Site-specific oxidation in peptides and proteins by metal-catalyzed oxidation reactions

Ph. D. University of Kansas, Chemistry 199

Eclipsing high-mass binaries I. Light curves and system parameters for CPD-518946, PISMIS24-1 and HD319702

We present first results of a comprehensive photometric O-star survey performed with a robotic twin refractor at the Universit\"atssternwarte Bochum located near Cerro Armazones in Chile. For three high-mass stars, namely Pismis24-1, CPD-518946 and HD319702, we determined the period through the Lafler-Kinman algorithm and model the light curves within the framework of the Roche geometry. For Pismis24-1, a previously known eclipsing binary, we provide first light curves and determined a photometric period of 2.36 days together with an orbital inclination of 61.8 degrees. The best-fitting model solution to the light curves suggest a detached configuration. With a primary temperature of T1 = 42520K we obtain the temperature of the secondary component as T2 = 41500K. CPD-518946 is another known eclipsing binary for which we present a revised photometric period of 1.96 days with an orbital inclination of 58.4 degrees. The system has likely a semi-detached configuration and a mass ratio q = M1/M2 = 2.8. If we adopt a primary temperature of T1 = 34550K we obtain T2 = 21500K for the secondary component. HD319702 is a newly discovered eclipsing binary member of the young open cluster NGC6334. The system shows well-defined eclipses favouring a detached configuration with a period of 2.0 days and an orbital inclination of 67.5 degrees. Combining our photometric result with the primary spectral type O8 III(f) (T1 = 34000K) we derive a temperature of T2 = 25200K for the secondary component.Comment: 7 pages, 4 figures, accepted for publication in Astronomy and Astrophysic

Dust reverberation-mapping of the Seyfert 1 galaxy WPVS48

Using robotic telescopes of the Universitatssternwarte Bochum near Cerro Armazones in Chile, we monitored the z=0.0377 Seyfert 1 galaxy WPVS48 (2MASX J09594263-3112581) in the optical (B and R) and near-infrared (NIR, J and Ks) with a cadence of two days. The light curves show unprecedented variability details. The NIR variation features of WPVS48 are consistent with the corresponding optical variations, but the features appear sharper in the NIR than in the optical, suggesting that the optical photons undergo multiple scatterings. The J and Ks emission, tracing the hot (1600 K) dust echo, lags the B and R variations by on average 64 +/- 4 days and 71 +/- 5 days, respectively (restframe). WPVS48 lies on the known tau-M_V relationship. However, the observed lag is about three times shorter than expected from the dust sublimation radius r_sub inferred from the optical-UV luminosity, and explanations for this common discrepancy are searched for. The sharp NIR echos argue for a face-on torus geometry and allow us to put forward two potential scenarios: 1) as previously proposed, in the equatorial plane of the accretion disk the inner region of the torus is flattened and may come closer to the accretion disk. 2) The dust torus with inner radius r_sub is geometrically and optically thick, so that the observer only sees the facing rim of the torus wall, which lies closer to the observer than the torus equatorial plane and therefore leads to an observed foreshortened lag. Both scenarios are able to explain the factor three discrepancy between tau and r_sub. Longer-wavelength dust reverberation data might enable one to distinguish between the scenarios.Comment: 4 pages, 6 figures, Published in Astronomy and Astrophysic

An eccentric companion at the edge of the brown dwarf desert orbiting the 2.4 Msun giant star HIP67537

We report the discovery of a substellar companion around the giant star HIP67537. Based on precision radial velocity measurements from CHIRON and FEROS high-resolution spectroscopic data, we derived the following orbital elements for HIP67537$\,b$: m$_b$sin$i$ = 11.1$^{+0.4}_{-1.1}$ M$_{\rm {\tiny jup}}$, $a$ = 4.9$^{+0.14}_{-0.13}$ AU and $e$ = 0.59$^{+0.05}_{-0.02}$. Considering random inclination angles, this object has $\gtrsim$ 65% probability to be above the theoretical deuterium-burning limit, thus it is one of the few known objects in the planet to brown-dwarf transition region. In addition, we analyzed the Hipparcos astrometric data of this star, from which we derived a minimum inclination angle for the companion of $\sim$ 2 deg. This value corresponds to an upper mass limit of $\sim$ 0.3 M$_\odot$, therefore the probability that HIP67537$\,b$ is stellar in nature is $\lesssim$ 7%. The large mass of the host star and the high orbital eccentricity makes HIP67537$\,b$ a very interesting and rare substellar object. This is the second candidate companion in the brown dwarf desert detected in the sample of intermediate-mass stars targeted by the EXPRESS radial velocity program, which corresponds to a detection fraction of $f$ = 1.6$^{+2.0}_{-0.5}$%. This value is larger than the fraction observed in solar-type stars, providing new observational evidence of an enhanced formation efficiency of massive substellar companions in massive disks. Finally, we speculate about different formation channels for this object.Comment: Accepted for publication to A&

K2-113b: A dense hot-Jupiter transiting a solar analogue

We present the discovery of K2-113b, a dense hot-Jupiter discovered using photometry from Campaign 8 of the Kepler-2 (K2) mission and high-resolution spectroscopic follow up obtained with the FEROS spectrograph. The planet orbits a $V=13.68$ solar analogue in a $P=5.81760^{+0.00003}_{-0.00003}$ day orbit, has a radius of $0.93^{+0.10}_{-0.07}R_J$ and a mass of $1.29^{+0.13}_{-0.14}M_J$. With a density of $1.97^{+0.60}_{-0.53}$ gr/cm$^3$, the planet is among the densest systems known having masses below 2 $M_J$ and $T_{eq} > 1000$, and is just above the temperature limit at which inflation mechanisms are believed to start being important. Based on its mass and radius, we estimate that K2-113b should have a heavy element content on the order of $\sim$ 110 $M_{\oplus}$ or greater.Comment: 8 pages, 7 figures. Accepted to MNRAS; added new photometry from newest version of EVEREST, which allows for a constrain on the secondary eclipse dept

Early Dust Formation and a Massive Progenitor for SN 2011ja?

SN 2011ja was a bright (I = -18.3) Type II supernova occurring in the nearby edge on spiral galaxy NGC 4945. Flat-topped and multi-peaked H-alpha and H-beta spectral emission lines appear between 64 - 84 days post-explosion, indicating interaction with a disc-like circumstellar medium inclined 30-45 degrees from edge-on. After day 84 an increase in the H- and K-band flux along with heavy attenuation of the red wing of the emission lines are strong indications of early dust formation, likely located in the cool dense shell created between the forward shock of the SN ejecta and the reverse shock created as the ejecta plows into the existing CSM. Radiative transfer modeling reveals both ~1.5 x 10^-4 Msun of pre-existing dust located ~ 10^16.7 cm away and ~ 5 x 10^-5 Msun of newly formed dust. Spectral observations after 1.5 years reveal the possibility that the fading SN is located within a young (3-6 Myr) massive stellar cluster, which when combined with tentative 56Ni mass estimates of 0.2 Msun may indicate a massive (> 25 Msun) progenitor for SN 2011ja.Comment: 13 pages, 8 figures, submitted to MNRAS awaiting final referee repor