53 research outputs found

    Electromagnetic shielding effectiveness of carbon fibre reinforced composites

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    This paper reports results on the shielding effectiveness parameter of laminated epoxy composites with carbon fibre reinforcements. Measurements of shielding effectiveness were carried out with a coaxial transmission line testing chamber according to ASTM 4935 standard and epoxy-matrix composites with continuous carbon-fibres were proven to be an excellent electromagnetic interference shielding material, where a composite slab made of 4 layers of prepregs provided more than 99.9% of electromagnetic attenuation. It was found that the reflection mechanism of the shielding material was mainly influenced by the fibre volume ratio, and that an increase in the number of layers of the composite resulted in higher shielding effectiveness due to a greater absorption mechanism. Calculations of the shielding effectiveness parameter of the material used were made by means of commercial electromagnetic simulation tools, having determined experimentally the overall resistivity of the composite. The findings presented in this work suggest that in presence of a greater number of interfaces at different impedance the separate modelling of matrix and fibres at mesoscopic scale must be taken into account

    A concise review on microwave-assisted polycondensation reactions and curing of polycondensation polymers with focus on the effect of process conditions

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    During the past 15 years, increasing application of microwave heating to polycondensation reactions has been witnessed. Experiments have been carried out at laboratory scale using widely different experimental procedures. The use of microwaves has often led to significant benefits compared to conventional heating experiments in terms of multi-fold decrease in reaction times and energy consumption and production of polymers with increased molecular weight and improved mechanical properties. In other cases, microwaves do not appear to produce any significant benefits compared to conventional heating. At present, guidelines to experimentalist as to the process conditions and experimental design that should be applied are missing and experimentation seems to be based on an empirical trial-and-error approach. In view of the very different experimental protocols that have been applied and the contradictory trends that are frequently reported, we aim in this review to shed light on the role of important process parameters, such as the presence and type of solvent, the dielectric properties of the mixture and the individual phases, the use of heterogeneous catalysts, pressure, stirring, reflux conditions, temperature measurement method and microwave absorbing fillers, which all seem to determine the occurrence and magnitude of the benefits enabled by microwaves during polycondensation reactions

    Predicting the behaviour of near-critical and supercritical alcohols at microwave frequencies: Validation of molecular dynamic simulations as a tool that can substitute for measurements under extreme experimental conditions

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    Equilibrium and non-equilibrium molecular dynamic simulations, predicting the dielectric properties of near-critical and supercritical methanol and ethanol at microwave frequencies have been carried out. The autocorrelation functions of the dielectric relaxation, show dependency on the slow component at the near-critical region for both alcohols. At the supercritical region, two competing relaxation mechanisms are observed, related to the large breakdown of the hydrogen-bonding network and the degree of clustering between the molecules. This approach closely matches experimental data at microwave frequencies and identical temperature and pressure conditions, validating the predictions of how the molecular structure and dynamics manifest themselves into the complex permittivity and dielectric relaxation behaviour. Thus, introducing a modelling-based solution to deliver accurate dielectric property values for materials at supercritical conditions for “a priori” screening of solvents, whilst removing the need to overcome engineering and safety challenges associated with the development of experimental equipment to practically generate such data

    Methinks: Enabling Sophisticated Comment Management in the Social Web

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    User reviews, comments and votes on the Social Web form the modern version of word-of-mouth communication, which has a huge impact on people’s shopping habits, businesses and the overall market. Despite that, systems have so far limited practical success in helping consumers and businesses analysing, managing and understanding Social Web content. In this paper, we present a new tool that leverages a combination of techniques from Semantic Web, Computational Argumentation and Crowdsourcing to support this activity, through an intuitive and functional user interface

    Understanding the scabbling of concrete using microwave energy

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    This paper reports on the use of microwave energy to scabble concrete. While the technique is not new, little information exists relating to the controllability of the process, the effect of different types of concrete and the performance and durability of the scabbled concrete post treatment. Concrete blocks supplied by the UK Sellafield nuclear site were treated with microwave energy using a 15kW system, operating at 2.45GHz. The effect of aggregate type (Whinstone, Gravel and Limestone); standoff distance; and effect of surface coating were studied to determine their influence on the systems performance, in terms of mass and area removal rates. Complimentary modelling studies were undertaken relating the power density of the microwave energy to observed scabbling profile. Mass and area removal rates averaged 11.3gs-1 and 3cms-1 respectively on treating large areas to a depth of 25mm. The process was shown to not adversely affect structural properties of the specimens after treatment

    Quantum gate algorithm for reference-guided DNA sequence alignment

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    Reference-guided DNA sequencing and alignment is an important process in computational molecular biology. The amount of DNA data grows very fast, and many new genomes are waiting to be sequenced while millions of private genomes need to be re-sequenced. Each human genome has 3.2 B base pairs, and each one could be stored with 2 bits of information, so one human genome would take 6.4 B bits or about 760 MB of storage (National Institute of General Medical Sciences). Today most powerful tensor processing units cannot handle the volume of DNA data necessitating a major leap in computing power. It is, therefore, important to investigate the usefulness of quantum computers in genomic data analysis, especially in DNA sequence alignment. Quantum computers are expected to be involved in DNA sequencing, initially as parts of classical systems, acting as quantum accelerators. The number of available qubits is increasing annually, and future quantum computers could conduct DNA sequencing, taking the place of classical computing systems. We present a novel quantum algorithm for reference-guided DNA sequence alignment modeled with gate-based quantum computing. The algorithm is scalable, can be integrated into existing classical DNA sequencing systems and is intentionally structured to limit computational errors. The quantum algorithm has been tested using the quantum processing units and simulators provided by IBM Quantum, and its correctness has been confirmed.Comment: 19 pages, 13 figure

    Evidence for the microwave effect during the annealing of zinc oxide

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    A microwave/conventional hybrid furnace has been used to anneal virtually fully dense zinc oxide ceramics under pure conventional and a microwave/conventional hybrid heating regime with a view to obtaining evidence for the ‘microwave effect’ during the resulting grain growth. In each case it was ensured that each sample within a series had an identical thermal history in terms of its temperature/time profile. The results showed that grain growth was enhanced during hybrid heating compared to pure conventional heating; the greatest enhancement, a factor of ~3 increase in average grain size, was observed in the range 1100-1150°C. The grain growth exponent decreased from 3 during conventional heating to 1.4 during hybrid heating in this temperature range, suggesting an acceleration of the diffusional processes involved. Temperature gradients within the samples were found to be too small to explain the results. This suggests that clear evidence has been found to support the existence of a genuine ‘microwave effect’

    Improving the design of industrial microwave processing systems through prediction of the dielectric properties of complex multi-layered materials

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    Rigorous design of industrial microwave processing systems requires in-depth knowledge of the dielectric properties of the materials to be processed. These values are not easy to measure, particularly when a material is multi-layered containing multiple phases, when one phase has a much higher loss than the other and the application is based on selective heating. This paper demonstrates the ability of the Clausius-Mossotti (CM) model to predict the dielectric constant of multi-layered materials. Furthermore, mixing rules and graphical extrapolation techniques were used to further evidence our conclusions and to estimate the loss factor. The material used for this study was vermiculite, a layered alumina-silicate mineral containing up to 10 % of an interlayer hydrated phase. It was measured at different bulk densities at two distinct microwave frequencies, namely 934 and 2143 MHz. The CM model, based on the ionic polarisability of the bulk material, gives only a prediction of the dielectric constant for experimental data with a deviation of less than 5 % at microwave frequencies. The complex refractive index model (CRIM), Landau, Lifshitz and Loyenga (LLL), Goldschmidt, Böttcher and Bruggeman-Hanai model equations are then shown to give a strong estimation of both dielectric constant and loss factor of the solid material compared to that of the measured powder with a deviation of less than 1 %. Results obtained from this work provide a basis for the design of further electromagnetic processing systems for multi-layered materials consisting of both high loss and low loss components
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