29,400 research outputs found

    Ferroelectricity in (K@C60_{60})n_n

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    A theoretical analysis of the ground state of long-chain (K@C60_{60})n_n is presented. Within mean field theory, a ferroelectric ground state is found to be stable because of the pseudo-Jahn-Teller mixing of the b1u_{1u} and the b2g_{2g} band with a zone-center optical phonon involving the displacement of the endohedral K^+ ions. A phase diagram for this model is derived in the narrow bandwidth regime.Comment: 6 pages, 4 figure

    Predictability of seasonal runoff in the Mississippi River basin

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    Recent advances in climate prediction and remote sensing offer the potential to improve long-lead streamflow forecasts and to provide better land surface state estimates at the time of forecast. We characterize predictability of runoff at seasonal timescales in the Mississippi River basin due to climatic persistence (represented by El Niño-Southern Oscillation and the Arctic Oscillation) and persistence related to the initial land surface state (soil moisture and snow). These climate and land surface state indicators, at varying lead times, are then used in a multiple linear regression to explain the variance of seasonal average runoff. Soil moisture dominates runoff predictability for lead times of 1 1/2 months, except in summer in the western part of the basin, where snow dominates. For the western part of the basin, the land surface state has a stronger predictive capability than climate indicators through leads of two seasons; climate indicators are more important in the east at lead times of one season or greater. Modest winter runoff predictability exists at a lead time of 3 seasons due to both climate and soil moisture, but this is in areas producing little runoff and is therefore of lessened importance. Local summer runoff predictability is limited to the western mountainous areas (generating high runoff) through a lead of 2 seasons. This could be useful to water managers in the western portion of the Mississippi River basin, because it suggests the potential to provide skillful forecast information earlier in the water year than currently used in operational forecasts

    Common problems and pitfalls in gear design

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    There are several pitfalls and problems associated with the successful design of a new gear transmission. A new design will require the knowledge and experience of several technical areas of engineering. Most of the pitfalls and problems associated with a new design are related to an inadequate evaluation of several areas, such as, the lubrication and cooling requirements, complete static and dynamic load analysis, evaluation of materials and heat treatment and the latest manufacturing technology. Some of the common problems of the gear design process are discussed with recommendations made for avoiding these conditions

    Improvement in surface fatigue life of hardened gears by high-intensity shot peening

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    Two groups of carburized, hardened, and ground spur gears that were manufactured from the same heat vacuum induction melted vacuum arc melted (VIM VAR) AISI 9310 steel were endurance tested for surface fatigue. Both groups were manufactured with a standard ground 16 rms surface finish. One group was subjected to a shot peening (SP) intensity of 7 to 9A, and the second group was subjected to a SP intensity of 15 to 17A. All gears were honed after SP to a surface finish of 16 rms. The gear pitch diameter was 8.89 cm. Test conditions were a maximum Hertz stress of 1.71 GPa, a gear temperature of 350 K, and a speed of 10000 rpm. The lubricant used for the tests was a synthetic paraffinic oil with an additive package. The following results were obtained: The 10 pct. surface fatigue (pitting) life of the high intensity (15 to 17A) SPed gears was 2.15 times that of the medium intensity (7 to 9A) SPed gears, the same as that calculated from measured residual stress at a depth of 127 microns. The measured residual stress for the high intensity SPed gears was 57 pct. higher than that for the medium intensity SPed gears at a depth of 127 microns and 540 pct. higher at a depth of 51 microns
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