302 research outputs found
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Syntheses, crystal structure and magnetic properties of Tl9RETe6 (RE = Ce, Sm, Gd)
The three compounds Tl9RETe6 with RE = Ce, Sm, Gd were synthesized from the elements at 1020 K. Their isostructural crystal structures are ordered derivatives of the Tl5Te3 type with rare-earth metal and thallium occupying different Wyckoff positions. The structures can be understood as charge-ordered in accordance with the Zintl-Klemm concept: 9 Tl+ + RE3+ + 6 Te2-. DFT calculations for Tl9GdTe6, however, result in a low, but finite density of states at the Fermi level. Magnetic data confirm trivalent Gd, but indicate a small amount of Ce4+ in Tl9CeTe6; no indications for long-range magnetic order was found down to T = 2 K
Electrical resistivity and tunneling anomalies in CeCuAs2
The compound CeCuAs2 is found to exhibit negative temperature (T) coefficient
of electrical resistivity (rho) under ambient pressure conditions in the entire
T-range of investigation (45 mK to 300 K), even in the presence of high
magnetic fields. Preliminary tunneling spectroscopic measurements indicate the
existence of a psuedo-gap at least at low temperatures, thereby implying that
this compound could be classified as a Kondo semi-conductor, though rho(T)
interestingly is not found to be of an activated type.Comment: To appear in the proceedings of SCES200
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Spin-glass state and reversed magnetic anisotropy induced by Cr doping in the Kitaev magnet α-RuCl3
Magnetic properties of the substitution series Ru1-xCrxCl3 were investigated to determine the evolution from the anisotropic Kitaev magnet α-RuCl3 with Jeff=1/2 magnetic Ru3+ ions to the isotropic Heisenberg magnet CrCl3 with S=3/2 magnetic Cr3+ ions. Magnetization measurements on single crystals revealed a reversal of the magnetic anisotropy under doping, which we argue to arise from the competition between anisotropic Kitaev and off-diagonal interactions on the Ru-Ru links and approximately isotropic Cr-Ru and isotropic Cr-Cr interactions. In addition, combined magnetization, ac susceptibility, and specific-heat measurements clearly show the destabilization of the long-range magnetic order of α-RuCl3 in favor of a spin-glass state of Ru1-xCrxCl3 for a low doping of x≤0.1. The corresponding freezing temperature as a function of Cr content shows a broad maximum around x ≤ 0.45
Dilution of the magnetic lattice in the Kitaev candidate α-RuCl<sub>3</sub> by Rh<sup>3+</sup> doping
Dilution of the magnetic lattice in the Kitaev candidate -RuCl by Rh doping
Magnetic dilution of a well-established Kitaev candidate system is realized
in the substitutional RuRhCl series (). Optimized
syntheses protocols yield uniformly-doped single crystals and polycrystalline
powders that are isostructural to the parental -RuCl as per X-ray
diffraction. The Rh content is accurately determined by the quantitative
energy-dispersive X-ray spectroscopy technique with standards. We determine the
magnetic phase diagram of RuRhCl for in-plane magnetic fields
from magnetization and specific-heat measurements as a function of and
stacking periodicity, and identify the suppression of the magnetic order at towards a disordered phase, which does not show any clear
signature of freezing into a spin glass. Comparing with previous studies on the
substitution series RuIrCl, we propose that chemical pressure
would contribute to the suppression of magnetic order especially in
RuIrCl and that the zigzag magnetic ground state appears to be
relatively robust with respect to the dilution of the
Kitaev----Heisenberg magnetic lattice. We also discovered a slight
dependence of the magnetic properties on thermal cycling, which would be due to
an incomplete structural transition
Crystal Growth and Structure Determination of Pigment Orange 82
The crystal structure of the important industrial orangepigment PO82, major part of the BASF Colors amp; Effects productSicopal Orange K L 2430, was solved from combined X ray singlecrystal, X ray and neutron powder diffraction,119Sn Mössbauer spec troscopy, transmission electron microscopy, electron diffraction, andchemical analyses. The structure contains Keggin type clusters com posed of four [M3O13] trimers consisting each of three MO6 octahedra that share edges and one common oxygen atom connecting the trimersto the central ZnO4tetrahedron. The octahedrally coordinated metalatom position is mixed occupied by Ti4 ,Sn4 , and Zn2 . AdjacentKeggin clusters share vertices and are further interconnected to fourZnO4tetrahedra. This framework of interconnectedMO6octahedra andZnO4tetrahedra contains channels along [110], in which the Sn2 cat ions are locate
Pressure-induced dimerization and valence bond crystal formation in the Kitaev-Heisenberg magnet alpha-RuCl3
Magnetization and high-resolution x-ray diffraction measurements of the
Kitaev-Heisenberg material alpha-RuCl3 reveal a pressure-induced
crystallographic and magnetic phase transition at a hydrostatic pressure of
p=0.2 GPa. This structural transition into a triclinic phase is characterized
by a very strong dimerization of the Ru-Ru bonds, accompanied by a collapse of
the magnetic susceptibility. Ab initio quantum-chemistry calculations disclose
a pressure-induced enhancement of the direct 4d-4d bonding on particular Ru-Ru
links, causing a sharp increase of the antiferromagnetic exchange interactions.
These combined experimental and computational data show that the Kitaev spin
liquid phase in alpha-RuCl3 strongly competes with the crystallization of spin
singlets into a valence bond solid
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