The British Geological Survey's new Geomagnetic Data Web Service

Increasing demand within the geomagnetism community for high quality real-time or near-real-time observatory data means there is a requirement for data producers to have a robust and scalable data processing infrastructure capable of delivering geomagnetic data products over the Internet in a variety of formats. We describe a new software system, developed at BGS, which will allow access to our geomagnetic data products both within our organisation's intranet and over the Internet. We demonstrate how the system is designed to afford easy access to the data by a wide range of software clients and allow rapid development of software utilizing our observatory data

High-shock FM transmitter Final report, phase I

Electronic component testing of high-shock FM TRANSMITTER

D1 and D5-Brane Actions in AdS_m x S^n

The kappa-invariant and supersymmetric actions of D1 and D5-branes in AdS_3 x S^3 are investigated, as well as the action of a D5-brane in an AdS_5 x S^5 background. The action of a D5-brane lying totally in an AdS_3 x S^3 background is found. Some progress was made towards finding the action for the D5-brane free to move in the whole AdS_3 x S^3 x T^4 space, however the supersymmetric action found here is not kappa-invariant and the reasons the method used did not find a kappa-invariant solution are discussed.Comment: 17pp, Latex, improved explanations, a definition adde

Fabrication and test of lightweight honeycomb sandwich structures Final report

Fabrication and testing of lightweight honeycomb sandwich structure

One-loop Corrections to the S Parameter in the Four-site Model

We compute the leading chiral-logarithmic corrections to the S parameter in the four-site Higgsless model. In addition to the usual electroweak gauge bosons of the Standard Model, this model contains two sets of heavy charged and neutral gauge bosons. In the continuum limit, the latter gauge bosons can be identified with the first excited Kaluza-Klein states of the W^\pm and Z bosons of a warped extra-dimensional model with an SU(2)_L \times SU(2)_R \times U(1)_X bulk gauge symmetry. We consider delocalized fermions and show that the delocalization parameter must be considerably tuned from its tree-level ideal value in order to reconcile experimental constraints with the one-loop results. Hence, the delocalization of fermions does not solve the problem of large contributions to the S parameter in this class of theories and significant contributions to S can potentially occur at one-loop.Comment: 28 pages, 7 figure

A gallium phosphide high-temperature bipolar junction transistor

Preliminary results are reported on the development of a high temperature (350 C) gallium phosphide bipolar junction transistor (BJT) for geothermal and other energy applications. This four-layer p(+)n(-)pp(+) structure was formed by liquid phase epitaxy using a supercooling technique to insure uniform nucleation of the thin layers. Magnesium was used as the p-type dopant to avoid excessive out-diffusion into the lightly doped base. By appropriate choice of electrodes, the device may also be driven as an n-channel junction field-effect transistor. The initial design suffers from a series resistance problem which limits the transistor's usefulness at high temperatures

Calculating NMR parameters in aluminophosphates : evaluation of dispersion correction schemes

Periodic density functional theory (DFT) calculations have recently emerged as a popular tool for assigning solid-state nuclear magnetic resonance (NMR) spectra. However, in order for the calculations to yield accurate results, accurate structural models are also required. In many cases the structural model (often derived from crystallographic diffraction) must be optimised (i.e., to an energy minimum) using DFT prior to the calculation of NMR parameters. However, DFT does not reproduce weak long-range "dispersion'' interactions well, and optimisation using some functionals can expand the crystallographic unit cell, particularly when dispersion interactions are important in defining the structure. Recently, dispersion-corrected DFT (DFT-D) has been extended to periodic calculations, to compensate for these missing interactions. Here, we investigate whether dispersion corrections are important for aluminophosphate zeolites (AlPOs) by comparing the structures optimised by DFT and DFT-D (using the PBE functional). For as-made AlPOs (containing cationic structure-directing agents (SDAs) and framework-bound anions) dispersion interactions appear to be important, with significant changes between the DFT and DFT-D unit cells. However, for calcined AlPOs, where the SDA-anion pairs are removed, dispersion interactions appear much less important, and the DFT and DFT-D unit cells are similar. We show that, while the different optimisation strategies yield similar calculated NMR parameters (providing that the atomic positions are optimised), the DFT-D optimisations provide structures in better agreement with the experimental diffraction measurements. Therefore, it appears that DFT-D calculations can, and should, be used for the optimisation of calcined and as-made AlPOs, in order to provide the closest agreement with all experimental measurements.PostprintPeer reviewe

Kinetics of the reduction of metalloproteins by chromous ion

The reduction of Cu(330) in Rhus vernicifera laccase by chromous ion is 30% faster than reduction of Cu(614) at room temperature [pH 4.8, µ = 0.1 (NaCl)], and two parallel first-order paths, attributed to heterogeneity of the protein, are observed at both wavelengths. The reactions of stellacyanin, spinach and French-bean plastocyanins, and cytochrome c with chromous ion under similar conditions are faster than that with laccase by factors of 102 to 104, and are first order in protein concentration. Comparison of rates and activation parameters for the reduction of "blue" copper in laccase, stellacyanin, and the two plastocyanins indicates that reduction of the Cu(614) site in laccase may occur by intramolecular electron transfer from one of the Cu(330) sites. Our value of ΔH (17.4 kcal/mol) for the chromous ion reduction of cytochrome c is consistent with a mechanism in which major conformational changes in the protein must accompany electron transfer