Polarized Infrared Emission by Polycyclic Aromatic Hydrocarbons resulting from Anisotropic Illumination

We study the polarized infrared emission by Polycyclic Aromatic Hydrocarbons (PAHs), when anisotropically illuminated by UV photons. PAH molecules are modeled as planar disks with in-plane and out-of-plane vibrational dipoles. As first pointed out by Leger (1988), infrared emission features resulting from in-plane and out-of-plane modes should have orthogonal polarization directions. We show analytically how the degree of polarization depends on the viewing geometry and the molecule's internal alignment between principal axis of inertia and angular momentum, which gets worse after photon absorption. Longer wavelength features, emitted after better internal alignment is recovered, should be more strongly polarized. The degree of polarization for uni-directional illumination (e.g., by a star) is larger than for diffuse illumination (e.g., by a disk galaxy), all else being equal. For PAHs in the Cold Neutral Medium, the predicted polarization is probably too small to distinguish from the contribution of linear dichroism by aligned foreground dust. The level of polarization predicted for PAH emission from the Orion Bar is only ~0.06% at 3.3 microns; Sellgren et al. (1988) report a much larger value, 0.86+-0.28%, which suggests that the smallest PAHs may have moderately suprathermal rotation rates. Future observations of (or upper limits on) the degree of polarization for the Orion Bar or for dust above edge-on galaxies (e.g., NGC 891 or M82) may constrain the internal alignment of emitting PAHs, thus providing clues to their rotational dynamics.Comment: 9 pages, 4 figures, 1 table, submitted to Ap

Direct evidence of dust growth in L183 from MIR light scattering

Theoretical arguments suggest that dust grains should grow in the dense cold parts of molecular clouds. Evidence of larger grains has so far been gathered in near/mid infrared extinction and millimeter observations. Interpreting the data is, however, aggravated by the complex interplay of density and dust properties (as well as temperature for thermal emission). We present new Spitzer data of L183 in bands that are sensitive and insensitive to PAHs. The visual extinction AV map derived in a former paper was fitted by a series of 3D Gaussian distributions. For different dust models, we calculate the scattered MIR radiation images of structures that agree agree with the AV map and compare them to the Spitzer data. The Spitzer data of L183 show emission in the 3.6 and 4.5 micron bands, while the 5.8 micron band shows slight absorption. The emission layer of stochastically heated particles should coincide with the layer of strongest scattering of optical interstellar radiation, which is seen as an outer surface on I band images different from the emission region seen in the Spitzer images. Moreover, PAH emission is expected to strongly increase from 4.5 to 5.8 micron, which is not seen. Hence, we interpret this emission to be MIR cloudshine. Scattered light modeling when assuming interstellar medium dust grains without growth does not reproduce flux measurable by Spitzer. In contrast, models with grains growing with density yield images with a flux and pattern comparable to the Spitzer images in the bands 3.6, 4.5, and 8.0 micron.Comment: 13 pages, 11 figures, accepted for publication in Astronomy and Astrophysic

The Carriers of the Interstellar Unidentified Infrared Emission Features: Aromatic or Aliphatic?

The unidentified infrared emission (UIE) features at 3.3, 6.2, 7.7, 8.6, and 11.3 micrometer, commonly attributed to polycyclic aromatic hydrocarbon (PAH) molecules, have been recently ascribed to coal- or kerogen-like organic nanoparticles with a mixed aromatic-aliphatic structure. However, we show in this Letter that this hypothesis is inconsistent with observations. We estimate the aliphatic fraction of the UIE carriers based on the observed intensities of the 3.4 and 6.85 micrometer emission features by attributing them exclusively to aliphatic C-H stretch and aliphatic C-H deformation vibrational modes, respectively. We derive the fraction of carbon atoms in aliphatic form to be <15%. We conclude that the UIE emitters are predominantly aromatic with aliphatic material at most a minor part of the UIE carriers. The PAH model is consistent with astronomical observations and PAHs dominate the strong UIE bands.Comment: 10 pages, 2 figures, accepted for publication in ApJ Letter

Structure of Stationary Photodissociation Fronts

The structure of stationary photodissociation fronts is revisited. H_2 self- shielding is discussed, including the effects of line overlap. We find that line overlap is important for N(H_2) > 10^{20} cm^{-2}. We compute multiline UV pumping models, and compare these with simple analytic approximations for the effects of self-shielding. The overall fluorescent efficiency of the photodissociation front is obtained for different ratios of chi/n_H (where chi characterizes the intensity of the incident UV) and different dust extinction laws. The dust optical depth tau_{pdr} to the point where 50% of the H is molecular is found to be a simple function of a dimensionless quantity phi_0 depending on chi/n_H, the rate coefficient for H_2 formation on grains, and the UV dust opacity. The fluorescent efficiency of the PDR also depends primarily on phi_0 for chi<3000 and n_H<10^4 cm^{-3}; for stronger radiation fields and higher densities radiative and collisional depopulation of vibrationally-excited levels interferes with the radiative cascade. The emission spectrum from the PDR is essentially independent of the color temperature $T_{color}$ of the incident UV for T_{color}>10^4K, but shows some sensitivity to the v-J distribution of newly-formed H_2. The 1-0S(1)/2-1S(1) and 2-1S(1)/6-4Q(1) intensity ratios, the ortho/para ratio, and the rotational temperature in the $v$=1 and $v$=2 levels are computed as functions of the temperature and density, for different values of chi and n_H. We apply our models to the reflection nebula NGC 2023. We are best able to reproduce the observations with models having chi=5000, n_H=10^5 cm^{-3}.Comment: 50 pages, 24 eps figures, uses aaspp4.sty . To appear in Ap.

Modeling Porous Dust Grains with Ballistic Aggregates. II. Light Scattering Properties

We study the light scattering properties of random ballistic aggregates constructed in Shen et al. (Paper I). Using the discrete-dipole-approximation, we compute the scattering phase function and linear polarization for random aggregates with various sizes and porosities, and with two different compositions: 100% silicate and 50% silicate-50% graphite. We investigate the dependence of light scattering properties on wavelength, cluster size and porosity using these aggregate models. We find that while the shape of the phase function depends mainly on the size parameter of the aggregates, the linear polarization depends on both the size parameter and the porosity of the aggregates, with increasing degree of polarization as the porosity increases. Contrary to previous studies, we argue that monomer size has negligible effects on the light scattering properties of ballistic aggregates, as long as the constituent monomer is smaller than the incident wavelength up to 2*pi*a_0/lambda\sim 1.6 where a_0 is the monomer radius. Previous claims for such monomer size effects are in fact the combined effects of size parameter and porosity. Finally, we present aggregate models that can reproduce the phase function and polarization of scattered light from the AU Mic debris disk and from cometary dust, including the negative polarization observed for comets at scattering angles 160<theta<180 deg. These aggregates have moderate porosities, P\sim 0.6, and are of sub-micron-size for the debris disk case, or micron-size for the comet case.Comment: Submitted to ApJ. Scattering properties can be downloaded at http://www.astro.princeton.edu/~draine/SDJ2009.html Target geometries are at http://www.astro.princeton.edu/~draine/agglom.htm