Influence of water absorption in flexible epoxy resins on the space charge behaviour

The aim of the current work is to achieve a better understanding of the influence of water uptake in flexible epoxy resins on the space charge dynamics at high electric fields. The space charge behaviour was studied using pulsed electroacoustic (PEA) technique. The samples were prepared from Araldite CY1311, which is a bisphenol-A epoxy resin. This particular resin was chosen because its glass transition is 0°C and hence it is in a flexible state at room temperature. All samples were conditioned in containers with saturated salt solutions or de-ionised water so that various water uptake levels were obtained. It was found that the space charge dynamics was correlated with the amount of absorbed water in the samples and this is consistent with the dielectric measurements made on the same material where ion transport was identified as the main charge transport process from the observed QDC behaviour

Limitations of Kramers-Kronig transform for calculation of the DC conductance magnitude from dielectric measurements

The Kramers-Kronig (K-K) transform relates the real and imaginary parts of the complex susceptibility as a consequence of the principle of causality. It is a special case of the Hilbert transform and it is often used for estimation of the DC conductance from dielectric measurements. In this work, the practical limitations of a numerical implementation of the Kramers-Kronig transform was investigated in the case of materials that exhibit both DC conductance and quasi-DC (QDC) charge transport processes such as epoxy resins. The characteristic feature of a QDC process is that the real and imaginary parts of susceptibility (permittivity) follow fractional power law dependences with frequency with the low frequency exponent approaching -1. Dipolar relaxation in solids on the other hand has a lower frequency exponent <1. The computational procedure proposed by Jonscher for calculation of the K-K transform involves extrapolation and truncation of the data to low frequencies so that convergence of the integrals is ensured. The validity of the analysis is demonstrated by performing K-K transformation on real experimental data and on theoretical data generated using the Dissado-Hill function. It has been found that the algorithm works well for dielectric relaxation responses but it is apparent that it does not work in the case of a low frequency power law in which the low frequency exponent approaches -1, i.e. in the case of QDC responses. In this case convergence can only be guaranteed by extrapolating the low frequency power law over many decades towards zero frequency

Statistical Analysis of Partial Discharges from Electrical Trees Grown in a Flexible Epoxy Resin

Electrical treeing is a long-term degradation mechanism in polymeric insulation, which can lead to electrical failure of HV insulation systems. The rate at which trees grow across the insulation depends on the PD activity occurring within them and hence the detection of the onset of electrical treeing could be established by PD monitoring. In this paper, a statistical analysis of the partial discharges detected during the growth of trees in an epoxy resin will be reported. The aim of this work was to provide additional insight into the physical mechanisms that lead to the observed fluctuations in the partial discharge activity. The results demonstrate interesting correlations between a number of statistical parameters, such as average discharge magnitude and standard deviation in the partial discharge amplitudes. These correlations could also be related to physical parameters such as the applied voltage magnitude and the measured power dissipation due to the partial discharges occurring during tree growth. The implications of this work for deterministic methodologies for the simulation of tree growth as well as for condition monitoring using feature recognition strategies for the early detection of tree growth will be discussed

Electron spin resonance study of changes during the development of a mouse myeloid leukaemia. I. Paramagnetic metal ions.

The blood, spleen and liver of mice were examined by means of electron spin resonance (e.s.r.), throughout the course of myeloid leukaemia induced by intravenous injection of leukaemic spleen cells. In blood, marked increases in the concentrations of iron transferrin and ceruloplasmin occurred within the first 3 days after injection. In the spleen, changes in the concentrations of paramagnetic copper and iron complexes were detectable by about the 5th day, before any measurable splenic enlargement, whilst in the liver changes were detectable by about the 8th day. The changes occurring in blood, spleen and liver during the development of leukaemia appear to be related and they are discussed in terms of iron transport

Influence of the temperature on the dielectric properties of epoxy resins

Electrical degradation processes in epoxy resins, such as electrical treeing, were found to be dependent on the temperature at which the experiments were carried out. Therefore, it is of considerable research interest to study the influence of temperature on the dielectric properties of the polymers and to relate the effect of temperature on these properties to the possible electrical degradation mechanisms. In this work, the dielectric properties of two different epoxy resin systems have been characterized via dielectric spectroscopy. The epoxy resins used were bisphenol-A epoxy resins Araldite CY1301 and Araldite CY1311, the later being a modified version of the former with added plasticizer. The CY1301 samples were tested below and above their glass transition temperature, while the CY1311 were tested well above it. Both epoxy systems possess similar behaviour above the glass transition temperature, e.g. in a flexible state, which can be characterized as a low frequency dispersion (LFD). On the other hand, it was found that below the glass transition temperature CY1301 samples have almost “flat” dielectric response in the frequency range considered. The influence of possible interfacial features on the measured results is discussed

Influence of absorbed moisture on the dielectric properties of epoxy resins

The dielectric response of two bisphenol-A epoxy resin systems Araldite CY1301 (Tg ~ 50°C) and Araldite CY1311 (Tg ~0°C) was studied at different levels of absorbed moisture. The dielectric measurements were carried out over the frequency range 1 mHz to 100 kHz and the results were characterised in terms of dc bulk electrical conduction and dielectric processes. The characteristic parameters (frequency and magnitude) of all processes have been found to be moisture dependent. In both resins above the glass transition temperature, absorbed moisture was found to be implicated in the formation of a bulk quasi-dc dielectric response consistent with cluster formation of the absorbed water molecules

ESR study of development of RFM/Un murine myeloid leukaemia.

The blood, spleen and liver of RFM/Un mice were examined by means of electron spin resonance (ESR) throughout the course of myeloid leukaemia induced by i.v. injection of leukaemic spleen cells. Marked changes in the concentration of iron transferrin and caeruloplasmin were observed in the blood 1 day after injection. As the disease progressed, changes occurred in the concentrations of the ascorbyl radical and of paramagnetic metal complexes in both spleen and liver. These changes are compared with those induced in RF/J mice injected with normal and leukaemic spleen cells from RFM/Un mice

Effects of temperature upon the collapse of a Bose-Einstein condensate in a gas with attractive interactions

We present a study of the effects of temperature upon the excitation frequencies of a Bose-Einstein condensate formed within a dilute gas with a weak attractive effective interaction between the atoms. We use the self-consistent Hartree-Fock Bogoliubov treatment within the Popov approximation and compare our results to previous zero temperature and Hartree-Fock calculations The metastability of the condensate is monitored by means of the $l=0$ excitation frequency. As the number of atoms in the condensate is increased, with $T$ held constant, this frequency goes to zero, signalling a phase transition to a dense collapsed state. The critical number for collapse is found to decrease as a function of temperature, the rate of decrease being greater than that obtained in previous Hartree-Fock calculations.Comment: 4 pages LaTeX, 3 eps figures. To appear as a letter in J. Phys.