Nuclear magnetic resonance spectroscopy: Abnormal splitting of ethyl groups due to molecular asymmetry

Nuclear magnetic resonance (n.m.r.) spectroscopy provides an excellent means for qualitative identification of ethyl groups by use of the familiar three-four pattern of spin-spin splitting (1). It has been observed previously (2) that the methylene protons of systems of the type R-CH2-CR1R2R3 (where R1 can be the same as R or different) may be magnetically nonequivalent and display AB rather than A2-type spectra (3). We now wish to report several examples of this type of behavior with ethyl groups, particularly ethoxy groups, knowledge of which could be important to anyone using n.m.r. for organic qualitative analysis

A DYNAMIC GENERAL EQUILIBRIUM ANALYSIS OF U.S. BIOFUELS PRODUCTION

With the rising global interest in energy security and climate change mitigation, biofuels have gained the prominent attention of researchers and policy makers. The U.S. has emerged as the leading producer of biofuels and is aiming for achieving a target of 36 billion gallons of renewable fuels by 2022 under its updated renewable fuels standard (RFS2) policy. In this paper, we study the longer-term global implications of large-scale renewable fuels production in the U.S. We utilize the GTAP v7.1 data base and introduce a detailed breakdown of agricultural crops, first and second generation biofuels and by-products. We update this fully disaggregated data base to reflect the 2010 global economy, based on secondary data for the sectors and regions included. We adapt the Applied Dynamic Analysis of Global Economy (ADAGE) model developed by Ross (2009) into a recursive dynamic framework and introduce agriculture, biofuels, and land use linkages. We construct a dynamic baseline from 2010 through 2050 in five-year time steps. The dynamics in the model comes from growth in GDP, population, capital accumulation, labor productivity, growth in natural resource stocks, and technological changes in the energy intensive and agricultural sectors. We implement a representative RFS2 policy scenario in the U.S for 2025, using two alternative approaches: (i) RFS permits approach – which assumes biofuels and petroleum fuels are perfect substitutes after adjusting for energy content, and (ii) Target share of biofuels in transportation fuels approach – which treats biofuels and petroleum fuels as imperfect substitutes. Both approaches offer insights regarding potential policy impacts, particularly on the international market and indirect land use change. Because the share approach keeps the biofuels share fixed in the regions outside the U.S., it does not result in dramatic changes in the rest of the world. In the permits approach, however, the regions without a specific policy requiring a given level of biofuels tend to reduce biofuels consumption. This is a result of the reduction in relative price of petroleum products as U.S. policy increases demand for biofuels and reduces global demand for petroleum, making renewable fuels less cost-competitive in the rest of the world.ADAGE, Biofuels, Computable General Equilibrium, Recursive Dynamic, Resource /Energy Economics and Policy,

Scavenger 0.1: A Theorem Prover Based on Conflict Resolution

This paper introduces Scavenger, the first theorem prover for pure first-order logic without equality based on the new conflict resolution calculus. Conflict resolution has a restricted resolution inference rule that resembles (a first-order generalization of) unit propagation as well as a rule for assuming decision literals and a rule for deriving new clauses by (a first-order generalization of) conflict-driven clause learning.Comment: Published at CADE 201

Boston's Education Pipeline: A Report Card

Assesses the city's progress in creating an effective and equitable education pipeline from early childhood through college or postsecondary training. Examines demographic and outcome data and risk and prevention factors, and notes areas for improvement

Computer simulations of electrorheological fluids in the dipole-induced dipole model

We have employed the multiple image method to compute the interparticle force for a polydisperse electrorheological (ER) fluid in which the suspended particles can have various sizes and different permittivites. The point-dipole (PD) approximation being routinely adopted in computer simulation of ER fluids is shown to err considerably when the particles approach and finally touch due to multipolar interactions. The PD approximation becomes even worse when the dielectric contrast between the particles and the host medium is large. From the results, we show that the dipole-induced-dipole (DID) model yields very good agreements with the multiple image results for a wide range of dielectric contrasts and polydispersity. As an illustration, we have employed the DID model to simulate the athermal aggregation of particles in ER fluids both in uniaxial and rotating fields. We find that the aggregation time is significantly reduced. The DID model accounts for multipolar interaction partially and is simple to use in computer simulation of ER fluids.Comment: 22 pages, 7 figures, submitted to Phys. Rev.

Bogoliubov angle and visualization of particle-hole mixture in superconductors

Superconducting excitations --Bogoliubov quasiparticles -- are the quantum mechanical mixture of negatively charged electron (-e) and positively charged hole (+e). Depending on the applied voltage bias in STM one can sample the particle and hole content of such a superconducting excitation. Recent Scanning Tunneling Microscope (STM) experiments offer a unique insight into the inner workings of the superconducting state of superconductors. We propose a new observable quantity for STM studies that is the manifestation of the particle-hole dualism of the quasiparticles. We call it a {\em Bogoliubov angle}. This angle measures the relative weight of particle and hole amplitude in the superconducting (Bogoliubov) quasiparticle. We argue that this quantity can be measured locally by comparing the ratio of tunneling currents at positive and negative biases. This Bogoliubov angle allows one to measure directly the energy and position dependent particle-hole admixture and therefore visualize robustness of superconducting state locally. It may also allow one to measure the particle-hole admixture of excitations in normal state above critical temperature and thus may be used to measure superconducting correlations in pseudogap state.Comment: 16 pages, latex file, 9 eps figure

CX3CR1 Polymorphisms are associated with atopy but not asthma in German children

Chemokines and their receptors are involved in many aspects of immunity. Chemokine CX3CL1, acting via its receptor CX3CR1, regulates monocyte migration and macrophage differentiation as well as T cell-dependent inflammation. Two common, nonsynonymous polymorphisms in CX3CR1 have previously been shown to alter the function of the CX3CL1/CX3CR1 pathway and were suggested to modify the risk for asthma. Using matrix-assisted laser desorption/ionization time-of-flight technology, we genotyped polymorphisms Val249Ile and Thr280Met in a cross-sectional population of German children from Munich (n = 1,159) and Dresden ( n = 1,940). For 249Ile an odds ratio of 0.77 (95% confidence interval 0.63-0.96; p = 0.017) and for 280Met an odds ratio of 0.71 ( 95% confidence interval 0.56-0.89; p = 0.004) were found with atopy in Dresden but not in Munich. Neither polymorphism was associated with asthma. Thus, amino acid changes in CX3CR1 may influence the development of atopy but not asthma in German children. Potentially, other factors such as environmental effects may modify the role of CX3CR1 polymorphisms. Copyright (c) 2007 S. Karger AG, Basel

Correspondence between solar fine-scale structures in the corona, transition region, and lower atmosphere from collaborative observations

The Soft X-Ray Imaging Payload and the High Resolution Telescope and Spectrograph (HRTS) instrument were launched from White Sands on 11 December 1987 in coordinated sounding rocket flights to investigate the correspondence of coronal and transition region structures, especially the relationship between X-ray bright points (XBPs) and transition region small spatial scale energetic events. The coaligned data from X-ray images are presented along with maps of sites of transition region energetic events observed in C IV (100,000 K), HRTS 1600 A spectroheliograms of the T sub min region and ground based magnetogram and He I 10830 A images

Ground state of a polydisperse electrorheological solid: Beyond the dipole approximation

The ground state of an electrorheological (ER) fluid has been studied based on our recently proposed dipole-induced dipole (DID) model. We obtained an analytic expression of the interaction between chains of particles which are of the same or different dielectric constants. The effects of dielectric constants on the structure formation in monodisperse and polydisperse electrorheological fluids are studied in a wide range of dielectric contrasts between the particles and the base fluid. Our results showed that the established body-centered tetragonal ground state in monodisperse ER fluids may become unstable due to a polydispersity in the particle dielectric constants. While our results agree with that of the fully multipole theory, the DID model is much simpler, which offers a basis for computer simulations in polydisperse ER fluids.Comment: Accepted for publications by Phys. Rev.

Gas Accretion Traced in Absorption in Galaxy Spectroscopy

The positive velocity shift of absorption transitions tracing diffuse material observed in a galaxy spectrum is an unambiguous signature of gas flow toward the host system. Spectroscopy probing, e.g., NaI D resonance lines in the rest-frame optical or MgII and FeII in the near-ultraviolet is in principle sensitive to the infall of cool material at temperatures ~ 100-10,000 K anywhere along the line of sight to a galaxy's stellar component. However, secure detections of this redshifted absorption signature have proved challenging to obtain due to the ubiquity of cool gas outflows giving rise to blueshifted absorption along the same sightlines. In this chapter, we review the bona fide detections of this phenomenon. Analysis of NaI D line profiles has revealed numerous instances of redshifted absorption observed toward early-type and/or AGN-host galaxies, while spectroscopy of MgII and FeII has provided evidence for ongoing gas accretion onto >5% of luminous, star-forming galaxies at z ~ 0.5-1. We then discuss the potentially ground-breaking benefits of future efforts to improve the spectral resolution of such studies, and to leverage spatially-resolved spectroscopy for new constraints on inflowing gas morphology.Comment: 21 pages, 7 figures. Invited review to appear in Gas Accretion onto Galaxies, Astrophysics and Space Science Library, eds. A. J. Fox & R. Dav\'e, to be published by Springe