14,839 research outputs found
Nuclear magnetic resonance spectroscopy: Abnormal splitting of ethyl groups due to molecular asymmetry
Nuclear magnetic resonance (n.m.r.) spectroscopy provides an excellent means for qualitative identification of ethyl groups by use of the familiar three-four pattern of spin-spin splitting (1). It has been observed previously (2) that the methylene protons of systems of the type R-CH2-CR1R2R3 (where R1 can be the same as R or different) may be magnetically nonequivalent and display AB rather than A2-type spectra (3). We now wish to report several examples of this type of behavior with ethyl groups, particularly ethoxy groups, knowledge of which could be important to anyone using n.m.r. for organic qualitative analysis
A DYNAMIC GENERAL EQUILIBRIUM ANALYSIS OF U.S. BIOFUELS PRODUCTION
With the rising global interest in energy security and climate change mitigation, biofuels have gained the prominent attention of researchers and policy makers. The U.S. has emerged as the leading producer of biofuels and is aiming for achieving a target of 36 billion gallons of renewable fuels by 2022 under its updated renewable fuels standard (RFS2) policy. In this paper, we study the longer-term global implications of large-scale renewable fuels production in the U.S. We utilize the GTAP v7.1 data base and introduce a detailed breakdown of agricultural crops, first and second generation biofuels and by-products. We update this fully disaggregated data base to reflect the 2010 global economy, based on secondary data for the sectors and regions included. We adapt the Applied Dynamic Analysis of Global Economy (ADAGE) model developed by Ross (2009) into a recursive dynamic framework and introduce agriculture, biofuels, and land use linkages. We construct a dynamic baseline from 2010 through 2050 in five-year time steps. The dynamics in the model comes from growth in GDP, population, capital accumulation, labor productivity, growth in natural resource stocks, and technological changes in the energy intensive and agricultural sectors. We implement a representative RFS2 policy scenario in the U.S for 2025, using two alternative approaches: (i) RFS permits approach – which assumes biofuels and petroleum fuels are perfect substitutes after adjusting for energy content, and (ii) Target share of biofuels in transportation fuels approach – which treats biofuels and petroleum fuels as imperfect substitutes. Both approaches offer insights regarding potential policy impacts, particularly on the international market and indirect land use change. Because the share approach keeps the biofuels share fixed in the regions outside the U.S., it does not result in dramatic changes in the rest of the world. In the permits approach, however, the regions without a specific policy requiring a given level of biofuels tend to reduce biofuels consumption. This is a result of the reduction in relative price of petroleum products as U.S. policy increases demand for biofuels and reduces global demand for petroleum, making renewable fuels less cost-competitive in the rest of the world.ADAGE, Biofuels, Computable General Equilibrium, Recursive Dynamic, Resource /Energy Economics and Policy,
Scavenger 0.1: A Theorem Prover Based on Conflict Resolution
This paper introduces Scavenger, the first theorem prover for pure
first-order logic without equality based on the new conflict resolution
calculus. Conflict resolution has a restricted resolution inference rule that
resembles (a first-order generalization of) unit propagation as well as a rule
for assuming decision literals and a rule for deriving new clauses by (a
first-order generalization of) conflict-driven clause learning.Comment: Published at CADE 201
Boston's Education Pipeline: A Report Card
Assesses the city's progress in creating an effective and equitable education pipeline from early childhood through college or postsecondary training. Examines demographic and outcome data and risk and prevention factors, and notes areas for improvement
Computer simulations of electrorheological fluids in the dipole-induced dipole model
We have employed the multiple image method to compute the interparticle force
for a polydisperse electrorheological (ER) fluid in which the suspended
particles can have various sizes and different permittivites. The point-dipole
(PD) approximation being routinely adopted in computer simulation of ER fluids
is shown to err considerably when the particles approach and finally touch due
to multipolar interactions. The PD approximation becomes even worse when the
dielectric contrast between the particles and the host medium is large. From
the results, we show that the dipole-induced-dipole (DID) model yields very
good agreements with the multiple image results for a wide range of dielectric
contrasts and polydispersity. As an illustration, we have employed the DID
model to simulate the athermal aggregation of particles in ER fluids both in
uniaxial and rotating fields. We find that the aggregation time is
significantly reduced. The DID model accounts for multipolar interaction
partially and is simple to use in computer simulation of ER fluids.Comment: 22 pages, 7 figures, submitted to Phys. Rev.
Bogoliubov angle and visualization of particle-hole mixture in superconductors
Superconducting excitations --Bogoliubov quasiparticles -- are the quantum
mechanical mixture of negatively charged electron (-e) and positively charged
hole (+e). Depending on the applied voltage bias in STM one can sample the
particle and hole content of such a superconducting excitation. Recent Scanning
Tunneling Microscope (STM) experiments offer a unique insight into the inner
workings of the superconducting state of superconductors. We propose a new
observable quantity for STM studies that is the manifestation of the
particle-hole dualism of the quasiparticles. We call it a {\em Bogoliubov
angle}. This angle measures the relative weight of particle and hole amplitude
in the superconducting (Bogoliubov) quasiparticle. We argue that this quantity
can be measured locally by comparing the ratio of tunneling currents at
positive and negative biases. This Bogoliubov angle allows one to measure
directly the energy and position dependent particle-hole admixture and
therefore visualize robustness of superconducting state locally. It may also
allow one to measure the particle-hole admixture of excitations in normal state
above critical temperature and thus may be used to measure superconducting
correlations in pseudogap state.Comment: 16 pages, latex file, 9 eps figure
CX3CR1 Polymorphisms are associated with atopy but not asthma in German children
Chemokines and their receptors are involved in many aspects of immunity. Chemokine CX3CL1, acting via its receptor CX3CR1, regulates monocyte migration and macrophage differentiation as well as T cell-dependent inflammation. Two common, nonsynonymous polymorphisms in CX3CR1 have previously been shown to alter the function of the CX3CL1/CX3CR1 pathway and were suggested to modify the risk for asthma. Using matrix-assisted laser desorption/ionization time-of-flight technology, we genotyped polymorphisms Val249Ile and Thr280Met in a cross-sectional population of German children from Munich (n = 1,159) and Dresden ( n = 1,940). For 249Ile an odds ratio of 0.77 (95% confidence interval 0.63-0.96; p = 0.017) and for 280Met an odds ratio of 0.71 ( 95% confidence interval 0.56-0.89; p = 0.004) were found with atopy in Dresden but not in Munich. Neither polymorphism was associated with asthma. Thus, amino acid changes in CX3CR1 may influence the development of atopy but not asthma in German children. Potentially, other factors such as environmental effects may modify the role of CX3CR1 polymorphisms. Copyright (c) 2007 S. Karger AG, Basel
Correspondence between solar fine-scale structures in the corona, transition region, and lower atmosphere from collaborative observations
The Soft X-Ray Imaging Payload and the High Resolution Telescope and Spectrograph (HRTS) instrument were launched from White Sands on 11 December 1987 in coordinated sounding rocket flights to investigate the correspondence of coronal and transition region structures, especially the relationship between X-ray bright points (XBPs) and transition region small spatial scale energetic events. The coaligned data from X-ray images are presented along with maps of sites of transition region energetic events observed in C IV (100,000 K), HRTS 1600 A spectroheliograms of the T sub min region and ground based magnetogram and He I 10830 A images
Ground state of a polydisperse electrorheological solid: Beyond the dipole approximation
The ground state of an electrorheological (ER) fluid has been studied based
on our recently proposed dipole-induced dipole (DID) model. We obtained an
analytic expression of the interaction between chains of particles which are of
the same or different dielectric constants. The effects of dielectric constants
on the structure formation in monodisperse and polydisperse electrorheological
fluids are studied in a wide range of dielectric contrasts between the
particles and the base fluid. Our results showed that the established
body-centered tetragonal ground state in monodisperse ER fluids may become
unstable due to a polydispersity in the particle dielectric constants. While
our results agree with that of the fully multipole theory, the DID model is
much simpler, which offers a basis for computer simulations in polydisperse ER
fluids.Comment: Accepted for publications by Phys. Rev.
Gas Accretion Traced in Absorption in Galaxy Spectroscopy
The positive velocity shift of absorption transitions tracing diffuse
material observed in a galaxy spectrum is an unambiguous signature of gas flow
toward the host system. Spectroscopy probing, e.g., NaI D resonance lines in
the rest-frame optical or MgII and FeII in the near-ultraviolet is in principle
sensitive to the infall of cool material at temperatures ~ 100-10,000 K
anywhere along the line of sight to a galaxy's stellar component. However,
secure detections of this redshifted absorption signature have proved
challenging to obtain due to the ubiquity of cool gas outflows giving rise to
blueshifted absorption along the same sightlines. In this chapter, we review
the bona fide detections of this phenomenon. Analysis of NaI D line profiles
has revealed numerous instances of redshifted absorption observed toward
early-type and/or AGN-host galaxies, while spectroscopy of MgII and FeII has
provided evidence for ongoing gas accretion onto >5% of luminous, star-forming
galaxies at z ~ 0.5-1. We then discuss the potentially ground-breaking benefits
of future efforts to improve the spectral resolution of such studies, and to
leverage spatially-resolved spectroscopy for new constraints on inflowing gas
morphology.Comment: 21 pages, 7 figures. Invited review to appear in Gas Accretion onto
Galaxies, Astrophysics and Space Science Library, eds. A. J. Fox & R. Dav\'e,
to be published by Springe
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