Solubility analysis of homologous series of amino acids and solvation energetics in aqueous potassium sulfate solution

In this study we estimated the solubilities of glycine, D,L-alanine, D,L-nor-valine and D,L-serine in aqueous mixtures of potassium sulfate (K2SO4) at 298.15 K using analytical ‘gravimetric method’. The experimental solubilities of homologous series of amino acids in aqueous K2SO4 mixture were discussed in terms of relative solubility, salting-in and salting-out effect by evaluating the influential constants. The effect of physicochemical and chemical factors on solubility were discussed briefly and correlated with the thermodynamics. Initially, the study of solvation energetics such as transfer Gibbs energies were evaluated based on the calculations from solubility data and relative stability of the experimental molecules was discussed under the experimental condition. © 2019 The Author(s

Influence of Zinc on the yield and nutrition of wet season rice (Oryza sativa) grown under aeric endoaquept

A field experiment on wet season kharif rice (Oryza sativa L.) cv IET 4094 was conducted during the year 2010- 11 and 2011-12 in an aeric endoaquept to study the influence of applied zinc on the growth, yield and nutrition of rice. The results show that the application of chelated zinc (Zn-EDTA) increased N, P, K and Zn concentration in dry matter and grains of rice. The highest amount of N, P,K and Zn in rice dry matter and grain have been found to be recorded in the treatment where the recommended levels of NPK (80:40:40) and chelated zinc in two splits (one at basal and the second one at grand tillering stage) were applied. The percent increase in the yield of grain (43.20) and straw (68.50) were also recorded highest in the treatment where Zn-EDTA was applied in two splits (0.5 kg/ha as basal + 0.5 kg/ha at grand tillering stage) over that of the control, while that of the same percent increase of the applied Zn–EDTA was highest in rice grain yield (18.40) over that of the corresponding highest level of ZnSO4.7H2O (20 kg/ha) at two splits

Evaluation of an Organic Package of Practice Towards Green Gram Cultivation and Assessment of its Effectiveness in Terms of Crop Sustainability and Soil Quality Development

Restoration of soil has been identified as the option; to ensure crop sustainability. However, as per Trophobiosis Theory of French Scientist F. Chaboussou, focus on development of healthy plants is necessary to abate pest and disease invasion so as to ensure sustained crop performance, even under unfavorable environmental conditions. The present study, in randomized block design with green gram as test crop; was undertaken in Krishi Vigyan Kendra (Howrah, West Bengal) to evaluate the effectiveness of Inhana Rational Farming (IRF) Technology towards crop yield and soil quality development under different sustainable models viz. organic cultivation, integrated soil with organic crop management and non- chemical crop management; as compared to conventional farming practice. Highest yield was recorded under organic (933 kg ha-1) followed by integrated (921 kg ha-1) and non- chemical plant management (902 kg ha-1). The results were well corroborated with the plant development index obtained under these treatments. Favorable trend of soil quality under sustainable models especially in terms of microbial properties indicated the role of quality compost towards speedy rejuvenation of soil dynamics. The study indicated that reduction of synthetic fertilizers and qualitative management of soil is essential to restrict yield decline. However, plant management shall be prerequisite for ensuring crop sustainability without any time lag and under the changing climatic patterns. In this respect the potential of IRF Technology has been well accounted

An Overview of Recommender Systems in the Internet of Things

The Internet Of Things (IoT) is an emerging paradigm that envisions a networked infrastructure enabling different types of devices to be interconnected. It creates different kinds of artifacts (e.g., services and applications) in various application domains such as health monitoring, sports monitoring, animal monitoring, enhanced retail services, and smart homes. Recommendation technologies can help to more easily identify relevant artifacts and thus will become one of the key technologies in future IoT solutions. In this article, we provide an overview of existing applications of recommendation technologies in the IoT context and present new recommendation techniques on the basis of real-world IoT scenarios

Electron beam-formed ferromagnetic defects on MoS2 surface along 1T phase transition

1 T phase incorporation into 2H-MoS2 via an optimal electron irradiation leads to induce a weak ferromagnetic state at room temperature, together with the improved transport property. In addition to the 1T-like defects, the electron irradiation on the cleaved MoS2 surface forms the concentric circletype defects that are caused by the 2 H/1 T phase transition and the vacancies of the nearby S atoms of the Mo atoms. The electron irradiation-reduced bandgap is promising in vanishing the Schottky barrier to attaining spintronics device. The simple method to control and improve the magnetic and electrical properties on the MoS2 surface provides suitable ways for the low-dimensional device applications.ope

Temperature induced crossing in the optical bandgap of mono and bilayer MoS2 on SiO2

Photoluminescence measurements in mono- and bilayer-MoS2 on SiO2 were undertaken to determine the thermal effect of the MoS2/SiO2 interface on the optical bandgap. The energy and intensity of the photoluminescence from monolayer MoS2 were lower and weaker than those from bilayer MoS2 at low temperatures, whilst the opposite was true at high temperatures above 200 K. Density functional theory calculations suggest that the observed optical bandgap crossover is caused by a weaker substrate coupling to the bilayer than to the monolayer