Comparative techno-economic analysis of ORC and gasification for bioenergy applications

The use of biomass for decentralized energy production has undergone a significant development the last years. The fact that this fuel is CO(2)-free provides many advantages in European and world aims for sustainable energy sources. Biomass trigeneration is a relatively new concept, which has the potential to improve the bioenergy economics for areas with warm climate, for which traditional biomass cogeneration was unfeasible. This concept can be applied with various energy conversion technologies, two of which are investigated in this paper: ORC and gasification. Both technologies are applied for a specific case study. The technological and financial comparison of the two technologies shows that gasification offers improved yield for the investment, mainly due to the higher electrical efficiency factor. However, attention should be placed to the increased investment risk of gasification projects, which could be an aversive factor for some investors. (C) 2008 Elsevier Ltd. All rights reserved

Improved droplet breakup models for spray applications

The current study examines the performance of two zero-dimensional (0D) aerodynamically-induced breakup models, utilized for the prediction of droplet deformation during the breakup process in the bag, multi-mode and sheet-thinning regimes. The first model investigated is an improved version of the widely used Taylor analogy breakup (TAB) model, which compared to other models has the advantage of having an analytic solution. Following, a model based on the modified Navier–Stokes (M-NS) is examined. The parameters of both models are estimated based upon published experimental data for the bag breakup regime and CFD simulations with Diesel droplets performed as part of this work for the multi-mode and sheet-thinning regimes, for which there is a scarcity of experimental data. Both models show good accuracy in the prediction of the temporal evolution of droplet deformation in the three breakup regimes, compared to the experimental data and the CFD simulations. It is found that the best performance of the two is achieved with the M-NS model. Finally, a unified secondary breakup model is presented, which incorporates various models found in the literature, i.e. TAB, non-linear TAB (NLTAB), droplet deformation and breakup (DDB) and M-NS, into one equation using adjustable coefficients, allowing to switch among the different models

Biomass fast pyrolysis energy balance of a 1kg/h test rig

The present paper offers a methodological approach towards the estimation and definition of enthalpies constituting an energy balance around a fast pyrolysis experiment conducted in a laboratory scale fluid bed with a capacity of 1 kg/ h. Pure N2 was used as fluidization medium at atmospheric pressure and the operating temperature (∼500°C) was adjusted with electrical resistors. The biomass feedstock type that was used was beech wood. An effort was made to achieve a satisfying 92.5% retrieval of products (dry basis mass balance) with the differences mainly attributed to loss of some bio-oil constituents into the quenching medium, ISOPAR™. The chemical enthalpy recovery for bio-oil, char and permanent gases is calculated 64.6%, 14.5% and 7.1%, respectively. All the energy losses from the experimental unit into the environment, namely the pyrolyser, cooling unit etc. are discussed and compared to the heat of fast pyrolysis that was calculated at 1123.5 kJ per kg of beech wood. This only represents 2.4% of the biomass total enthalpy or 6.5% its HHV basis. For the estimation of some important thermo-physical properties such as heat capacity and density, it was found that using data based on the identified compounds from the GC/MS analysis is very close to the reference values despite the small fraction of the bio-oil components detected. The methodology and results can help as a starting point for the proper design of fast pyrolysis experiments, pilot and/or industrial scale plants

Numerical investigation of the aerodynamic breakup of droplets in tandem

The present work examines the aerodynamic breakup of four liquid droplets in tandem formation at Diesel engine conditions using the Volume of Fluid (VOF) method. The examined Weber (We) numbers range from 15 up to 64 and the non-dimensional distances between the droplet centres (L/D0) vary from 1.25 up to 20. Focus is given on the breakup process of the third droplet of the row, which is regarded as a “representative chain droplet”; its development is compared against that of an isolated droplet at the same flow conditions. It is found that for small distances and depending on the We number, the obtained shapes and breakup modes between the droplets are different, with the representative chain droplet experiencing a new breakup mode in the multi-mode regime, termed as “shuttlecock”. This is characterized by an oblique peripheral stretching of the droplet caused by the acting of pressure forces at an off-centre region. Moreover, the drag coefficient and liquid surface area of the representative chain droplet are lower than the corresponding ones of the isolated droplet, while the breakup initiation time is longer and the minimum We number required for breakup (critical We) is higher; correlations are provided to quantify the effect of droplet distance on the aforementioned quantities. Generally, the droplet proximity becomes important for L/D0< 9. Finally, the predicted drag coefficient is utilised in a simplified 0-D model that is capable of estimating the temporal evolution of droplet velocity of the representative chain droplet

High-throughput screening of metal-porphyrin-like graphenes for selective capture of carbon dioxide

Nanostructured materials, such as zeolites and metal-organic frameworks, have been considered to capture CO2. However, their application has been limited largely because they exhibit poor selectivity for flue gases and low capture capacity under low pressures. We perform a high-throughput screening for selective CO2 capture from flue gases by using first principles thermodynamics. We find that elements with empty d orbitals selectively attract CO2 from gaseous mixtures under low CO2 pressures (similar to 10(-3) bar) at 300 K and release it at similar to 450 K. CO2 binding to elements involves hybridization of the metal d orbitals with the CO2 pi orbitals and CO2-transition metal complexes were observed in experiments. This result allows us to perform high-throughput screening to discover novel promising CO2 capture materials with empty d orbitals (e.g., Sc- or V-porphyrin-like graphene) and predict their capture performance under various conditions. Moreover, these findings provide physical insights into selective CO2 capture and open a new path to explore CO2 capture materialsopen

Biomass combustion with ORC for decentralized bioenergy applications : a techno-economic approach

The use of biomass for decentralised energy production has undergone a significant development the last years. The fact that this fuel is CO2-free provides many advantages in European and world aims for sustainable energy sources. Biomass trigeneration is a relatively new concept, which has the potential to improve the bioenergy economics for areas with warm climate, for which traditional biomass cogeneration was unfeasible. This concept can be applied with various energy conversion technologies, among others the biomass combustion coupled with the Organic Rankine Cycle process. The fact that ORC is a proven technology for waste heat applications provides advantages for its coupling with combustion. This combination is examined in the present study, in terms of the financial yield of an ORC tri-generation project. The concept of ORC biomass trigeneration is applied for a case study in Greece and interesting results regarding the cost and the profitability of the project are presented