A hierarchy of models related to nanoflows and surface diffusion

In last years a great interest was brought to molecular transport problems at nanoscales, such as surface diffusion or molecular flows in nano or sub-nano-channels. In a series of papers V. D. Borman, S. Y. Krylov, A. V. Prosyanov and J. J. M. Beenakker proposed to use kinetic theory in order to analyze the mechanisms that determine mobility of molecules in nanoscale channels. This approach proved to be remarkably useful to give new insight on these issues, such as density dependence of the diffusion coefficient. In this paper we revisit these works to derive the kinetic and diffusion models introduced by V. D. Borman, S. Y. Krylov, A. V. Prosyanov and J. J. M. Beenakker by using classical tools of kinetic theory such as scaling and systematic asymptotic analysis. Some results are extended to less restrictive hypothesis

Long Term Object Drift Forecast in the Ocean With Tide and

In this paper, we propose a new method to forecast the drift of objects in near coastal ocean on a period of several weeks. The proposed approach consists in estimating the probability of events linked to the drift using Monte Carlo simulations. It couples an averaging method which permits to decrease the computational cost and a statistical method in order to take into account the variability of meteorological loading factors

Large time dynamics of a classical system subject to a fast varying force

International audienceWe investigate the asymptotic behavior of solutions to a kinetic equation describing the evolution of particles subject to the sum of a fixed, confining, Hamiltonian, and a small, time-oscillating, perturbation. The equation also involves an interaction operator which acts as a relaxation in the energy variable. This paper aims at providing a classical counterpart to the derivation of rate equations from the atomic Bloch equations. In the present classical setting, the homogenization procedure leads to a diffusion equation in the energy variable, rather than a rate equation, and the presence of the relaxation operator regularizes the limit process, leading to finite diffusion coefficients. The key assumption is that the time-oscillatory perturbation should have well-defined long time averages: our procedure includes general "ergodic" behaviors, amongst which periodic, or quasi-periodic potentials only are a particular case

Theory of Transport Processes and the Method of the Nonequilibrium Statistical Operator

The aim of this review is to provide better understanding of a few approaches that have been proposed for treating nonequilibrium (time-dependent) processes in statistical mechanics with the emphasis on the inter-relation between theories. The ensemble method, as it was formulated by J. W. Gibbs, have the great generality and the broad applicability to equilibrium statistical mechanics. Different macroscopic environmental constraints lead to different types of ensembles, with particular statistical characteristics. In the present work, the statistical theory of nonequilibrium processes which is based on nonequilibrium ensemble formalism is discussed. The kinetic approach to dynamic many-body problems, which is important from the point of view of the fundamental theory of irreversibility, is alluded to. The emphasis is on the method of the nonequilibrium statistical operator (NSO) developed by D. N. Zubarev. The NSO method permits one to generalize the Gibbs ensemble method to the nonequilibrium case and to construct a nonequilibrium statistical operator which enables one to obtain the transport equations and calculate the transport coefficients in terms of correlation functions, and which, in the case of equilibrium, goes over to the Gibbs distribution. Although some space is devoted to the formal structure of the NSO method, the emphasis is on its utility. Applications to specific problems such as the generalized transport and kinetic equations, and a few examples of the relaxation and dissipative processes, which manifest the operational ability of the method, are considered.Comment: This submission has been removed by arXiv admin because the files submitted were incomplet