6 research outputs found
Effect of KCl and CsCl on the Electrical Conductivity of Molten LiF–KBr at the Critical Composition
The electrical conductivity was measured from the melting
point
to 1280 K for molten 0.7 LiF–0.3 KBr (its composition corresponds
to the top of the miscibility gap) containing (2.3, 4.4, 6.5, 8.8,
and 11.2) mol % KCl or (1.2, 2.5, 5.5, and 10.2) mol % CsCl to establish
the influence of this solute on the stability of the two-phase system.
These results indicate that the temperature dependences of the conductivity
along the saturation lines for all of the mixtures studied herein
are similar to one another. Hence, this demonstrates that small additions
of KCl and CsCl to the dissolving melt of LiF-KBr do not exert a substantial
influence on its type of criticality. In the vicinity of the critical
point, the temperature dependence on conductivity differences for
melts is investigated and is described by the equation Δκ
≈ (<i>T</i><sub>c</sub> – <i>T</i>)<sup><i>k</i></sup>, where <i>k</i> is the critical
exponent (<i>k</i> = 0.98). The critical temperature changes
as a function of the mixture composition and depends on the ion size
of the salt added. The critical temperature increases continuously
with the addition of CsCl to molten LiF-KBr, whereas it decreases
as the fraction as KCl is added. This circumstance must occur during
the organization process, as salts accumulate in the dissolving molten
mixture, and they prevent the confluence of the phases at a given
operating temperature. To interpret the experimental results, the
charged hard sphere model for ionic melts in the Debye–Hückel
approximation was used with an account of the excluded volume
X‑ray Generated Recombination Exciplexes of Substituted Diphenylacetylenes with Tertiary Amines: A Versatile Experimental Vehicle for Targeted Creation of Deep-Blue Electroluminescent Systems
Customizable
and technology-friendly functional materials are one
of the mainstays of emerging organic electronics and optoelectronics.
We show that recombination exciplexes of simple substituted diphenylacetylenes
with tertiary amines can be a convenient source of tunable deep-blue
emission with possible applications in organic electroluminescent
systems. The optically inaccessible exciplexes were produced via recombination
of radiation-generated radical ion pairs in alkane solution, which
mimics charge transport and recombination in the active layer of practical
organic light-emitting diodes in a simple solution-based experiment.
Despite varying and rather poor intrinsic emission properties, diphenylacetylene
and its prototypical methoxy (donor) or trifluoromethyl (acceptor)
monosubstituted derivatives readily form recombination exciplexes
with <i>N</i>,<i>N</i>-dimethylaniline and other
tertiary amines that produce emission with maxima ranging from 385
to 435 nm. The position of emission band maximum linearly correlates
with readily calculated gas-phase electron affinity of the corresponding
diphenylacetylene, which can be used for fast computational prescreening
of the candidate molecules, and various substituted diphenylacetylenes
can be synthesized via relatively simple and universal cross-coupling
reactions of Sonogashira and Castro. Together, the simple solution-based
experiment, computationally cheap prescreening method, and universal
synthetic strategy may open a very broad and chemically convenient
class of compounds to obtain OLEDs and OLED-based multifunctional
devices with tunable emission spectrum and high conversion efficiency
that has yet not been seriously considered for these purposes
X‑ray Generated Recombination Exciplexes of Substituted Diphenylacetylenes with Tertiary Amines: A Versatile Experimental Vehicle for Targeted Creation of Deep-Blue Electroluminescent Systems
Customizable
and technology-friendly functional materials are one
of the mainstays of emerging organic electronics and optoelectronics.
We show that recombination exciplexes of simple substituted diphenylacetylenes
with tertiary amines can be a convenient source of tunable deep-blue
emission with possible applications in organic electroluminescent
systems. The optically inaccessible exciplexes were produced via recombination
of radiation-generated radical ion pairs in alkane solution, which
mimics charge transport and recombination in the active layer of practical
organic light-emitting diodes in a simple solution-based experiment.
Despite varying and rather poor intrinsic emission properties, diphenylacetylene
and its prototypical methoxy (donor) or trifluoromethyl (acceptor)
monosubstituted derivatives readily form recombination exciplexes
with <i>N</i>,<i>N</i>-dimethylaniline and other
tertiary amines that produce emission with maxima ranging from 385
to 435 nm. The position of emission band maximum linearly correlates
with readily calculated gas-phase electron affinity of the corresponding
diphenylacetylene, which can be used for fast computational prescreening
of the candidate molecules, and various substituted diphenylacetylenes
can be synthesized via relatively simple and universal cross-coupling
reactions of Sonogashira and Castro. Together, the simple solution-based
experiment, computationally cheap prescreening method, and universal
synthetic strategy may open a very broad and chemically convenient
class of compounds to obtain OLEDs and OLED-based multifunctional
devices with tunable emission spectrum and high conversion efficiency
that has yet not been seriously considered for these purposes