Characterization of phyllosilicates observed in the central Mawrth Vallis region, Mars, their potential formational processes, and implications for past climate

Mawrth Vallis contains one of the largest exposures of phyllosilicates on Mars. Nontronite, montmorillonite, kaolinite, and hydrated silica have been identified throughout the region using data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). In addition, saponite has been identified in one observation within a crater. These individual minerals are identified and distinguished by features at 1.38–1.42, ∼1.91, and 2.17–2.41 μm. There are two main phyllosilicate units in the Mawrth Vallis region. The lowermost unit is nontronite bearing, unconformably overlain by an Al-phyllosilicate unit containing montmorillonite plus hydrated silica, with a thin layer of kaolinite plus hydrated silica at the top of the unit. These two units are draped by a spectrally unremarkable capping unit. Smectites generally form in neutral to alkaline environments, while kaolinite and hydrated silica typically form in slightly acidic conditions; thus, the observed phyllosilicates may reflect a change in aqueous chemistry. Spectra retrieved near the boundary between the nontronite and Al-phyllosilicate units exhibit a strong positive slope from 1 to 2 μm, likely from a ferrous component within the rock. This ferrous component indicates either rapid deposition in an oxidizing environment or reducing conditions. Formation of each of the phyllosilicate minerals identified requires liquid water, thus indicating a regional wet period in the Noachian when these units formed. The two main phyllosilicate units may be extensive layers of altered volcanic ash. Other potential formational processes include sediment deposition into a marine or lacustrine basin or pedogenesis

Phyllosilicate Diversity and Past Aqueous Activity Revealed at Mawrth Vallis, Mars

Observations by the Mars Reconnaissance Orbiter/Compact Reconnaissance Imaging Spectrometer for Mars in the Mawrth Vallis region show several phyllosilicate species, indicating a wide range of past aqueous activity. Iron/magnesium (Fe/Mg)–smectite is observed in light-toned outcrops that probably formed via aqueous alteration of basalt of the ancient cratered terrain. This unit is overlain by rocks rich in hydrated silica, montmorillonite, and kaolinite that may have formed via subsequent leaching of Fe and Mg through extended aqueous events or a change in aqueous chemistry. A spectral feature attributed to an Fe^(2+) phase is present in many locations in the Mawrth Vallis region at the transition from Fe/Mg-smectite to aluminum/silicon (Al/Si)–rich units. Fe^(2+)-bearing materials in terrestrial sediments are typically associated with microorganisms or changes in pH or cations and could be explained here by hydrothermal activity. The stratigraphy of Fe/Mg-smectite overlain by a ferrous phase, hydrated silica, and then Al-phyllosilicates implies a complex aqueous history

Mineralogy of Juventae Chasma: Sulfates in the light‐toned mounds, mafic minerals in the bedrock, and hydrated silica and hydroxylated ferric sulfate on the plateau

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/95351/1/jgre2657.pd

A synthesis of Martian aqueous mineralogy after 1 Mars year of observations from the Mars Reconnaissance Orbiter

Martian aqueous mineral deposits have been examined and characterized using data acquired during Mars Reconnaissance Orbiter's (MRO) primary science phase, including Compact Reconnaissance Imaging Spectrometer for Mars hyperspectral images covering the 0.4–3.9 μm wavelength range, coordinated with higher–spatial resolution HiRISE and Context Imager images. MRO's new high-resolution measurements, combined with earlier data from Thermal Emission Spectrometer; Thermal Emission Imaging System; and Observatoire pour la Minéralogie, L'Eau, les Glaces et l'Activitié on Mars Express, indicate that aqueous minerals are both diverse and widespread on the Martian surface. The aqueous minerals occur in 9–10 classes of deposits characterized by distinct mineral assemblages, morphologies, and geologic settings. Phyllosilicates occur in several settings: in compositionally layered blankets hundreds of meters thick, superposed on eroded Noachian terrains; in lower layers of intracrater depositional fans; in layers with potential chlorides in sediments on intercrater plains; and as thousands of deep exposures in craters and escarpments. Carbonate-bearing rocks form a thin unit surrounding the Isidis basin. Hydrated silica occurs with hydrated sulfates in thin stratified deposits surrounding Valles Marineris. Hydrated sulfates also occur together with crystalline ferric minerals in thick, layered deposits in Terra Meridiani and in Valles Marineris and together with kaolinite in deposits that partially infill some highland craters. In this paper we describe each of the classes of deposits, review hypotheses for their origins, identify new questions posed by existing measurements, and consider their implications for ancient habitable environments. On the basis of current data, two to five classes of Noachian-aged deposits containing phyllosilicates and carbonates may have formed in aqueous environments with pH and water activities suitable for life

A Mission Simulating the Search for Life on Mars with Automated Drilling, Sample Handling, and Life Detection Instruments Performed in the Hyperarid Core of the Atacama Desert, Chile

We report on a field demonstration of a rover-based drilling mission to search for biomolecular evidence of life in the arid core of the Atacama Desert, Chile. The KREX2 rover carried the Honeybee Robotics 1 m depth The Regolith and Ice Drill for Exploration of New Terrains (TRIDENT) drill and a robotic arm with scoop that delivered subsurface fines to three flight prototype instruments: (1) The Signs of Life Detector (SOLID), a protein and biomolecule analyzer based on fluorescence sandwich microarray immunoassay; (2) the Planetary In Situ Capillary Electrophoresis System (PISCES), an amino acid analyzer based on subcritical water extraction coupled to microchip electrophoresis analysis; and (3) a Wet Chemistry Laboratory cell to measure soluble ions using ion selective electrodes and chronopotentiometry. A California-based science team selected and directed drilling and sampling of three sites separated by hundreds of meters that included a light-toned basin area showing evidence of aqueous activity surrounded by a rocky desert pavement. Biosignatures were detected in basin samples collected at depths ranging from 20 to 80 cm but were not detected in the surrounding area. Subsurface stratigraphy of the units drilled was interpreted from drill sensor data as fine-scale layers of sand/clay sediments interspersed with layers of harder material in the basins and a uniform subsurface composed of course-to-fine sand in the surroundings. The mission timeline and number of commands sent to accomplish each activity were tracked. The deepest sample collected (80 cm) required 55 commands, including drilling and delivery to three instruments. Elapsed time required for drilling and sample handling was less than 3 hours to collect sample from 72 cm depth, including time devoted to recovery from a jammed drill. The experiment demonstrated drilling, sample transfer technologies, and instruments that accomplished successful detection of biomolecular evidence of life in one of the most biologically sparse environments on Earth.The ARADS project was part of the NASA Planetary Science and Technology through Analog Research (PSTAR) program, managed by Dr. Mary Voytek. Dr. Stoker was supported for article preparation by the NASA Internal Scientist Funding Model. The work of Víctor Parro, Mercedes Moreno-Paz, and Laura Sánchez-García was funded by grant number RTI2018-094368-B-I00 (SOLID) and MDM-2017-0737 Unidad de Excelencia “Maria de Maeztu”–Centro de Astrobiología (CSIC-INTA), by the Spanish Ministry of Science and Innovation/State Agency of Research MCIN/AEI/10.13039/501100011033, and by “ERDF A way of making Europe.” Research by P. Willis, F. Mora and F. Kehl of the Jet Propulsion Laboratory, California Institute of Technology, was carried out under a contract with the National Aeronautics and Space Administration (80NM0018D0004).With funding from the Spanish government through the ‘María de Maeztu Unit of Excelence’ accreditation (CEX-2019-000940-M).Peer reviewe

Evidence for a sedimentary origin of a clay minerals in the Mawrth Vallis region, Mars

Clay minerals detected spectroscopically in the Mawrth Vallis region of Mars correspond to a complex, layered, thick (>600 m) stratigraphic section of ancient bedrock. Because the light-toned, clay-bearing rocks are lithologically diverse over a broad area (>80,000 km2), have significant internal layering and complexity, and contain buried impact craters within the section (demonstrating that they were deposited over a geologically significant duration of time), we interpret the host rocks as sedimentary or possibly pyroclastic. Crater counts date the claybearing rocks to early-middle Noachian time (estimated as 3.8-4.1 Ga). Geomorphic observations suggest that the rocks were lithified early and deeply eroded during the late Noachian-early Hesperian. The combination of a probable ancient sedimentary context of the clays and a moderate pH formation environment implied by the occurrence of smectites clearly places these rocks among the most important targets for future astrobiological exploration. © 2007 The Geological Society of America.Link_to_subscribed_fulltex

Spatial Spectroscopic Models for Remote Exploration

Ancient hydrothermal systems are a high-priority target for a future Mars sample return mission because they contain energy sources for microbes and can preserve organic materials (Farmer, 2000 ; MEPAG Next Decade Science Analysis Group, 2008 ; McLennan et al., 2012 ; Michalski et al., 2017 ). Characterizing these large, heterogeneous systems with a remote explorer is difficult due to communications bandwidth and latency; such a mission will require significant advances in spacecraft autonomy. Science autonomy uses intelligent sensor platforms that analyze data in real-time, setting measurement and downlink priorities to provide the best information toward investigation goals. Such automation must relate abstract science hypotheses to the measurable quantities available to the robot. This study captures these relationships by formalizing traditional "science traceability matrices" into probabilistic models. This permits experimental design techniques to optimize future measurements and maximize information value toward the investigation objectives, directing remote explorers that respond appropriately to new data. Such models are a rich new language for commanding informed robotic decision making in physically grounded terms. We apply these models to quantify the information content of different rover traverses providing profiling spectroscopy of Cuprite Hills, Nevada. We also develop two methods of representing spatial correlations using human-defined maps and remote sensing data. Model unit classifications are broadly consistent with prior maps of the site's alteration mineralogy, indicating that the model has successfully represented critical spatial and mineralogical relationships at Cuprite

Spatial Spectroscopic Models for Remote Exploration

Ancient hydrothermal systems are a high-priority target for a future Mars sample return mission because they contain energy sources for microbes and can preserve organic materials (Farmer, 2000 ; MEPAG Next Decade Science Analysis Group, 2008 ; McLennan et al., 2012 ; Michalski et al., 2017 ). Characterizing these large, heterogeneous systems with a remote explorer is difficult due to communications bandwidth and latency; such a mission will require significant advances in spacecraft autonomy. Science autonomy uses intelligent sensor platforms that analyze data in real-time, setting measurement and downlink priorities to provide the best information toward investigation goals. Such automation must relate abstract science hypotheses to the measurable quantities available to the robot. This study captures these relationships by formalizing traditional "science traceability matrices" into probabilistic models. This permits experimental design techniques to optimize future measurements and maximize information value toward the investigation objectives, directing remote explorers that respond appropriately to new data. Such models are a rich new language for commanding informed robotic decision making in physically grounded terms. We apply these models to quantify the information content of different rover traverses providing profiling spectroscopy of Cuprite Hills, Nevada. We also develop two methods of representing spatial correlations using human-defined maps and remote sensing data. Model unit classifications are broadly consistent with prior maps of the site's alteration mineralogy, indicating that the model has successfully represented critical spatial and mineralogical relationships at Cuprite

HiRISE views enigmatic deposits in the Sirenum Fossae region of Mars

HiRISE images together with other recent orbital data from Mars define new characteristics of enigmatic Hesperian-aged deposits in Sirenum Fossae that are mostly 100–200 m thick, drape kilometers of relief, and often display generally low relief surfaces. New characteristics of the deposits, previously mapped as the “Electris deposits,” include local detection of meter-scale beds that show truncating relationships, a generally light-toned nature, and a variably blocky, weakly indurated appearance. Boulders shed by erosion of the deposits are readily broken down and contribute little to talus. Thermal inertia values for the deposits are ~200 J m^(−2) K^(−1) s^(−1/2) and they may incorporate hydrated minerals derived from weathering of basalt. The deposits do not contain anomalous amounts of water or water ice. Deflation may dominate degradation of the deposits over time and points to an inventory of fine-grained sediment. Together with constraints imposed by the regional setting on formation processes, these newly resolved characteristics are most consistent with an eolian origin as a loess-like deposit comprised of redistributed and somewhat altered volcanic ash. Constituent sediments may be derived from airfall ash deposits in the Tharsis region. An origin directly related to airfall ash or similar volcanic materials is less probable and emplacement by alluvial/fluvial, impact, lacustrine, or relict polar processes is even less likely