910 research outputs found
Molecular junctions for thermal transport between graphene nanoribbons: covalent bonding vs. interdigitated chains
Proper design and manufacturing thermal bridges based on molecular junctions
at the contact between graphene platelets or other thermally conductive
nanoparticles would provide a fascinating way to produce efficient heat
transport networks for the exploitation in heat management applications. In
this work, using Non Equilibrium Molecular Dynamics, we calculated thermal
conductance of alkyl chains used as molecular junctions between two graphene
nanoribbons, both as covalently bound and Van der Waals interdigitated chains.
Effect of chain length, grafting density, temperature and chain interdigitation
were systematically studied. A clear reduction of conductivity was found with
increasing chain length and decreasing grafting density, while lower
conductivity was observed for Van der Waals interdigitated chains compared to
covalently bound ones. The importance of molecular junctions in enhancing
thermal conductance at graphene nanoribbons contacts was further evidenced by
calculating the conductance equivalence between a single chain and an
overlapping of un-functionalized graphene sheets. As an example, one single
pentyl covalently bound chain was found to have a conductance equivalent to the
overlapping of an area corresponding to about 152 carbon atoms. These results
contribute to the understanding of thermal phenomena occurring within networks
of thermally conductive nanoparticles, including graphene nanopapers and
graphene-based polymer nanocomposites, which are or high interest for the heat
management application in electronics and generally in low-temperature heat
exchange and recovery
Computational modeling of thermal interfaces in graphene based nanostructures
L'abstract è presente nell'allegato / the abstract is in the attachmen
A Multiscale Investigation on the Thermal Transport in Polydimethylsiloxane Nanocomposites: Graphene vs. Borophene
Graphene and borophene are highly attractive two-dimensional materials with outstanding physical properties. In this study we employed combined atomistic continuum multi-scale modeling to explore the effective thermal conductivity of polymer nanocomposites made of polydimethylsilox-ane (PDMS) polymer as the matrix and graphene and borophene as nanofillers. PDMS is a versatile polymer due to its chemical inertia, flexibility and a wide range of properties that can be tuned during synthesis. We first conducted classical Molecular Dynamics (MD) simulations to calculate the thermal conductance at the interfaces between graphene and PDMS and between borophene and PDMS. Acquired results confirm that the interfacial thermal conductance between nanosheets and polymer increases from the single-layer to multilayered nanosheets and finally converges, in the case of graphene, to about 30 MWm−2 K−1 and, for borophene, up to 33 MWm−2 K−1. The data provided by the atomistic simulations were then used in the Finite Element Method (FEM) simulations to evaluate the effective thermal conductivity of polymer nanocomposites at the continuum level. We explored the effects of nanofiller type, volume content, geometry aspect ratio and thickness on the nanocomposite effective thermal conductivity. As a very interesting finding, we found that borophene nanosheets, despite having almost two orders of magnitude lower thermal conductivity than graphene, can yield very close enhancement in the effective thermal conductivity in comparison with graphene, particularly for low volume content and small aspect ratios and thicknesses. We conclude that, for the polymer-based nanocomposites, significant improvement in the thermal conductivity can be reached by improving the bonding between the fillers and polymer, or in other words, by enhancing the thermal conductance at the interface. By taking into account the high electrical conductivity of borophene, our results suggest borophene nanosheets as promising nanofillers to simultaneously enhance the polymers’ thermal and electrical conductivity
Unexpected discovery of surgical gauze during a robotic radical prostatectomy identified as a capturing lymph node on magnetic resonance
Multiparametric magnetic resonance, plays a crucial role in several steps of the management of prostate cancer.
Various factors could alter the interpretation and reduce the accuracy of MR. Among these the group of the
retained surgical items, can produce serious implications for the health of patient, as well as medical-legal
consequences. Here we report the case of a patient, with a prostate tumor, who performed a mp-MRI of the
prostate, where it was reported as collateral finding, compatible thesis with lymphadenopathy. During robotic
assisted radical prostatectomy, was found a gauze, which persisted asymptomatic, retained after a previous right inguinal hernioplast
Edge-Grafted Molecular Junctions between Graphene Nanoplatelets: Applied Chemistry to Enhance Heat Transfer in Nanomaterials
The edge-functionalization of graphene nanoplatelets (GnP) was carried out
exploiting diazonium chemistry, aiming at the synthesis of edge decorated
nanoparticles to be used as building blocks in the preparation of engineered
nanostructured materials for enhanced heat transfer. Indeed, both phenol
functionalized and dianiline-bridged GnP (GnP-OH and E-GnP, respectively) were
assembled in nanopapers exploiting the formation of non-covalent and covalent
molecular junctions, respectively. Molecular dynamics allowed to estimate the
thermal conductance for the two different types of molecular junction,
suggesting a factor 6 between conductance of covalent vs. non-covalent
junctions. Furthermore, the chemical functionalization was observed to drive
the self-organization of the nanoflakes into the nanopapers, leading to a 20%
enhancement of the thermal conductivity for GnP-OH and E-GnP while the cross
plane thermal conductivity was boosted by 150% in the case of E-GnP. The
application of chemical functionalization to the engineering of contact
resistance in nanoparticles network was therefore validated as a fascinating
route for the enhancement of heat exchange efficiency on nanoparticle networks,
with great potential impact in low-temperature heat exchange and recovery
application
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