7 research outputs found

    Method of assembling a thermal expansion compensator

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    A thermal expansion compensator is provided and includes a first electrode structure having a first surface, a second electrode structure having a second surface facing the first surface and an elastic element bonded to the first and second surfaces and including a conductive element by which the first and second electrode structures electrically and/or thermally communicate, the conductive element having a length that is not substantially longer than a distance between the first and second surfaces

    Thermal expansion compensator having an elastic conductive element bonded to two facing surfaces

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    A thermal expansion compensator is provided and includes a first electrode structure having a first surface, a second electrode structure having a second surface facing the first surface and an elastic element bonded to the first and second surfaces and including a conductive element by which the first and second electrode structures electrically and/or thermally communicate, the conductive element having a length that is not substantially longer than a distance between the first and second surfaces

    High Temperature Stable Nanocrystalline SiGe Thermoelectric Material

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    A method of forming a nanocomposite thermoelectric material having microstructural stability at temperatures greater than 1000 C. The method includes creating nanocrystalline powder by cryomilling. The method is particularly useful in forming SiGe alloy powder

    Poly(amide-imide)/Silica Supported PEI Hollow Fiber Sorbents for Postcombustion CO 2

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    Amine-loaded poly(amide-imide) (PAI)/silica hollow fiber sorbents are created and used in a rapid temperature swing adsorption (RTSA) system for CO₂ capture under simulated postcombustion flue gas conditions. Poly(ethylenimine) (PEI) is infused into the PAI/mesoporous silica hollow fiber sorbents during fiber solvent exchange steps after fiber spinning. A lumen-side barrier layer is also successfully formed on the bore side of PAI/silica hollow fiber sorbents by using a mixture of Neoprene with cross-linking agents in a post-treatment process. The amine loaded fibers are tested in shell-and-tube modules by exposure on the shell side at 1 atm and 35°C to simulated flue gas with an inert tracer (14 mol % CO2, 72 mol % N2, and 14 mol % He, at 100% relative humidity (RH)). The fibers show a breakthrough CO₂ capacity of 0.85 mmol/g-fiber and a pseudoequilibrium CO₂ uptake of 1.19 mmol/g-fiber. When tested in the temperature range of 35-75°C, the PAI/silica/PEI fiber sorbents show a maximum CO₂ capacity at 65°C, owing to a trade-off between thermodynamic and kinetic factors. To overcome mass transfer limitations in rigidified PEI infused in the silica, an alternate PEI infusion method using a glycerol/PEI/methanol mixture is developed, and the CO₂ sorption performance is improved significantly, effectively doubling the functional sorption capacity. Specifically, the glycerol-plasticized sorbents are found to have a breakthrough and equilibrium CO₂ capacity of 1.3 and 2.0 mmol/g of dry fiber sorbent at 35°C, respectively. Thus, this work demonstrates two PAI-based sorbents that are optimized for different sorption conditions with the PAI/silica/PEI sorbents operating effectively at 65°C and the PAI/silica/PEI-glycerol sorbents operating well at 35°C with significantly improved sorption capacity
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