2,841 research outputs found
Carrier generation and transport in bulk heterojunction films processed with 1,8-octanedithiol as a processing additive
Improved performance of polymer-based solar cells based on poly[2,6-(4,4-bis-(2-ethylhexyl)- 4H -cyclopenta[2,1-b;3,4- b???] dithiophene)-alt-4,7-(2,1,3-benzo-thiadiazole)] PCPDTBT has been obtained by using 1,8-octanedithiol (ODT) as a processing additive in the polymer solution used to spin cast the bulk heterojunction films. Although ultrafast spectroscopy studies indicate that the carrier losses are reduced in the films processed with ODT [similar to the reduced carrier losses after thermal annealing of bulk heterojunction (BHJ) materials made from P3HT:PCBM], the magnitude of the reduction is not sufficient to explain the observed factor of 2 increase in the power conversion efficiency. From the analysis of carrier transport in field effect transistors, we find increased electron mobility in the PCPDTBT: PC70 BM composites when fabricated with ODT, which is indicative of enhanced connectivity of PC70 BM networks. The improved electron mobility appears to be the primary origin of the improved power conversion efficiency in BHJ films.open453
The quantization of the chiral Schwinger model based on the BFT-BFV formalism II
We apply an improved version of Batalin-Fradkin-Tyutin (BFT) Hamiltonian
method to the a=1 chiral Schwinger Model, which is much more nontrivial than
the a>1.\delta\xi$ in the measure. As a result, we explicitly
obtain the fully gauge invariant partition function, which includes a new type
of Wess-Zumino (WZ) term irrelevant to the gauge symmetry as well as usual WZ
action.Comment: 17 pages, To be published in J. Phys.
Supersymmetric quantum mechanics with nonlocal potentials
We consider supersymmetric quantum mechanical models with both local and
nonlocal potentials. We present a nonlocal deformation of exactly solvable
local models. Its energy eigenfunctions and eigenvalues are determined exactly.
We observe that both our model Hamiltonian and its supersymmetric partner may
have normalizable zero-energy ground states, in contrast to local models with
nonperiodic or periodic potentials.Comment: 4 pages, REVTeX, Minor revisions for clarificatio
Frustrated two-dimensional Josephson junction array near incommensurability
To study the properties of frustrated two-dimensional Josephson junction
arrays near incommensurability, we examine the current-voltage characteristics
of a square proximity-coupled Josephson junction array at a sequence of
frustrations f=3/8, 8/21, 0.382 , 2/5, and 5/12.
Detailed scaling analyses of the current-voltage characteristics reveal
approximately universal scaling behaviors for f=3/8, 8/21, 0.382, and 2/5. The
approximately universal scaling behaviors and high superconducting transition
temperatures indicate that both the nature of the superconducting transition
and the vortex configuration near the transition at the high-order rational
frustrations f=3/8, 8/21, and 0.382 are similar to those at the nearby simple
frustration f=2/5. This finding suggests that the behaviors of Josephson
junction arrays in the wide range of frustrations might be understood from
those of a few simple rational frustrations.Comment: RevTex4, 4 pages, 4 eps figures, to appear in Phys. Rev.
On the Foundation of the Relativistic Dynamics with the Tachyon
The theoretical foundation of the object moving faster than light in vacuum
({\it tachyon}) is still missing or incomplete. Here we present the classical
foundation of the relativistic dynamics including the tachyon. An anomalous
sign-factor extracted from the transformation of
under the Lorentz transformation, which has been always missed in the usual
formulation of the tachyon, has a crucial role in the dynamics of the tachyon.
Due to this factor the mass of the tachyon transforms in the unusual way
although the energy and momentum, which are defined as the conserved quantities
in all uniformly moving systems, transform in the usual way as in the case of
the object moving slower than light ({\it bradyon}). We show that this result
can be also obtained from the least action approach. On the other hand, we show
that the ambiguities for the description of the dynamics for the object moving
with the velocity of light ({\it luxon}) can be consistently removed only by
introducing a new dynamical variable. Furthermore, by using the fundamental
definition of the momentum and energy we show that the zero-point energy for
any kind of the objects, {\it i.e.}, the tachyon, bradyon, and luxon, which has
been known as the undetermined constant, should satisfy some constraints for
consistency, and we note that this is essentially another novel relativistic
effect. Finally, we remark about the several unsolved problems.Comment: 39 pages, latex, 15 figures avaliable upon reques
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Photoreversible interconversion of a phytochrome photosensory module in the crystalline state.
A major barrier to defining the structural intermediates that arise during the reversible photointerconversion of phytochromes between their biologically inactive and active states has been the lack of crystals that faithfully undergo this transition within the crystal lattice. Here, we describe a crystalline form of the cyclic GMP phosphodiesterases/adenylyl cyclase/FhlA (GAF) domain from the cyanobacteriochrome PixJ in Thermosynechococcus elongatus assembled with phycocyanobilin that permits reversible photoconversion between the blue light-absorbing Pb and green light-absorbing Pg states, as well as thermal reversion of Pg back to Pb. The X-ray crystallographic structure of Pb matches previous models, including autocatalytic conversion of phycocyanobilin to phycoviolobilin upon binding and its tandem thioether linkage to the GAF domain. Cryocrystallography at 150 K, which compared diffraction data from a single crystal as Pb or after irradiation with blue light, detected photoconversion product(s) based on Fobs - Fobs difference maps that were consistent with rotation of the bonds connecting pyrrole rings C and D. Further spectroscopic analyses showed that phycoviolobilin is susceptible to X-ray radiation damage, especially as Pg, during single-crystal X-ray diffraction analyses, which could complicate fine mapping of the various intermediate states. Fortunately, we found that PixJ crystals are amenable to serial femtosecond crystallography (SFX) analyses using X-ray free-electron lasers (XFELs). As proof of principle, we solved by room temperature SFX the GAF domain structure of Pb to 1.55-Å resolution, which was strongly congruent with synchrotron-based models. Analysis of these crystals by SFX should now enable structural characterization of the early events that drive phytochrome photoconversion
Critical Behavior of Frustrated Josephson Junction Arrays with Bond Disorder
The scaling behavior of the current-voltage () characteristics of a
two-dimensional proximity-coupled Josephson junction array (JJA) with quenched
bond disorder was investigated for frustrations , 1/3, 2/5, and 1/2. For
all these frustrations including 1/5 and 2/5 where a strongly first-order phase
transition is expected in the absence of disorder, the characteristics
exhibited a good scaling behavior. The critical exponent indicates that
bond disorder may drive the phase transitions of frustrated JJA's to be
continuous but not into the Ising universality class, contrary to what was
observed in Monte Carlo simulations. The dynamic critical exponent for
JJA's was found to be only 0.60 - 0.77.Comment: RevTeX4, 4 pages, 4 figures, the manuscript is replaced with the
published versio
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Investigating the impact of poverty on colonization and infection with drug-resistant organisms in humans: a systematic review
Background
Poverty increases the risk of contracting infectious diseases and therefore exposure to antibiotics. Yet there is lacking evidence on the relationship between income and non-income dimensions of poverty and antimicrobial resistance. Investigating such relationship would strengthen antimicrobial stewardship interventions.
Methods
A systematic review was conducted following Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines. PubMed, Ovid, MEDLINE, EMBASE, Scopus, CINAHL, PsychINFO, EBSCO, HMIC, and Web of Science databases were searched in October 2016. Prospective and retrospective studies reporting on income or non-income dimensions of poverty and their influence on colonisation or infection with antimicrobial-resistant organisms were retrieved. Study quality was assessed with the Integrated quality criteria for review of multiple study designs (ICROMS) tool.
Results
Nineteen articles were reviewed. Crowding and homelessness were associated with antimicrobial resistance in community and hospital patients. In high-income countries, low income was associated with Streptococcus pneumoniae and Acinetobacter baumannii resistance and a seven-fold higher infection rate. In low-income countries the findings on this relation were contradictory. Lack of education was linked to resistant S. pneumoniae and Escherichia coli. Two papers explored the relation between water and sanitation and antimicrobial resistance in low-income settings.
Conclusions
Despite methodological limitations, the results suggest that addressing social determinants of poverty worldwide remains a crucial yet neglected step towards preventing antimicrobial resistance
Barriers and facilitators of evidence-based management of patients with bacterial infections among general dental practitioners:a theory-informed interview study
Background: General dental practitioners (GDPs) regularly prescribe antibiotics to manage dental infections although most infections can be treated successfully by local measures. Published guidance to support GDPs to make appropriate prescribing decisions exists but there continues to be wide variation in dental antibiotic prescribing. An interview study was conducted as part of the Reducing Antibiotic Prescribing in Dentistry (RAPiD) trial to understand the barriers and facilitators of using local measures instead of prescribing antibiotics to manage bacterial infections. Methods: Thirty semi-structured one-to-one telephone interviews were conducted using the Theoretical Domains Framework (TDF). Responses were coded into domains of the TDF and sub-themes. Priority domains (high frequency: ≥50 % interviewees discussed) relevant to behaviour change were identified as targets for future intervention efforts and mapped onto 'intervention functions' of the Behaviour Change Wheel system. Results: Five domains (behavioural regulation, social influences, reinforcement, environmental context and resources, and beliefs about consequences) with seven sub-themes were identified as targets for future intervention. All participants had knowledge about the evidence-based management of bacterial infections, but they reported difficulties in following this due to patient factors and time management. Lack of time was found to significantly influence their decision processes with regard to performing local measures. Beliefs about their capabilities to overcome patient influence, beliefs that performing local measures would impact on subsequent appointment times as well as there being no incentives for performing local measures were also featured. Though no knowledge or basic skills issues were identified, the participants suggested some continuous professional development programmes (e.g. time management, an overview of published guidance) to address some of the barriers. The domain results suggest a number of intervention functions through which future interventions could change GDPs' antibiotic prescribing for bacterial infections: imparting skills through training, providing an example for GDPs to imitate (i.e. modelling) or creating the expectation of a reward (i.e. incentivisation). Conclusions: This is the first theoretically informed study to identify barriers and facilitators of evidence-based management of patients with bacterial infections among GDPs. A pragmatic approach is needed to address the modifiable barriers in future interventions intended to change dentists' inappropriate prescribing behaviour.</p
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