494 research outputs found
Correlation between electric-field-induced phase transition and piezoelectricity in lead zirconate titanate films
We observed that electric field induces phase transition from tetragonal to
rhombohedral in polycrystalline morphotropic lead zirconate titanate (PZT)
films, as reported in 2011 for bulk PZT. Moreover, we evidenced that this
field-induced phase transition is strongly correlated with PZT film
piezoelectric properties, that is to say the larger the phase transition, the
larger the longitudinal piezoelectric coefficient d 33,eff . Although d 33,eff
is already comprised between as 150 to 170 pm/V, our observation suggests that
one could obtain larger d 33,eff values, namely 250 pm/V, by optimizing the
field-induced phase transition thanks to composition fine tuning
Inverse barocaloric effects in ferroelectric BaTiO<inf>3</inf> ceramics
We use calorimetry to identify pressure-driven isothermal entropy changes in ceramic samples of the prototypical ferroelectric BaTiO3. Near the structural phase transitions at ∼400 K (cubic-tetragonal) and ∼280 K (tetragonal-orthorhombic), the inverse barocaloric response differs in sign and magnitude from the corresponding conventional electrocaloric response. The differences in sign arise due to the decrease in unit-cell volume on heating through the transitions, whereas the differences in magnitude arise due to the large volumetric thermal expansion on either side of the transitions.European Research Council (Starting Grant ID: 680032), Engineering and Physical Sciences Research Council (Grant ID: EP/M003752/1), CICyT (Spain) (Project Nos. MAT2013-40590-P and FIS2014-54734-P), DGU (Catalonia) (Project No. 2014SGR00581), SUR (DEC Catalonia), AGAUR, FNR Luxembourg through COFERMAT project, Royal SocietyThis is the final version of the article. It first appeared from American Institute of Physics Publishing via http://dx.doi.org/10.1063/1.496159
Molecular dynamics simulations of lead clusters
Molecular dynamics simulations of nanometer-sized lead clusters have been
performed using the Lim, Ong and Ercolessi glue potential (Surf. Sci. {\bf
269/270}, 1109 (1992)). The binding energies of clusters forming crystalline
(fcc), decahedron and icosahedron structures are compared, showing that fcc
cuboctahedra are the most energetically favoured of these polyhedral model
structures. However, simulations of the freezing of liquid droplets produced a
characteristic form of ``shaved'' icosahedron, in which atoms are absent at the
edges and apexes of the polyhedron. This arrangement is energetically favoured
for 600-4000 atom clusters. Larger clusters favour crystalline structures.
Indeed, simulated freezing of a 6525-atom liquid droplet produced an imperfect
fcc Wulff particle, containing a number of parallel stacking faults. The
effects of temperature on the preferred structure of crystalline clusters below
the melting point have been considered. The implications of these results for
the interpretation of experimental data is discussed.Comment: 11 pages, 18 figues, new section added and one figure added, other
minor changes for publicatio
Influence of Field-Induced Phase Transition on Poly(Vinylidene Fluoride-Trifluoroethylene-Chlorotrifluoroethylene) Strain
This work is focused on understanding the reasons behind the large electrostrictive strain of poly(vinylidene fluoride-trifluoroethylene-chlorotrifluoroethylene) terpolymer. Although a few explanations have been proposed in the literature, it remains largely unclear. Here, the role of an electrically induced phase transition is investigated. The strain in the crystalline part of the polymer is monitored using XRD while an electric field is applied onto the sample. Three regions of interest are clearly evidenced and, of particular interest, we observe a change in crystal symmetry located on the 30-70 V μm-1 range. In that region, the lattice progressively loses its hexagonal symmetry and moves toward the phase usually observed at lower temperature, with a higher polar order. In parallel, we conduct macroscopic strain measurements to compare to the XRD data. Three different regimes are also observed with a sudden increase in electrostrictive coefficient on the 30-70 V μm-1 interval, going from 19 to 33 m4C-1. This corresponds to a 1% strain, i.e., 25% of the total deformation measured at 100 V μm-1. By thoroughly comparing macroscopic strain and x-ray measurements, we are able to single out and quantify the impact of this field-induced phase transition in the polymer overall strain.P.L. and E.D. thank FNR (Fonds National de la Recherche) for partly funding this research through the project CAMELHEAT C17/MS/11703691/Defay. Sylvie Tencé-Girault’s contribution is achieved within the frame-work of the Industrial Chair Arkema (Arkema/CNRS-ENSAM-Cnam)
Dark-Photon Search using Data from CRESST-II Phase 2
Identifying the nature and origin of dark matter is one of the major
challenges for modern astro and particle physics. Direct dark-matter searches
aim at an observation of dark-matter particles interacting within detectors.
The focus of several such searches is on interactions with nuclei as provided
e.g. by Weakly Interacting Massive Particles. However, there is a variety of
dark-matter candidates favoring interactions with electrons rather than with
nuclei. One example are dark photons, i.e., long-lived vector particles with a
kinetic mixing to standard-model photons. In this work we present constraints
on this kinetic mixing based on data from CRESST-II Phase 2 corresponding to an
exposure before cuts of 52\,kg-days. These constraints improve the existing
ones for dark-photon masses between 0.3 and 0.7\,keV/c.Comment: submitted EPJ
Results on MeV-scale dark matter from a gram-scale cryogenic calorimeter operated above ground
Models for light dark matter particles with masses below 1 GeV/c are a
natural and well-motivated alternative to so-far unobserved weakly interacting
massive particles. Gram-scale cryogenic calorimeters provide the required
detector performance to detect these particles and extend the direct dark
matter search program of CRESST. A prototype 0.5 g sapphire detector developed
for the -cleus experiment has achieved an energy threshold of
eV, which is one order of magnitude lower than previous
results and independent of the type of particle interaction. The result
presented here is obtained in a setup above ground without significant
shielding against ambient and cosmogenic radiation. Although operated in a
high-background environment, the detector probes a new range of light-mass dark
matter particles previously not accessible by direct searches. We report the
first limit on the spin-independent dark matter particle-nucleon cross section
for masses between 140 MeV/c and 500 MeV/c.Comment: 6 pages, 6 figures, v3: ancillary files added, v4: high energy
spectrum (0.6-12keV) added to ancillary file
Limits on Dark Matter Effective Field Theory Parameters with CRESST-II
CRESST is a direct dark matter search experiment, aiming for an observation
of nuclear recoils induced by the interaction of dark matter particles with
cryogenic scintillating calcium tungstate crystals. Instead of confining
ourselves to standard spin-independent and spin-dependent searches, we
re-analyze data from CRESST-II using a more general effective field theory
(EFT) framework. On many of the EFT coupling constants, improved exclusion
limits in the low-mass region (< 3-4 GeV) are presented.Comment: 7 pages, 9 figure
Final results of the EDELWEISS-II WIMP search using a 4-kg array of cryogenic germanium detectors with interleaved electrodes
The EDELWEISS-II collaboration has completed a direct search for WIMP dark
matter with an array of ten 400-g cryogenic germanium detectors in operation at
the Laboratoire Souterrain de Modane. The combined use of thermal phonon
sensors and charge collection electrodes with an interleaved geometry enables
the efficient rejection of gamma-induced radioactivity as well as near-surface
interactions. A total effective exposure of 384 kg.d has been achieved, mostly
coming from fourteen months of continuous operation. Five nuclear recoil
candidates are observed above 20 keV, while the estimated background is 3.0
events. The result is interpreted in terms of limits on the cross-section of
spin-independent interactions of WIMPs and nucleons. A cross-section of
4.4x10^-8 pb is excluded at 90%CL for a WIMP mass of 85 GeV. New constraints
are also set on models where the WIMP-nucleon scattering is inelastic.Comment: 23 pages, 5 figures; matches published versio
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