833 research outputs found
Dynamic Structural Flexibility of Fe-MOF-5 Evidenced by â”â·Fe Mössbauer Spectroscopy
Temperature-dependent â”â·Fe Mössbauer spectra were collected on Fe[subscript x]Zn[subscript 4âx](1,4-benzenedicarboxylate)â (Fe-MOF-5). When measured under an Ar atmosphere, the data at higher temperatures reveal thermal population of the lowest-lying electronic excited state, as expected for low symmetry tetrahedral ferrous ions. In the presence of Nâ, however, the temperature dependence becomes exaggerated and the spectra cannot be fitted to a single species. A fluctuating electric field gradient at the Fe nuclei best explains these data and suggests dynamic structural distortions induced by weak interactions with Nâ. This direct evidence of dynamic behaviour at MOF open metal sites is relevant for the use of MOF SBUs in catalysis, gas separation, and other applications that invoke similar phenomena
Hole Drift Mobility Measurements on a-Si:H using Surface and Uniformly Absorbed Illumination
The standard, time-of-flight method for measuring drift mobilities in semiconductors uses strongly absorbed illumination to create a sheet of photocarriers near an electrode interface. This method is problematic for solar cells deposited onto opaque substrates, and in particular cannot be used for hole photocarriers in hydrogenated amorphous silicon (a-Si:H) solar cells using stainless steel substrates. In this paper we report on the extension of the time-of-flight method that uses weakly absorbed illumination. We measured hole drift-mobilities on seven a-Si:H nip solar cells using strongly and weakly absorbed illumination incident through the n-layer. For thinner devices from two laboratories, the drift-mobilities agreed with each other to within a random error of about 15%. For thicker devices from United Solar, the driftmobilities were about twice as large when measured using strongly absorbed illumination. We propose that this effect is due to a mobility profile in the intrinsic absorber layer in which the mobility decreases for increasing distance from the substrate
Large scale shell model calculations for odd-odd Mn isotopes
Large scale shell model calculations have been carried out for odd-odd
Mn isotopes in two different model spaces. First set of calculations
have been carried out in full shell valence space with two recently
derived shell interactions namely GXPF1A and KB3G treating Ca
as core. The second set of calculations have been performed in
valence space with the interaction treating Ca as core and
imposing a truncation by allowing up to a total of six particle excitations
from the 0f orbital to the upper orbitals for protons and
from the upper orbitals to the 0g orbital for neutron. For
low-lying states in Mn, the KB3G and GXPF1A both predicts good results
and for Mn, KB3G is much better than GXPF1A. For negative parity and
high-spin positive parity states in both isotopes interaction is
required. Experimental data on Mn is sparse and therefore it is not
possible to make any definite conclusions. More experimental data on negative
parity states is needed to ascertain the importance of 0g and higher
orbitals in neutron rich Mn isotopes.Comment: 5 pages, 4 figures, Submitted to Eur. Phys. J.
Measurement of excited states in 40Si and evidence for weakening of the N=28 shell gap
Excited states in 40Si have been established by detecting gamma-rays
coincident with inelastic scattering and nucleon removal reactions on a liquid
hydrogen target. The low excitation energy, 986(5) keV, of the 2+[1] state
provides evidence of a weakening in the N=28 shell closure in a neutron-rich
nucleus devoid of deformation-driving proton collectivity.Comment: accepted for publication in PR
Spectroscopy of the odd-odd fp-shell nucleus 52Sc from secondary fragmentation
The odd-odd fp-shell nucleus 52Sc was investigated using in-beam gamma-ray
spectroscopy following secondary fragmentation of a 55V and 57Cr cocktail beam.
Aside from the known gamma-ray transition at 674(5)keV, a new decay at
E_gamma=212(3) keV was observed. It is attributed to the depopulation of a
low-lying excited level. This new state is discussed in the framework of
shell-model calculations with the GXPF1, GXPF1A, and KB3G effective
interactions. These calculations are found to be fairly robust for the
low-lying level scheme of 52Sc irrespective of the choice of the effective
interaction. In addition, the frequency of spin values predicted by the shell
model is successfully modeled by a spin distribution formulated in a
statistical approach with an empirical, energy-independent spin-cutoff
parameter.Comment: accepted for publication in PR
Enhanced collectivity in 74Ni
The neutron-rich nucleus 74Ni was studied with inverse-kinematics inelastic
proton scattering using a 74Ni radioactive beam incident on a liquid hydrogen
targetat a center-of-mass energy of 80 MeV. From the measured de-excitation
gamma-rays, the population of the first 2+ state was quantified. The
angle-integrated excitation cross section was determined to be 14(4) mb. A
deformation length of delta = 1.04(16) fm was extracted in comparison with
distorted wave theory, which suggests that the enhancement of collectivity
established for 70Ni continues up to 74Ni. A comparison with results of shell
model and quasi-particle random phase approximation calculations indicates that
the magic character of Z = 28 or N = 50 is weakened in 74Ni
One-neutron knockout in the vicinity of the N=32 sub-shell closure: 9Be(57Cr,56Cr+ gamma)X
The one-neutron knockout reaction 9Be(57Cr,56Cr + gamma)X has been measured
in inverse kinematics with an intermediate-energy beam. Cross sections to
individual states in 56Cr were partially untangled through the detection of the
characteristic gamma-ray transitions in coincidence with the reaction residues.
The experimental inclusive longitudinal momentum distribution and the yields to
individual states are compared to calculations that combine spectroscopic
factors from the full fp shell model and nucleon-removal cross sections
computed in a few-body eikonal approach.Comment: PRC, in pres
Probing shell structure and shape changes in neutron-rich sulfur isotopes through transient-field g factor measurements on fast radioactive beams of 38S and 40S
The shell structure underlying shape changes in neutron-rich nuclei near N=28
has been investigated by a novel application of the transient field technique
to measure the first-excited state g factors in 38S and 40S produced as fast
radioactive beams. There is a fine balance between proton and neutron
contributions to the magnetic moments in both nuclei. The g factor of deformed
40S does not resemble that of a conventional collective nucleus because spin
contributions are more important than usual.Comment: 10 pages, 6 figures, accepted in PR
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