russian Academy of Sciences, 109316 Moscow, Russian FederationΒ 2Federal State Institution Β«Federal Research Centre Β«Fundamentals of BiotechnologyΒ» of the Russian Academy of SciencesΒ», Leninsky prospect, 33, build. 2, 119071 Moscow, Russian FederationΠΠ΄Π½ΠΎΠΉ ΠΈΠ· ΠΎΡΠ½ΠΎΠ²Π½ΡΡ
ΠΏΡΠΎΠ±Π»Π΅ΠΌ ΡΠΎΠ²ΡΠ΅ΠΌΠ΅Π½Π½ΠΎΠ³ΠΎ ΠΏΡΠΎΠΈΠ·Π²ΠΎΠ΄ΡΡΠ²Π° ΠΌΡΡΠ½ΡΡ
ΠΏΡΠΎΠ΄ΡΠΊΡΠΎΠ² ΡΠ²Π»ΡΠ΅ΡΡΡ ΠΊΠ°ΡΠ΅ΡΡΠ²ΠΎ ΠΌΡΡΠ½ΠΎΠ³ΠΎ ΡΡΡΡΡ, ΠΊΠΎΡΠΎΡΠΎΠ΅ Π·Π°Π²ΠΈΡΠΈΡ ΠΎΡ ΡΠ°Π·Π½ΡΡ
ΡΠ°ΠΊΡΠΎΡΠΎΠ², Π²ΠΊΠ»ΡΡΠ°Ρ Π³Π΅Π½Π΅ΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠΎΡΡΠ°Π²Π»ΡΡΡΠΈΠ΅, ΡΡΠ»ΠΎΠ²ΠΈΡ ΡΡΠ°Π½ΡΠΏΠΎΡΡΠΈΡΠΎΠ²Π°Π½ΠΈΡ, ΠΏΡΠΎΠΈΠ·Π²ΠΎΠ΄ΡΡΠ²Π° ΠΈ ΠΏΠ΅ΡΠ΅ΡΠ°Π±ΠΎΡΠΊΠΈ. Π Π½Π°ΠΈΠ±ΠΎΠ»Π΅Π΅ Π·Π½Π°ΡΠΈΠΌΡΠΌ ΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΠ°ΠΌ ΠΌΡΡΠ° ΠΎΡΠ½ΠΎΡΡΡΡΡ Π±Π΅Π»ΠΊΠΈ, ΠΎΠ±ΡΠ΅Π΅ ΡΠΎΠ΄Π΅ΡΠΆΠ°Π½ΠΈΠ΅, ΡΡΡΡΠΊΡΡΡΠ° ΠΈ ΡΡΠ½ΠΊΡΠΈΠΎΠ½Π°Π»ΡΠ½ΠΎΠ΅ ΡΠΎΡΡΠΎΡΠ½ΠΈΠ΅ ΠΊΠΎΡΠΎΡΡΡ
Π² ΡΠΎΡΡΠ°Π²Π΅ ΡΡΠΎΠΉ ΡΠ»ΠΎΠΆΠ½ΠΎΠΉ Π±ΠΈΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΎΠΉ ΡΠΈΡΡΠ΅ΠΌΡ, Ρ Π±ΠΎΠ»ΡΡΠΈΠΌ ΠΊΠΎΠ»ΠΈΡΠ΅ΡΡΠ²ΠΎΠΌ Π²Π·Π°ΠΈΠΌΠΎΠ΄Π΅ΠΉΡΡΠ²ΡΡΡΠΈΡ
ΡΠΎΡΡΠ°Π²Π»ΡΡΡΠΈΡ
, ΠΏΠΎΡΡΠΎΡΠ½Π½ΠΎ ΠΈΠ·ΠΌΠ΅Π½ΡΠ΅ΡΡΡ. ΠΠ»Ρ ΠΈΠ·ΡΡΠ΅Π½ΠΈΡ ΠΌΠ΅ΠΆΠ²ΠΈΠ΄ΠΎΠ²ΡΡ
ΠΈ Π²Π½ΡΡΡΠΈΠ²ΠΈΠ΄ΠΎΠ²ΡΡ
ΠΎΡΠΎΠ±Π΅Π½Π½ΠΎΡΡΠ΅ΠΉ Π±Π΅Π»ΠΊΠΎΠ² ΠΌΡΡΠ°, ΡΡΠ°Π½ΡΡΠΎΡΠΌΠ°ΡΠΈΠΈ ΠΈΡ
Π² ΠΏΡΠΎΡΠ΅ΡΡΠ΅ ΡΠΎΠ·ΡΠ΅Π²Π°Π½ΠΈΡ ΠΈ ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΎΠΉ ΠΎΠ±ΡΠ°Π±ΠΎΡΠΊΠΈ ΡΡΠ΅Π±ΡΡΡΡΡ ΡΠΎΠ²ΡΠ΅ΠΌΠ΅Π½Π½ΡΠ΅ Π°Π½Π°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΡΠ΅Ρ
Π½ΠΎΠ»ΠΎΠ³ΠΈΠΈ, ΠΎΡΠ½ΠΎΠ²Π°Π½Π½ΡΠ΅ Π½Π° ΡΠΈΡΡΠ΅ΠΌΠ½ΠΎΠΌ ΠΏΠΎΠ΄Ρ
ΠΎΠ΄Π΅ ΠΊ Π°Π½Π°Π»ΠΈΠ·Ρ. Π¨ΠΈΡΠΎΠΊΠΈΠ΅ Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡΠΈ Π² ΡΡΠΎΠΌ Π½Π°ΠΏΡΠ°Π²Π»Π΅Π½ΠΈΠΈ ΠΎΡΠΊΡΡΠ²Π°Π΅Ρ ΠΏΡΠΎΡΠ΅ΠΎΠΌΠΈΠΊΠ°, ΠΊΠ°ΠΊ ΠΌΠ΅ΡΠΎΠ΄ΠΎΠ»ΠΎΠ³ΠΈΠΈ ΠΈΠ·ΡΡΠ΅Π½ΠΈΡ Π±Π΅Π»ΠΊΠΎΠ² Π² ΠΎΠΏΡΠ΅Π΄Π΅Π»Π΅Π½Π½ΠΎΠΉ ΡΠΈΡΡΠ΅ΠΌΠ΅ ΠΈ Π² ΠΎΠΏΡΠ΅Π΄Π΅Π»Π΅Π½Π½ΠΎΠ΅ Π²ΡΠ΅ΠΌΡ, ΠΏΠΎΠ·Π²ΠΎΠ»ΡΡΡΠ°Ρ ΠΈΠ΄Π΅Π½ΡΠΈΡΠΈΡΠΈΡΠΎΠ²Π°ΡΡ ΠΈ ΡΠ°Π·ΡΠ°Π±Π°ΡΡΠ²Π°ΡΡ ΡΠΎΡΠ½ΡΠ΅ Π°Π½Π°Π»ΠΈΡΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΠΌΠ΅ΡΠΎΠ΄Ρ ΠΏΠΎΠΈΡΠΊΠ° Π±ΠΈΠΎΠΌΠ°ΡΠΊΠ΅ΡΠΎΠ² ΠΈ Π²ΡΡΠ²Π»Π΅Π½ΠΈΡ Π½Π΅Π΄ΠΎΠ±ΡΠΎΡΠΎΠ²Π΅ΡΡΠ½ΡΡ
ΠΏΡΠ°ΠΊΡΠΈΠΊ. Π£ΡΠΈΡΡΠ²Π°Ρ Π²ΡΡΠΎΠΊΡΡ Π΄ΠΎΠ±Π°Π²Π»Π΅Π½Π½ΡΡ ΡΡΠΎΠΈΠΌΠΎΡΡΡ ΠΈ ΠΌΠ½ΠΎΠ³ΠΎΠΊΠΎΠΌΠΏΠΎΠ½Π΅Π½ΡΠ½ΠΎΡΡΡ ΡΠΎΡΡΠ°Π²Π°, Π³ΠΎΡΠΎΠ²ΡΠ΅ ΠΌΡΡΠ½ΡΠ΅ ΠΏΡΠΎΠ΄ΡΠΊΡΡ ΠΎΡΠ½ΠΎΡΡΡΡΡ ΠΊ ΡΠΈΡΠ»Ρ Π½Π°ΠΈΠ±ΠΎΠ»Π΅Π΅ ΠΏΠΎΠ΄Π²Π΅ΡΠΆΠ΅Π½Π½ΡΡ
ΡΠ°Π»ΡΡΠΈΡΠΈΠΊΠ°ΡΠΈΠΈ. Π ΡΠ°Π±ΠΎΡΠ΅ ΠΏΡΠ΅Π΄ΡΡΠ°Π²Π»Π΅Π½Π° ΠΌΠ΅ΡΠΎΠ΄ΠΈΠΊΠ° Π²ΡΡΠΎΠΊΠΎΡΡΡΠ΅ΠΊΡΠΈΠ²Π½ΠΎΠΉ ΠΆΠΈΠ΄ΠΊΠΎΡΡΠ½ΠΎΠΉ Ρ
ΡΠΎΠΌΠ°ΡΠΎΠ³ΡΠ°ΡΠΈΠΈ Ρ ΠΌΠ°ΡΡ-ΡΠΏΠ΅ΠΊΡΡΠΎΠΌΠ΅ΡΡΠΈΡΠ΅ΡΠΊΠΈΠΌ Π΄Π΅ΡΠ΅ΠΊΡΠΎΡΠΎΠΌ (ΠΠΠΠ₯-ΠΠ‘), Π°Π΄Π°ΠΏΡΠΈΡΠΎΠ²Π°Π½Π½Π°Ρ Π΄Π»Ρ ΠΎΠ±Π½Π°ΡΡΠΆΠ΅Π½ΠΈΡ ΠΈ ΠΊΠΎΠ»ΠΈΡΠ΅ΡΡΠ²Π΅Π½Π½ΠΎΠ³ΠΎ ΠΎΠΏΡΠ΅Π΄Π΅Π»Π΅Π½ΠΈΡ Π΄Π²ΡΡ
ΡΠ°Π·Π»ΠΈΡΠ½ΡΡ
Π²ΠΈΠ΄ΠΎΠ² ΠΌΡΡΠ° (Π³ΠΎΠ²ΡΠ΄ΠΈΠ½Π° ΠΈ ΡΠ²ΠΈΠ½ΠΈΠ½Π°) Π² ΡΠ»ΠΎΠΆΠ½ΠΎΠΉ Π±ΠΈΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΎΠΉ ΠΌΠ°ΡΡΠΈΡΠ΅, ΡΠ°ΠΊΠΎΠΉ ΠΊΠ°ΠΊ Π±Π΅ΡΡΡΡΡΠΊΡΡΡΠ½ΡΠ΅ ΡΠ°ΡΡΠΈ. ΠΠΎΡΠ»Π΅ Π²ΡΠ΄Π΅Π»Π΅Π½ΠΈΡ Π±Π΅Π»ΠΊΠΎΠ² ΠΈ ΡΠ°ΡΡΠ΅ΠΏΠ»Π΅Π½ΠΈΡ ΠΈΡ
ΡΡΠΈΠΏΡΠΈΠ½ΠΎΠΌ Π±ΡΠ»ΠΈ Π²ΡΠ±ΡΠ°Π½Ρ Π²ΠΈΠ΄ΠΎΡΠΏΠ΅ΡΠΈΡΠΈΡΠ½ΡΠ΅ ΠΏΠ΅ΠΏΡΠΈΠ΄Π½ΡΠ΅ ΠΌΠ°ΡΠΊΠ΅ΡΡ Π΄Π»Ρ ΠΊΠ°ΠΆΠ΄ΠΎΠ³ΠΎ Π²ΠΈΠ΄Π° ΠΆΠΈΠ²ΠΎΡΠ½ΠΎΠ³ΠΎ Ρ ΡΠ΅Π»ΡΡ ΠΊΠΎΠ»ΠΈΡΠ΅ΡΡΠ²Π΅Π½Π½ΠΎΠ³ΠΎ ΠΎΠΏΡΠ΅Π΄Π΅Π»Π΅Π½ΠΈΡ. ΠΠ΅ΡΠΎΠ΄ΠΈΠΊΠ° Π±ΡΠ»Π° Π°ΠΏΡΠΎΠ±ΠΈΡΠΎΠ²Π°Π½Π° Π½Π° ΠΌΠΎΠ΄Π΅Π»ΡΠ½ΡΡ
ΠΎΠ±ΡΠ°Π·ΡΠ°Ρ
ΡΠΌΠ΅ΡΠΈ ΠΌΡΡΠ΅ΡΠ½ΠΎΠΉ ΡΠΊΠ°Π½ΠΈ Π΄Π²ΡΡ
Π²ΠΈΠ΄ΠΎΠ² ΠΆΠΈΠ²ΠΎΡΠ½ΡΡ
. Π£ΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½Π° Ρ
ΠΎΡΠΎΡΠ°Ρ ΡΡΠ²ΡΡΠ²ΠΈΡΠ΅Π»ΡΠ½ΠΎΡΡΡ Ρ Π²ΠΎΠ·ΠΌΠΎΠΆΠ½ΠΎΡΡΡΡ ΠΊΠΎΠ»ΠΈΡΠ΅ΡΡΠ²Π΅Π½Π½ΠΎΠ³ΠΎ ΠΎΠΏΡΠ΅Π΄Π΅Π»Π΅Π½ΠΈΡ ΠΌΡΡΠ΅ΡΠ½ΠΎΠΉ ΡΠΊΠ°Π½ΠΈ ΠΊΠ°ΠΆΠ΄ΠΎΠ³ΠΎ Π²ΠΈΠ΄Π° ΠΆΠΈΠ²ΠΎΡΠ½ΠΎΠ³ΠΎ, ΠΏΡΠΈ ΠΈΡΠΏΠΎΠ»ΡΠ·ΠΎΠ²Π°Π½ΠΈΠΈ ΡΠΏΠ΅ΡΠΈΠ°Π»ΡΠ½ΡΡ
Π³ΡΠ°Π΄ΡΠΈΡΠΎΠ²ΠΎΡΠ½ΡΡ
Π³ΡΠ°ΡΠΈΠΊΠΎΠ². Π Π°Π·ΡΠ°Π±ΠΎΡΠ°Π½Π½Π°Ρ ΠΌΠ΅ΡΠΎΠ΄ΠΈΠΊΠ° ΠΌΠΎΠΆΠ΅Ρ Π½Π°ΠΉΡΠΈ ΡΠΈΡΠΎΠΊΠΎΠ΅ ΠΏΡΠΈΠΌΠ΅Π½Π΅Π½ΠΈΠ΅ Ρ ΠΊΠΎΠ½ΡΡΠΎΠ»ΠΈΡΡΡΡΠΈΡ
ΠΎΡΠ³Π°Π½ΠΈΠ·Π°ΡΠΈΠΉ, Π½Π°ΠΏΡΠ°Π²Π»Π΅Π½Π½ΡΡ
Π½Π° ΠΏΡΠΎΡΠΈΠ²ΠΎΠ΄Π΅ΠΉΡΡΠ²ΠΈΠ΅ Π½Π΅ΡΠΎΠΎΡΠ²Π΅ΡΡΡΠ²ΠΈΡΠΌ ΠΏΠΎ ΡΠΊΡΡΡΠΎΠΉ Π·Π°ΠΌΠ΅Π½Π΅ Π²ΠΈΠ΄ΠΎΠ² ΠΌΡΡΠ° Π±ΠΎΠ»Π΅Π΅ Π΄Π΅ΡΠ΅Π²ΡΠΌ ΠΈΠ»ΠΈ Π½ΠΈΠ·ΠΊΠΎΡΠΎΡΡΠ½ΡΠΌΠΈ ΡΡΡΡΠ΅ΠΌ.ΠΠ»ΡΡΠ΅Π²ΡΠ΅ ΡΠ»ΠΎΠ²Π°: ΠΠΈΠΎΠΌΠ°ΡΠΊΠ΅Ρ, ΠΏΡΠΎΡΠΎΡΠΈΠΏΠΈΡΠ΅ΡΠΊΠΈΠ΅ ΠΏΠ΅ΠΏΡΠΈΠ΄Ρ, ΠΠΠΠ₯-ΠΠ‘, Π²ΠΈΠ΄ΠΎΠ²Π°Ρ ΠΈΠ΄Π΅Π½ΡΠΈΡΠΈΠΊΠ°ΡΠΈΡDOI: http://dx.doi.org/10.15826/analitika.2019.23.4.01
Complex formation of d-metal ions at the interface of Tb III-doped silica nanoparticles as a basis of substrate-responsive TbIII-centered luminescence
The complex formation of d-metal ions at the interface of Tb III-doped silica nanoparticles modified by amino groups is introduced as a route to sensing d-metal ions and some organic molecules. Diverse modes of surface modification (covalent and noncovalent) are used to fix amino groups onto the silica surface. The interfacial binding of d-metal ions and complexes is the reason for the TbIII-centered luminescence quenching. The regularities and mechanisms of quenching are estimated for the series of d-metal ions and their complexes with chelating ligands. The obtained results reveal the interfacial binding of CuII ions as the basis of their quantitative determination in the concentration range 0.1-2.5 ΞΌM by means of steady-state and time-resolved fluorescence measurements. The variation of chelating ligands results in a significant effect on the quenching regularities due to diverse binding modes (inner or outer sphere) between amino groups at the interface of nanoparticles and FeIII ions. The applicability of the steady-state and time-resolved fluorescence measurements to sense both Fe III ions and catechols in aqueous solution by means of Tb III-doped silica nanoparticles is also introduced. Β© 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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