74 research outputs found

    The MOSDEF Survey: the Variation of the Dust Attenuation Curve with Metallicity

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    We derive the UV-optical stellar dust attenuation curve of galaxies at z=1.4-2.6 as a function of gas-phase metallicity. We use a sample of 218 star-forming galaxies, excluding those with very young or heavily obscured star formation, from the MOSFIRE Deep Evolution Field (MOSDEF) survey with Hα\alpha, HÎČ\beta, and [NII]λ6585\lambda 6585 spectroscopic measurements. We constrain the shape of the attenuation curve by comparing the average flux densities of galaxies sorted into bins of dust obscuration using Balmer decrements, i.e., Hα\alpha-to-HÎČ\beta luminosities. The average attenuation curve for the high-metallicity sample (12+log(O/H)>8.5, corresponding to M∗≳1010.4 M⊙M_*\gtrsim10^{10.4}\,M_{\odot}) has a shallow slope, identical to that of the Calzetti local starburst curve, and a significant UV 2175A extinction bump that is ∌0.5×\sim 0.5\times the strength of the Milky Way bump. On the other hand, the average attenuation curve of the low-metallicity sample (12+log(O/H) ∌8.2−8.5\sim 8.2-8.5) has a steeper slope similar to that of the SMC curve, only consistent with the Calzetti slope at the 3σ3\sigma level. The UV bump is not detected in the low-metallicity curve, indicating the relative lack of the small dust grains causing the bump at low metallicities. Furthermore, we find that on average the nebular reddening (E(B-V)) is a factor of 2 times larger than that of the stellar continuum for galaxies with low metallicities, while the nebular and stellar reddening are similar for galaxies with higher metallicities. The latter is likely due to a high surface density of dusty clouds embedding the star forming regions but also reddening the continuum in the high-metallicity galaxies.Comment: 20 pages and 9 figures and 1 appendix, accepted for publication in Ap

    Photoreduction of anthracenes catalyzed by peri ‐xanthenoxanthene: a scalable and sustainable Birch‐type alternative

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    The typical Birch reduction transforms arenes into cyclohexa‐1,4‐dienes by using alkali metals, an alcohol as a proton source, and an amine as solvent. Capitalizing on the strong photoreductive properties of peri‐xanthenoxanthene (PXX), herein we report the photocatalyzed “Birch‐type” reduction of acenes by employing visible blue light irradiation at room temperature in the presence of air. Upon excitation at 405 or 460 nm in the presence of a mixture of N, N‐diisopropylethylamine (DIPEA) and trifluoromethanesulfonimide (HNTf2) in DMSO, PXX photocatalyzes the selective reduction of full‐carbon acene derivatives (24–75 %). Immobilization of PXX onto polydimethylsiloxane (PDMS) beads (PXX‐PDMS) allowed the use of the catalyst in heterogeneous batch reactions, giving 9‐phenyl‐9,10‐dihydroanthracene in high yield (68 %). The catalyst could easily be recovered and reused, with no notable drop in performance observed after five reaction cycles. Integration of the PXX‐PDMS beads into a microreactor enabled the reduction of acenes under continuous‐flow conditions, thereby validating the sustainability and scalability of this heterogeneous‐phase approach

    Multiplex PCR for detection of plasmid-mediated colistin resistance determinants, mcr-1, mcr-2, mcr-3, mcr-4 and mcr-5 for surveillance purposes

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    International audiencePlasmid-mediated colistin resistance mechanisms have been identified worldwide in the past years. A multiplex polymerase chain reaction (PCR) protocol for detection of all currently known transferable colistin resistance genes (mcr-1 to mcr-5, and variants) in Enterobacteriaceae was developed for surveillance or research purposes. Methods: We designed four new primer pairs to amplify mcr-1, mcr-2, mcr-3 and mcr-4 gene products and used the originally described primers for mcr-5 to obtain a stepwise separation of ca 200 bp between amplicons. The primer pairs and amplification conditions allow for single or multiple detection of all currently described mcr genes and their variants present in Enterobacteriaceae. The protocol was validated testing 49 European Escherichia coli and Salmonella isolates of animal origin. Results: Multiplex PCR results in bovine and porcine isolates from Spain, Germany, France and Italy showed full concordance with whole genome sequence data. The method was able to detect mcr-1, mcr-3 and mcr-4 as singletons or in different combinations as they were present in the test isolates. One new mcr-4 variant, mcr-4.3, was also identified. Conclusions: This method allows rapid identification of mcr-positive bacteria and overcomes the challenges of phenotypic detection of colistin resistance. The multiplex PCR should be particularly interesting in settings or laboratories with limited resources for performing genetic analysis as it provides information on the mechanism of colistin resistance without requiring genome sequencing

    Neural Network Based Approach to Recognition of Meteor Tracks in the Mini-EUSO Telescope Data

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    Mini-EUSO is a wide-angle fluorescence telescope that registers ultraviolet (UV) radiation in the nocturnal atmosphere of Earth from the International Space Station. Meteors are among multiple phenomena that manifest themselves not only in the visible range but also in the UV. We present two simple artificial neural networks that allow for recognizing meteor signals in the Mini-EUSO data with high accuracy in terms of a binary classification problem. We expect that similar architectures can be effectively used for signal recognition in other fluorescence telescopes, regardless of the nature of the signal. Due to their simplicity, the networks can be implemented in onboard electronics of future orbital or balloon experiments.Comment: 15 page

    Internet of Things in Sustainable Energy Systems

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    Our planet has abundant renewable and conventional energy resources but technological capability and capacity gaps coupled with water-energy needs limit the benefits of these resources to citizens. Through IoT technology solutions and state-of-the-art IoT sensing and communications approaches, the sustainable energy-related research and innovation can bring a revolution in this area. Moreover, by the leveraging current infrastructure, including renewable energy technologies, microgrids, and power-to-gas (P2G) hydrogen systems, the Internet of Things in sustainable energy systems can address challenges in energy security to the community, with a minimal trade-off to environment and culture. In this chapter, the IoT in sustainable energy systems approaches, methodologies, scenarios, and tools is presented with a detailed discussion of different sensing and communications techniques. This IoT approach in energy systems is envisioned to enhance the bidirectional interchange of network services in grid by using Internet of Things in grid that will result in enhanced system resilience, reliable data flow, and connectivity optimization. Moreover, the sustainable energy IoT research challenges and innovation opportunities are also discussed to address the complex energy needs of our community and promote a strong energy sector economy

    Customer & Employee Satisfaction in the Health Service Sector: Analysis and Measurement Methodologies

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    In order measure the competitiveness of a local Health Service organisation it is necessary to analyse not only internal performance levels but also the perceived quality of the services provided and the level of customer satisfaction attained; this is directly linked to the management aspects of the Healthcare provider. Therefore we suggest performing a comparison between the external and internal ‘image’ of the structure. In addition, having specified a global subjective measure of satisfaction, we will perform a comparison between customer and employee satisfaction. We will illustrate the results of a survey, carried out on two subject samples (customers and employees of the Healthcare provider in question) to which two different types of questionnaire, similar for some items, are provided.Customer Satisfaction, Employee Satisfaction, External Image, Internal Image,

    ConsĂ©quences de la crĂ©ation de l’aire marine rĂ©gionale du PrĂȘcheur (Martinique) sur la pĂȘche martiniquaise

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    The creation of regional marine reserve of PrĂȘcheur will lead to the implementation of fisheries management measures within the perimeter of the reserve. From a short-term perspective, fishers will see limitations of their fishing practices. But, from a longer-term perspective, they should gain substantial benefits from these restrictions; the increase of biomass due to the “reserve effect” should lead to increased volumes of catches in fishing areas. It should also lead to an enhancement of traditional practices such as line fishing, jig or “piscine” fishing, which have been abandoned for several years in spite of their lesser impact on marine ecosystems
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