We observed that electric field induces phase transition from tetragonal to
rhombohedral in polycrystalline morphotropic lead zirconate titanate (PZT)
films, as reported in 2011 for bulk PZT. Moreover, we evidenced that this
field-induced phase transition is strongly correlated with PZT film
piezoelectric properties, that is to say the larger the phase transition, the
larger the longitudinal piezoelectric coefficient d 33,eff . Although d 33,eff
is already comprised between as 150 to 170 pm/V, our observation suggests that
one could obtain larger d 33,eff values, namely 250 pm/V, by optimizing the
field-induced phase transition thanks to composition fine tuning
