Hot Corrosion of Weldments

Hot corrosion of the weldment is the result of the reaction between oxidation and sulfidation, which affects welded joints exposed to combustion gases containing sulfate coal ash at high temperature. It is also demonstrated that welding processes, weld consumables, temperature of exposure, and mixture of salt environment are important factors in hot corrosion of the weldment

Biological effects of power frequency magnetic fields: Neurochemical and toxicological changes in developing chick embryos

BACKGROUND: There are several reports that indicate a linkage between exposure to power frequency (50 – 60 Hz) magnetic fields with abnormalities in the early embryonic development of the chicken. The present study was designed to understand whether power frequency electromagnetic fields could act as an environmental insult and invoke any neurochemical or toxicological changes in developing chick embryo model. METHODS: Fertilized chicken eggs were subjected to continuous exposure to magnetic fields (50 Hz) of varying intensities (5, 50 or 100 μT) for a period of up to 15 days. The embryos were taken out of the eggs on day 5, day 10 and day 15. Neurochemical (norepinephrine and 5-hydroxytryptamine) and amino acid (tyrosine, glutamine and tryptophan) contents were measured, along with an assay of the enzyme glutamine synthetase in the brain. Preliminary toxicological investigations were carried out based on aminotransferases (AST and ALT) and lactate dehydrogenase activities in the whole embryo as well as in the liver. RESULTS: The study revealed that there was a significant increase (p < 0.01 and p < 0.001) in the level of norepinephrine accompanied by a significant decrease (p < 0.01 and p < 0.001) in the tyrosine content in the brain on day 15 following exposure to 5, 50 and 100 μT magnetic fields. There was a significant increase (p < 0.001) in glutamine synthetase activity resulting in the significantly enhanced (p < 0.001) level of glutamine in the brain on day 15 (for 100 μT only). The possible mechanisms for these alterations are discussed. Further, magnetic fields had no effect on the levels of tryptophan and 5-hydroxytryptamine in the brain. Similarly, there was no effect on the activity of either aminotransferases or lactate dehydrogenase in the whole embryo or liver due to magnetic field exposure. CONCLUSIONS: Based on these studies we conclude that magnetic field-induced changes in norepinephrine levels might help explain alterations in the circadian rhythm, observed during magnetic field stress. Also, the enhanced level of glutamine can act as a contributing factor for developmental abnormalities

Mechanical Characterization of Monel 400 and 316 Stainless Steel Weldments

AbstractDissimilar combinations of Monel 400 and austenitic stainless steel AISI 316 is widely used in the petrochemical, nuclear industries where the weldments are usually subjected to hot corrosion. This paper deals with the assessment of metallurgical and mechanical properties of these bimetallic joints obtained by Gas Tungsten Arc Welding process using ERNiCrMo-3 filler metal. A detailed structure- property relationship was made on these bimetallic joints using the combined techniques of optical microscopy, SEM/EDAX analysis

Synthesis and Antimicrobial Activity of 2-(Aminoacid ester)-3-(6-methyl-2-pyridyl)-3,4-dihydro-2H-1,3,2 &#955;5- benzoxazaphosphinin-2-thiones

Synthesis of 2-(aminoacid ester)-3-(6-methyl-2-pyridyl)-3,4-dihydro-2H-1,3,2λ5-benzoxazaphosphinin-2-thiones (3a–j) was accomplished through a two-step process. It involves the prior preparation of 2-chloro-3-(6-methyl-2-pyridyl)-3,4-dihydro-2H-1,3,2λ5-benzoxazaphosphinin-2-thione monochloride (2) and its subsequent reaction with the aminoacid ester hydrochlorides in dry tetrahydrofuran-toluene in the presence of triethylamine at various temperatures. These compounds were characterizedby IR, 1H, 13C, 31P NMR and mass spectral data.Keywords: 2-[(6-methyl-2-pyridyl) amino] methylphenol, 1,3,2-benzoxazaphosphinin-2-thione, antimicrobial activit

An unusual reaction of 2-amino-4-chlorophenol with arylphosphorothioic dichlorides

1053-105

Effect of grain boundary precipitation on the mechanical integrity of EBW joints of Inconel 625

The precipitation effects on the mechanical behavior of electron beam welded joints of Inconel 625 in the as-welded [AW] and post-weld heat treatment [PWHT] conditions have been investigated in this research study. A PWHT comprising of direct aging [DA] treatment at 700 °C for 100 h in vacuum at a pressure of 10−5 mbar was performed on the weld joints. The microstructure of the base alloy opined the precipitation of MC system carbides and γ′′ strengthening phase after subjecting to DA. Also, Nb–Mo rich precipitates and the Laves phase was noticed in the inter-dendritic arms of the fusion zone (FZ) of welded joints in the AW conditions. DA treatment has a notable effect on the weld mechanical characteristics of Inconel 625 joints. The precipitation of γ′′ strengthening phase is reasoned for the significant rise in the yield strength [YS] and tensile strength [TS] of the base alloy and EBW joints

Synthesis and antimicrobial activity of 2-substituted-6-chloro-8-nitro-4-trichloromethyl-4<i>H</i>-1,3,2-benzodioxaphosphorin 2-oxides

317-320A series of 2-aryloxy/2-arylthio-6-chloro-8-nitro-4-trichloromethyl-4H-1,3,2-benzodioxaphosphorin 2-oxides 3 have been synthesized by-reacting 2-(2,2,,2-trichloro-1-hydroxyethyl)-4-chloro-6-nitrophenol 1 with different arylphosphorodichloridates 2 in the presence of triethylamine at 70-80°C. Some of these compounds are prepared by reacting the monochloride, 2-chloro- 6-chloro-8-nitro-4-trichloromethyl-4H-1, 3, 2-benzodioxaphosphorin 2-oxide 4, in situ with substituted phenol and thiols 5. The monochloride is prepared by condensing 2-(2,2,2-trichloro-1-hydroxyethyl)- 4-chloro-6-nitrophenol with phosphorus oxychloride. IR, 1H, 13C and 31P NMR and mass spectral data have been discussed. Some of these compounds have been screened for their antibacterial and antifungal activities