The Ehrenfest urn revisited: Playing the game on a realistic fluid model

The Ehrenfest urn process, also known as the dogs and fleas model, is realistically simulated by molecular dynamics of the Lennard-Jones fluid. The key variable is Delta z, i.e. the absolute value of the difference between the number of particles in one half of the simulation box and in the other half. This is a pure-jump stochastic process induced, under coarse graining, by the deterministic time evolution of the atomic coordinates. We discuss the Markov hypothesis by analyzing the statistical properties of the jumps and of the waiting times between jumps. In the limit of a vanishing integration time-step, the distribution of waiting times becomes closer to an exponential and, therefore, the continuous-time jump stochastic process is Markovian. The random variable Delta z behaves as a Markov chain and, in the gas phase, the observed transition probabilities follow the predictions of the Ehrenfest theory.Comment: Accepted by Physical Review E on 4 May 200

Non-analytic microscopic phase transitions and temperature oscillations in the microcanonical ensemble: An exactly solvable 1d-model for evaporation

We calculate exactly both the microcanonical and canonical thermodynamic functions (TDFs) for a one-dimensional model system with piecewise constant Lennard-Jones type pair interactions. In the case of an isolated $N$-particle system, the microcanonical TDFs exhibit (N-1) singular (non-analytic) microscopic phase transitions of the formal order N/2, separating N energetically different evaporation (dissociation) states. In a suitably designed evaporation experiment, these types of phase transitions should manifest themselves in the form of pressure and temperature oscillations, indicating cooling by evaporation. In the presence of a heat bath (thermostat), such oscillations are absent, but the canonical heat capacity shows a characteristic peak, indicating the temperature-induced dissociation of the one-dimensional chain. The distribution of complex zeros (DOZ) of the canonical partition may be used to identify different degrees of dissociation in the canonical ensemble.Comment: version accepted for publication in PRE, minor additions in the text, references adde

Einstein's quantum theory of the monatomic ideal gas: non-statistical arguments for a new statistics

In this article, we analyze the third of three papers, in which Einstein presented his quantum theory of the ideal gas of 1924-1925. Although it failed to attract the attention of Einstein's contemporaries and although also today very few commentators refer to it, we argue for its significance in the context of Einstein's quantum researches. It contains an attempt to extend and exhaust the characterization of the monatomic ideal gas without appealing to combinatorics. Its ambiguities illustrate Einstein's confusion with his initial success in extending Bose's results and in realizing the consequences of what later became to be called Bose-Einstein statistics. We discuss Einstein's motivation for writing a non-combinatorial paper, partly in response to criticism by his friend Ehrenfest, and we paraphrase its content. Its arguments are based on Einstein's belief in the complete analogy between the thermodynamics of light quanta and of material particles and invoke considerations of adiabatic transformations as well as of dimensional analysis. These techniques were well-known to Einstein from earlier work on Wien's displacement law, Planck's radiation theory, and the specific heat of solids. We also investigate the possible role of Ehrenfest in the gestation of the theory.Comment: 57 pp

Proof of the Ergodic Theorem and the H-Theorem in Quantum Mechanics

It is shown how to resolve the apparent contradiction between the macroscopic approach of phase space and the validity of the uncertainty relations. The main notions of statistical mechanics are re-interpreted in a quantum-mechanical way, the ergodic theorem and the H-theorem are formulated and proven (without "assumptions of disorder"), followed by a discussion of the physical meaning of the mathematical conditions characterizing their domain of validity.Comment: English translation by Roderich Tumulka of J. von Neumann: Beweis des Ergodensatzes und des H-Theorems. 41 pages LaTeX, no figures; v2: typos corrected. See also the accompanying commentary by S. Goldstein, J. L. Lebowitz, R. Tumulka, N. Zanghi, arXiv:1003.212

Microscopic chaos from Brownian motion?

A recent experiment on Brownian motion has been interpreted to exhibit direct evidence for microscopic chaos. In this note we demonstrate that virtually identical results can be obtained numerically using a manifestly microscopically nonchaotic system.Comment: 3 pages, 1 figure, Comment on P. Gaspard et al, Nature vol 394, 865 (1998); rewritten in a more popular styl

Is the number of Photons a Classical Invariant?

We describe an apparent puzzle in classical electrodynamics and its resolution. It is concerned with the Lorentz invariance of the classical analog of the number of photons.Comment: Revised version, 3 figure

Circular Orbits in Einstein-Gauss-Bonnet Gravity

The stability under radial and vertical perturbations of circular orbits associated to particles orbiting a spherically symmetric center of attraction is study in the context of the n-dimensional: Newtonian theory of gravitation, Einstein's general relativity, and Einstein-Gauss-Bonnet theory of gravitation. The presence of a cosmological constant is also considered. We find that this constant as well as the Gauss-Bonnet coupling constant are crucial to have stability for $n>4$.Comment: 11 pages, 4 figs, RevTex, Phys. Rev. D, in pres

Geometry, topology and dynamics of geodesic flows on noncompact polygonal surfaces

We establish the background for the study of geodesics on noncompact polygonal surfaces. For illustration, we study the recurrence of geodesics on $Z$-periodic polygonal surfaces. We prove, in particular, that almost all geodesics on a topologically typical $Z$-periodic surface with boundary are recurrent.Comment: 34 pages, 13 figures. To be published in V. V. Kozlov's Festschrif

Analysis of return distributions in the coherent noise model

The return distributions of the coherent noise model are studied for the system size independent case. It is shown that, in this case, these distributions are in the shape of q-Gaussians, which are the standard distributions obtained in nonextensive statistical mechanics. Moreover, an exact relation connecting the exponent $\tau$ of avalanche size distribution and the q value of appropriate q-Gaussian has been obtained as q=(tau+2)/tau. Making use of this relation one can easily determine the q parameter values of the appropriate q-Gaussians a priori from one of the well-known exponents of the system. Since the coherent noise model has the advantage of producing different tau values by varying a model parameter \sigma, clear numerical evidences on the validity of the proposed relation have been achieved for different cases. Finally, the effect of the system size has also been analysed and an analytical expression has been proposed, which is corroborated by the numerical results.Comment: 14 pages, 3 fig

Adiabatic quantization of Andreev levels

We identify the time $T$ between Andreev reflections as a classical adiabatic invariant in a ballistic chaotic cavity (Lyapunov exponent $\lambda$), coupled to a superconductor by an $N$-mode point contact. Quantization of the adiabatically invariant torus in phase space gives a discrete set of periods $T_{n}$, which in turn generate a ladder of excited states $\epsilon_{nm}=(m+1/2)\pi\hbar/T_{n}$. The largest quantized period is the Ehrenfest time $T_{0}=\lambda^{-1}\ln N$. Projection of the invariant torus onto the coordinate plane shows that the wave functions inside the cavity are squeezed to a transverse dimension $W/\sqrt{N}$, much below the width $W$ of the point contact.Comment: 4 pages, 3 figure