The adsorption structure of furan on Pd(1 1 1)

The structure of molecular furan, C4H4O, on Pd(1 1 1) has been investigated by O K-edge near-edge X-ray absorption fine structure (NEXAFS) and C 1s scanned-energy mode photoelectron diffraction (PhD). NEXAFS shows the molecule to be adsorbed with the molecular plane close to parallel to the surface, a conclusion confirmed by the PhD analysis. Chemical-state specific C 1s PhD data were obtained for the two inequivalent C atoms in the furan, the α-C atoms adjacent to the O atom, and the β-C atoms bonded only to C atoms, but only the PhD modulations for the α-C emitters were of sufficiently large amplitude for detailed evaluation using multiple scattering calculations. This analysis shows the α-C atoms to be located approximately 0.6 Å off-atop surface Pd atoms with an associated C–Pd bondlength of 2.13 ± 0.03 Å. Two alternative local geometries consistent with the data place the O atom in off-atop or near-hollow locations, and for each of these local structures there are two equally-possible registries relative to the fcc and hcp hollow sites. The results are in good agreement with earlier density functional theory calculations which indicate that the fcc and hcp registries are equally probable, but the PhD results fail to distinguish the two distinct local bonding geometries

A structural study of a C3H3 species coadsorbed with CO on Pd(1 1 1)

The combination of chemical-state-specific C 1s scanned-energy mode photoelectron diffraction (PhD) and O K-edge near-edge X-ray absorption fine structure (NEXAFS) has been used to determine the local adsorption geometry of the coadsorbed C3H3 and CO species formed on Pd(1 1 1) by dissociation of molecular furan. CO is found to adopt the same geometry as in the Pd(1 1 1)c(4 × 2)-CO phase, occupying the two inequivalent three-fold coordinated hollow sites with the C–O axis perpendicular to the surface. C3H3 is found to lie with its molecular plane almost parallel to the surface, most probably with the two ‘outer’ C atoms in equivalent off-atop sites, although the PhD analysis formally fails to distinguish between two distinct local adsorption sites

Improved Deposition and Performance of a Microencapsulated Sex Pheromone Formulation for Codling Moth (Lepidoptera: Tortricidae) with a Low Volume Application

Experiments were conducted to evaluate the deposition pattern and effectiveness in disrupting male orientation to virgin female-baited traps of a microencapsulated sex pheromone formulation for codling moth, Cydia pomonella (L.) in apple, Malus domestica Bordhausen. The efficacy of two application techniques was evaluated in field trials with the microencapsulated formulation Checkmate® CM-F: a high volume (926 liters per ha) application with an air blast sprayer and a low volume (46 liters per ha) application with a custom-built vertical boom sprayer. These treatments were compared to an unsprayed control and a control treatment where the formulation was applied directly on the ground within the plots. Disruption of virgin female-baited traps was significantly greater in the low volume versus the air blast application and versus the two types of control plots. Levels of disruption in the air blast-sprayed plots were not different from untreated plots or in plots where the sprayable sex pheromone was applied directly on the ground. A significant increase in the proportion of traps catching moths occurred in week 4. A significant interaction occurred among the effects of spray method, tree canopy position, and leaf surface on microcapsule deposition. This interaction was likely due to the low rate of deposition of microcapsules on the undersides of leaves in the lower canopy with the low volume sprayer. The low volume sprayer deposited significantly more microcapsules in the upper canopy than the air blast sprayer. Significantly more microcapsules were deposited on the underside versus the top of leaves in the upper canopy with the air blast but not with the low volume sprayer

CSM Testbed Development and Large-Scale Structural Applications

A research activity called Computational Structural Mechanics (CSM) conducted at the NASA Langley Research Center is described. This activity is developing advanced structural analysis and computational methods that exploit high-performance computers. Methods are developed in the framework of the CSM Testbed software system and applied to representative complex structural analysis problems from the aerospace industry. An overview of the CSM Testbed methods development environment is presented and some new numerical methods developed on a CRAY-2 are described. Selected application studies performed on the NAS CRAY-2 are also summarized

Video data modulation study, volume 1 Final report

Video data modulation technique

Dynamics of a two-level system strongly coupled to a high-frequency quantum oscillator

Recent experiments on quantum behavior in microfabricated solid-state systems suggest tantalizing connections to quantum optics. Several of these experiments address the prototypical problem of cavity quantum electrodynamics: a two-level system coupled to a quantum harmonic oscillator. Such devices may allow the exploration of parameter regimes outside the near-resonance and weak-coupling assumptions of the ubiquitous rotating-wave approximation (RWA), necessitating other theoretical approaches. One such approach is an adiabatic approximation in the limit that the oscillator frequency is much larger than the characteristic frequency of the two-level system. A derivation of the approximation is presented and the time evolution of the two-level-system occupation probability is calculated using both thermal- and coherent-state initial conditions for the oscillator. Closed-form evaluation of the time evolution in the weak-coupling limit provides insight into the differences between the thermal- and coherent-state models. Finally, potential experimental observations in solid-state systems, particularly the Cooper-pair box--nanomechanical resonator system, are discussed and found to be promising.Comment: 16 pages, 11 figures; revised abstract; some text revisions; added two figures and combined others; added references. Submitted to Phys. Rev.

K-ATP channel gene expression is induced by urocortin and mediates its cardioprotective effect

Background-Urocortin is a novel cardioprotective agent that can protect cardiac myocytes from the damaging effects of ischemia/reperfusion both in culture and in the intact heart and is effective when given at reperfusion.Methods and Results-We have analyzed global changes in gone expression in cardiac myocytes after urocortin treatment using gene chip technology. We report that urocortin specifically induces enhanced expression of the Kir 6.1 cardiac potassium channel subunit. On the basis of this finding, we showed that the cardioprotective effect of urocortin both in isolated cardiac cells and in the intact heart is specifically blocked by both generalized and mitochondrial-specific K-ATP channel blockers, whereas the cardioprotective effect of cardiotrophin-1 is unaffected. Conversely, inhibiting the Kir 6.1 channel subunit greatly enhances cardiac cell death after ischemia.Conclusions-This is, to our knowledge, the first report of the altered expression of a K-ATP. channel subunit induced by a cardioprotective agent and demonstrates that K-ATP, channel opening is essential for the effect of this novel cardioprotective agent

Energy Relaxation at a Hot-Electron Vortex Instability

At high dissipation levels, vortex motion in a superconducting film has been observed to become unstable at a certain critical vortex velocity v*. At substrate temperatures substantially below Tc, the observed behavior can be accounted for by a model in which the electrons reach an elevated temperature relative to the phonons and the substrate. Here we examine the underlying assumptions concerning energy flow and relaxation times in this model. A calculation of the rate of energy transfer from the electron gas to the lattice finds that at the instability, the electronic temperature reaches a very high value close to the critical temperature. Our calculated energy relaxation times are consistent with those deduced from the experiments. We also estimate the phonon mean free path and assess its effect on the flow of energy in the film.Comment: 8 pages, 7 figure