HIGH-VOLTAGE OPTICAL-EMISSION IN BINARY GASEOUS-MIXTURES OF N-2

Cataloged from PDF version of article.Optical emission in 1:1 binary gaseous mixtures under high voltage displays a varying character depending on pressure, applied voltage polarity, and chemical nature of the mixture. Under negative polarity, in pure N-2 and 50% mixture of Ar, O-2 and CO2, emission stemming from N-2(+) is enhanced relative to emission from neutral N-2. On mixtures of N-2 with gases containing halogens (CCl4, CHCl3, CH2Cl2, CF3H, CF2Cl2 and SF6) a reversal is observed, i.e. the N-2(+) emission is suppressed. An enhancement factor is defined as the ratio of the emission under negative polarity to positive polarity to quantify this polarity dependence. This enhancement factor varies between 0.01 and 50 depending on the second component in the mixture

Studies of tautomerism in the azonaphthol derivatives of benzimidazoles

The tautomeric behaviour of three azonaphthol derivatives of benzimidazoles, 1-[(6-nitro-1H-benzimidazol-5-yl)diazenyl]naphthalen-2-ol, 1-[1H-benzimidazol-5-yldiazenyl]naphthalen-2-ol and 1-[(1-methyl-1H-benzimi-dazol-5-yl)diazenyl]naphthalen-2-ol, were studied in solution, in solid state and in gas phase using spectroscopic techniques. The results show that the ketohydrazone tautomeric form is predominant in solution and in solid state while in gas phase the tautomeric equilibrium is on the azoenol side

In vitro transfection of HeLa cells with temperature sensitive polycationic copolymers

Cataloged from PDF version of article.In this study, we investigated different types of polyethyleneimine (PEI) and their block copolymers with N-isopropylacrylamide (NIPA) as temperature-sensitive polycationic non-viral vectors for transfection of HeLa cells in cell culture media. First carboxyl-terminated poly(NIPA) was synthesized and then copolymerized with PEIs branched or linear and with two different molecular weights (2 and 25 kDa). Addition of PEI units to the poly(NIPA) chains increased the LCST values up to body temperature. Zeta potentials of the copolymers were significantly lower than the corresponding PEI homopolymers. A green fluorescent protein expressing plasmid was used as a model. Complexes of this plasmid both with PEIs and their copolymers were formed. The zeta potentials of these complexes were between -3.1 and +21.3. Higher values were observed for the complexes prepared with branched and higher molecular weight PEIs. Copolymerization caused a profound decrease in the positive charges. Particle sizes of the complexes were in the range of 190-1235 nm. Using high polymer/plasmid ratios caused aggregation. The smallest complexes were obtained with the copolymer prepared with branched PEI with 25-kDa molecular weight. Copolymers were able to squeeze plasmid DNA more at the body temperature. Cytotoxicity was observed with PEIs especially with the branched higher molecular weights. Copolymerization reduced the cytotoxicity. The best in vitro DNA uptake efficiency (70%) was achieved with the complex prepared with poly(NIPA)/PEI25B. However, poly(NIPA)/PEI25L was the most successful vector for an effective gene expression without any significant toxicity. © 2004 Elsevier B.V. All rights reserved

Back diffusion of electrons in argon subjected to uniform time invariant orthogonal electric and magnetic fields

In this study, the processes of back diffusion in Ar subjected to crossed fields are analyzed by using the Monte Carlo simulation method in the E/N range of 50 to 500 Td (1 Td = 1 × 10–17 V cm2) for 0 \u3c B/N \u3c 25 × 10−19 T cm3. At a given constant E/N, escape factors decrease with an increasing crossed, reduced magnetic field B/N. This reduction in the escape factor is more pronounced in the lower E/N range. Furthermore, the mean number of collisions of back scattered electrons is quite large, and at a given E/N, the mean number of collisions decreases as the crossed B/N increases

Studies of tautomerism in the azonaphthol derivatives of benzimidazoles

The tautomeric behaviour of three azonaphthol derivatives of benzimidazoles, 1-[(6-nitro-1H-benzimidazol-5-yl)diazenyl]naphthalen-2-ol, 1-[1H-benzimidazol-5-yldiazenyl]naphthalen-2-ol and 1-[(1-methyl-1H-benzimi-dazol-5-yl)diazenyl]naphthalen-2-ol, were studied in solution, in solid state and in gas phase using spectroscopic techniques. The results show that the ketohydrazone tautomeric form is predominant in solution and in solid state while in gas phase the tautomeric equilibrium is on the azoenol side

Variable frame based Max-Weight algorithms for networks with switchover delay

This paper considers the scheduling problem for networks with interference constraints and switchover delays, where it takes a nonzero time to reconfigure each service schedule. Switchover delay occurs in many telecommunication applications such as satellite, optical or delay tolerant networks (DTNs). Under zero switchover delay it is well known that the Max-Weight algorithm is throughput-optimal without requiring knowledge of the arrival rates. However, we show that this property of Max-Weight no longer holds when there is a nonzero switchover delay. We propose a class of variable frame based Max-Weight (VFMW) algorithms which employ the Max-Weight schedule corresponding to the beginning of the frame during an interval of duration dependent on the queue sizes. The VFMW algorithms dynamically adapt the frame sizes to the stochastic arrivals and provide throughput-optimality without requiring knowledge of the arrival rates. Numerical results regarding the application of the VFMW algorithms to DTN and optical networks demonstrate a good delay performance.National Science Foundation (U.S.) (NSF grant CNS-0626781)National Science Foundation (U.S.) (NSF grant CNS-0915988)United States. Army Research Office (ARO Muri grant number W911NF-08-1-0238

Work Zone Simulator Analysis: Driver Performance and Acceptance of Alternate Merge Sign Configurations

Improving work zone road safety is an issue of great interest due to the high number of crashes observed in work zones. Departments of Transportation (DOTs) use a variety of methods to inform drivers of upcoming work zones. One method used by DOTs is work zone signage configuration. It is necessary to evaluate the efficiency of different configurations, by law, before implementation of new signage designs that deviate from national standards. This research presents a driving simulator based study, funded by the Missouri Department of Transportation (MoDOT) that evaluates a driver’s response to work zone sign configurations. This study has compared the Conventional Lane Merge (CLM) configurations against MoDOT’s alternate configurations. Study participants within target populations, chosen to represent a range of Missouri drivers, have attempted four work zone configurations, as part of a driving simulator experience. The test scenarios simulated both right and left work zone lane closures for both the CLM and MoDOT alternatives. Travel time was measured against demographic characteristics of test driver populations. Statistical data analysis was used to investigate the effectiveness of different configurations employed in the study. The results of this study were compared to results from a previous MoDOT to compare result of field and simulation study about MoDOT’s alternate configurations

Waste Management of Ege University during the COVID-19 period

Ege University manages packaging wastes, hazardous wastes, electronic wastes and organic wastes within the scope of integrated waste management and has been awarded the Ministry of Environment and Urbanization Zero Waste Certificate. For packaging waste, recycled and non-recyclable wastes are collected separately. Recycled wastes are collected in blue boxes and gray boxes are used for non-recyclable wastes. Along with the pandemic period, with the directive of the Ministry of Environment and Urbanization, extra gray boxes were added and used to collect waste materials such as masks, gloves, etc. The first COVID case in Turkey started in March 2020 and these studies came into effect in April. In this context, all staff and students are informed and the health of the community and the environment is protected.Keyword: waste management, mask and glove waste management, COVID-1

Porous and Complex Flow Structures in Modern Technologies

Porous and Complex Flow Structures in Modern Technologies represents a new approach to the field, considering the fundamentals of porous media in terms of the key roles played by these materials in modern technology. Intended as a text for advanced undergraduates and as a reference for practicing engineers, the book uses the physics of flows in porous materials to tie together a wide variety of important issues from such fields as biomedical engineering, energy conversion, civil engineering, electronics, chemical engineering, and environmental engineering. Thus, for example, flows of water and oil through porous ground play a central role in energy exploration and recovery (oil wells, geothermal fluids), energy conversion (effluents from refineries and power plants), and environmental engineering (leachates from waste repositories). Similarly, the demands of miniaturization in electronics and in biomedical applications are driving research into the flow of heat and fluids through small-scale porous media (heat exchangers, filters, gas exchangers). Filters, catalytic converters, the drying of stored grains, and a myriad of other applications involve flows through porous media. By providing a unified theoretical framework that includes not only the traditional homogeneous and isotropic media but also models in which the assumptions of representative elemental volumes or global thermal equilibrium fail, the book provides practicing engineers the tools they need to analyze complex situations that arise in practice. This volume includes examples, solved problems and an extensive glossary of symbols