The application of electrochemical impedance spectroscopy for characterizing the degradation of Ni(OH)2/NiOOH electrodes

The use of wide-band electrochemical impedance spectroscopy is described for characterizing the degradation of porous Ni(OH)2/NiOOH electrodes in concentrated KOH electrolyte solutions. The impedance spectra are interpreted in terms of a finite electrical transmission line and the changes in the components of the electrical analog are followed as a function of cycle number. The degradation of the capacity of rolled and bonded Ni(OH)2/NiOOH electrodes is caused by rupture of ohmic contacts within the active mass and by restructuring which results in a decrease in the number of active pores

Predicting the steady state thickness of passive films in order to prevent degradations of implant

Some implants have approximately a lifetime of 15 years. The femoral stem, for example, should be made of 316L/316LN stainless steel. Fretting corrosion, friction under small displacements, should occur during human gait, due to repeated loadings and un-loadings, between stainless steel and bone for instance. Some experimental investigations of fretting corrosion have been practiced. As well known, metallic alloys and especially stainless steels are covered with a passive film that prevents from the corrosion and degradation. This passive layer of few nanometers, at ambient temperature, is the key of our civilization according to some authors. This work is dedicated to predict the passive layer thicknesses of stainless steel under fretting corrosion with a specific emphasis on the role of proteins. The model is based on the Point Defect Model (micro scale) and an update of the model on the friction process (micro-macro scale). Genetic algorithm was used for finding solution of the problem. The major results are, as expected from experimental results, albumin prevents from degradation at the lowest concentration of chlorides; an incubation time is necessary for degrading the passive film; under fretting corrosion and high concentration of chlorides the passive behavior is annihilated

Mass killings and detection of impacts

Highly energetic bolide impacts occur and their flux is known. For larger bodies the energy release is greater than for any other short-term global phenomenon. Such impacts produce or release a large variety of shock induced changes including major atmospheric, sedimentologic, seismic and volcanic events. These events must necessarily leave a variety of records in the stratigraphic column, including mass killings resulting in major changes in population density and reduction or extinction of many taxonomic groups, followed by characteristic patterns of faunal and flora replacement. Of these effects, mass killings, marked by large-scale loss of biomass, are the most easily detected evidence in the field but must be manifest on a near-global scale. Such mass killings that appear to be approximately synchronous and involve disappearance of biomass at a bedding plane in many sedimentologically independent sections globally suggest a common cause and probable synchroneity. Mass killings identify an horizon which may be examined for evidence of cause. Geochemical markers may be ephemeral and absence may not be significant. There appears to be no reason why ongoing phenomena such as climate and sea-level changes are primary causes of anomolous episodic events

Investigating the Relationship between Environment and Active Galactic Nuclei activity at High Redshift

This thesis presents an investigation into the relationship between large-scale structure environment and Active Galactic Nuclei (AGN) activity at high redshift. To accomplish this, the environments of AGN are studied from two complementary perspectives. Firstly, various observations of a specific large-scale structure at z = 2.3 are used to assess the level of AGN activity in relation to the field. The main result of this study is that both the emission-line and X-ray selected AGN populations are significantly enhanced; X-ray detected Lyman Alpha Emitters (LAEs), however, are not found to be significantly enhanced. The host galaxy properties of z ~ 1 X-ray sources are then derived and studied in detail. Confirming previous results, X-ray sources are found in optically luminous (MB ~< −20.5mag), massive (log(M∗/ M⊙) ≥ 10.5) red and blue hosts. A larger fraction of red/green hosts harbour obscured (log(NH) ≥ 22) AGN than blue, with the most obscured sources (log(NH) ≥ 23.5) also being more frequently found in red/green host galaxies than blue. The second approach used the 3rd-nearest neighbour measure to study the environment of X-ray hosts at z ~ 1, accounting for their optical colour, luminosity and stellar mass. A main new and important result is that X-ray hosts are found in regions of enhanced density compared to optical galaxies of equivalent mass, which is not due to the observed colour-density relation at z ~ 1. The enhancement is found to be most significant at the reddest colours, brightest luminosities, and highest stellar masses. The results from this thesis show that the dense environments probed in this work generally promote AGN activity. This is probably not due to major mergers, but could be due to an increased probability of minor mergers/interactions and/or milder environmental processes triggering nuclear activity. Alternatively, perhaps there is some other galaxy property (e.g., residing in higher mass haloes) which is conducive to AGN activity

Studies on Pitting Corrosion of Al-Cu-Li Alloys Part III: Passivation Kinetics of AA2098-T851 Based on the Point Defect Model.

In this paper, the passivation kinetics of AA2098-T851 was investigated by a fundamental theoretical interpretation of experimental results based on the mixed potential model (MPM). The steady state passive layer formed on the AA2098-T851 in NaHCO3 solution in a CO2 atmosphere upon potentiostatic stepping in the anodic direction followed by stepping in the opposite direction was explored. Potentials were selected in a way that both anodic passive dissolution of the metal and hydrogen evolution reaction (HER) occur, thereby requiring the MPM for interpretation. Optimization of the MPM on the experimental electrochemical impedance spectroscopy (EIS) data measured after each potentiostatic step revealed the important role of the migration of Al interstitials in determining the kinetics of passive layer formation and dissolution. More importantly, it is shown that the inequalities of the kinetics of formation and dissolution of the passive layer as observed in opposite potential stepping directions lead to the irreversibility of the passivation process. Finally, by considering the Butler-Volmer (B-V) equation for the cathodic reaction (HER) in the MPM, and assuming the quantum mechanical tunneling of the charge carriers across the barrier layer of the passive film, it was shown that the HER was primarily controlled by the slow electrochemical discharge of protons at the barrier layer/solution (outer layer) interface

Astrometry and Exoplanets: the Gaia Era, and Beyond

The wealth of information in the Gaia catalogue of exoplanets will constitute a fundamental contribution to several hot topics of the astrophysics of planetary systems. I briefly review the potential impact of Gaia micro-arsec astrometry in several areas of exoplanet science, discuss what key follow-up observations might be required as a complement to Gaia data, and shed some light on the role of next generation astrometric facilities in the arena of planetary systems.Comment: 6 pages, 1 figure. Proceedings of the final ELSA Conference 'Gaia: at the frontiers of astrometry', Sevres (France), 7-11 June 2010. To appear in EAS Publication Series, EDP Science

Venereology at the Polyclinic: postgraduate medical education among General Practitioners in England, 1899–1914

In 1899 the British Medical Journal enthusiastically announced that a new postgraduate teaching college was to open in London. The aim of the Medical Graduates’ College and Polyclinic (MGC) was to provide continuing education to general practitioners. It drew upon emerging specialisms and in so doing built upon the generalist training received at an undergraduate level. Courses were intended to refresh knowledge and to introduce general practitioners to new knowledge claims and clinical practices. The establishment of postgraduate institutions such as the MGC marked an important stage in the development of medical education in England. Yet these institutions, and the emergence of postgraduate medical education more broadly, have been largely overlooked by historians. Moreover the history of venereological training among medical undergraduates and postgraduates alike has been overlooked. The study of such special subjects characterised postgraduate study. This article examines the dissemination of venereological knowledge among subscribers to MGC as an important case study for the development of institutionalised postgraduate medical education in England at the turn of the twentieth century

Direct Detection of Galactic Halo Dark Matter

The Milky Way Galaxy contains a large, spherical component which is believed to harbor a substantial amount of unseen matter. Recent observations indirectly suggest that as much as half of this ``dark matter'' may be in the form of old, very cool white dwarfs, the remnants of an ancient population of stars as old as the Galaxy itself. We conducted a survey to find faint, cool white dwarfs with large space velocities, indicative of their membership in the Galaxy's spherical halo component. The survey reveals a substantial, directly observed population of old white dwarfs, too faint to be seen in previous surveys. This newly discovered population accounts for at least 2% of the halo dark matter. It provides a natural explanation for the indirect observations, and represents a direct detection of Galactic halo dark matter.Comment: 13 pages, 4 figures, 1 table. Note added after Science Express online publication: This text reflects the correction of a few typographical errors in the online version of the table. It also includes the new constraint on the calculation of d_max which accounts for the fact that the survey could not have detected stars with proper motions below 0.33 arcseconds per year. Published online at ScienceExpress www.sciencemag.org 22 March 2001; 10.1126/science.1059954; To appear in Science 27 April 200

Studies on Pitting Corrosion of Al-Cu-Li Alloys Part II: Breakdown Potential and Pit Initiation.

Prediction of the accumulated pitting corrosion damage in aluminum-lithium (Al-Li) is of great importance due to the wide application of these alloys in the aerospace industry. The Point Defect Model (PDM) is arguably one of the most well-developed techniques for evaluating the electrochemical behavior of passive metals. In this paper, the passivity breakdown and pitting corrosion performance of AA 2098-T851 was investigated using the PDM with the potentiodynamic polarization (PDP) technique in NaCl solutions at different scan rates, Cl- concentrations and pH. Both the PDM predictions and experiments reveal linear relationships between the critical breakdown potential (Ec) of the alloy and various independent variables, such as aCl- and pH. Optimization of the PDM of the near-normally distributed Ec as measured in at least 20 replicate experiments under each set of conditions, allowing for the estimation of some of the critical parameters on barrier layer generation and dissolution, such as the critical areal concentration of condensed cation vacancies (ξ) at the metal/barrier layer interface and the mean diffusivity of the cation vacancy in the barrier layer (D). With these values obtained-using PDM optimization-in one set of conditions, the Ec distribution can be predicted for any other set of conditions (combinations of aCl-, pH and T). The PDM predictions and experimental observations in this work are in close agreement

Ichthyological Bulletin of the J.L.B. Smith Institute of Ichthyology; No. 37

Lethrinops argentea Ahl, L. lethrinus (Gunther) and L. leptodon Regan are re-described and illustrated. An additional new species, L. longipinnis, sharing with the above the possession a steeply sloping, wedge-shaped snout, a slender lower pharyngeal bone and few (9—14) gillrakers is described. The status of L. lunaris Trewavas is discussed.Rhodes University Libraries (Digitisation