On-going development of five geochemical monitoring technologies for onshore CCS

A critical aspect of Carbon Capture and Storage (CCS) will be the ability to adequately monitor the injection site, both to ensure public and environmental safety and for “carbon credit auditing”. In the unlikely event of a leakage in the near-surface environment, the study of natural CO2 emanations in volcanic and geothermal environments have shown that the gas will tend to migrate along the path of least resistance and create spatially restricted “hotspot” leaks at the ground surface that can be challenging to find and quantify. For this reason, innovative technologies are required to improve our ability to detect, locate and characterize such features. To address this need our group is developing geochemical monitoring tools that confront the significant challenges associated with spatial, analytical and temporal resolution and sensitivity. Here we describe on-going work focused on increasing the Technology Readiness Level (TRL) of five prototypes and concepts developed by the Tectonics and Fluid Chemistry Lab (TFCL) at Sapienza University of Rome: the GasPro, Mapper, Multipla, Well-Star, and SWiM systems

Mapping and quantifying CO2 leakage using the Ground CO2 Mapper

The standard method for mapping and quantifying CO2 leakage flux from the ground surface to the atmosphere involves performing numerous point flux measurements using the accumulation chamber technique and then applying geostatistical interpolation to infer spatial distribution and estimate total mass transfer. Monte Carlo simulations using the program MCFlux have recently demonstrated, however, that uncertainty in the resultant estimate can be large if the chosen sample spacing is insufficient to capture the spatial complexity and size distribution of the leakage anomalies. In an effort to reduce this uncertainty we have developed a new tool, called the Ground CO2 Mapper, that rapidly measures the concentration of CO2 at the ground surface as a proxy for flux. Recently published results have illustrated the capabilities of the Mapper in terms of sensitivity and spatial resolution, as well as possible influencing parameters such as wind strength. The present work examines the potential of combining Mapper results with point flux measurements (using multivariate geostatistics) to improve data interpretation, with the MCFlux program being used once again to assess uncertainty in the final estimates

On-going and future research at the Sulcis site in Sardinia, Italy. Characterization and experimentation at a possible future CCS pilot

National Italian funding has recently been allocated for the construction of a 350 MWe coal-fired power plant / CCS demonstration plant in the Sulcis area of SW Sardinia, Italy. In addition, the recently approved EC-funded ENOS project (ENabling Onshore CO2 Storage in Europe) will use the Sulcis site as one of its main field research laboratories. Site characterization is already ongoing, and work has begun to design gas injection experiments at 100-200 m depth in a fault. This article gives an overview of results to date and plans for the future from the Sapienza University of Rome research group

The Ground CO2 Mapper. An innovative tool for the rapid and precise mapping of CO2 leakage distribution

The recently developed Ground CO2 Mapper (“Mapper” for short) is an inexpensive, light, robust, and low power consuming tool for determining the distribution of CO2 at the soil-atmosphere contact as an indicator of CO2 leakage. The basic premise behind the Mapper is that the contact between the ground surface and the atmosphere represents an interval where CO2 leaking from the subsurface can accumulate in anomalous concentrations due to two mechanisms, the higher density of CO2 with respect to air and the tendency of wind speed (and thus mixing) to approach zero near the ground surface due to frictional drag. Because of its measurement target and the tool’s very rapid response time, Mapper surveys can be conducted very quickly at a high sampling density, yielding accurate maps of CO2 spot anomalies. The unit can be used by anyone and deployed within only 5-10 minutes after sensor and GPS signal warm-up. Here we describe the Mapper and present results from a site of natural diffuse CO2 degassing in central Italy

Spatial-temporal water column monitoring using multiple, low-cost GasPro-pCO2 sensors: implications for monitoring, modelling, and potential impact

Monitoring of the water column in the vicinity of offshore Carbon Capture and Storage (CCS) sites is needed to ensure site integrity and to protect the surrounding marine ecosystem. In this regard, the use of continuous, autonomous systems is considered greatly advantageous due to the costs and limitations of periodic, ship-based sampling campaigns. While various geochemical monitoring tools have been developed their elevated costs and complexities mean that typically only one unit can be deployed at a time, yielding single point temporal data but no spatial data. To address this the authors have developed low-cost pCO2 sensors (GasPro-pCO2) that are small, robust, stable, and which have a low power consumption, characteristics which allow for the deployment of numerous units to monitor the spatial-temporal distribution of pCO2, temperature, and water pressure in surface water environments. The present article details the results of three field deployments at the natural, CO2-leaking site near Panarea, Island. While the first consisted of 6 probes placed on the sea floor for a 2.5 month period, the other two involved the deployment of 20 GasPro units along a transect through the water column in the vicinity of active CO2 seeps over 2 – 4 days. Results show both transport and mixing processes and highlight the dynamic nature of the leakage-induced marine geochemical anomalies. Implications for monitoring programs as well as potential impacts are discussed