Spectroscopic Examination of the Catalytic Decomposition of hydrogen Peroxide by a Copper (II) Complex of a Dissymmetric Schiff Base and an Imidazole Derivative.

Previous studies involving copper (II) complexed with a dissymmetric Schiff base and imidazole derivatives had identified catalase activity of these complexes towards H2O2. Reactions such as this are of great interest due to the important role of copper-based complexes in biological systems. Our research has been conducted to add to the base of knowledge regarding the efforts of other researchers to investigate copper complexes that exhibit similar reactivity as copper-based proteins towards dioxygen. The copper complex chosen for this study contained a tri-dentate Schiff base adduct which, when complexed with an imidazole derivative, limited the manner in which peroxo adducts could bind while providing distinct spectral peaks which were used to conduct kinetic studies. Our results indicate a reaction mechanism by which the role of the complexed copper (II) ion is to activate the peroxo adduct for decomposition through reactions with other peroxide molecules, dioxygen, and water

Nuclear magnetic resonance spectroscopy: Abnormal splitting of ethyl groups due to molecular asymmetry

Nuclear magnetic resonance (n.m.r.) spectroscopy provides an excellent means for qualitative identification of ethyl groups by use of the familiar three-four pattern of spin-spin splitting (1). It has been observed previously (2) that the methylene protons of systems of the type R-CH2-CR1R2R3 (where R1 can be the same as R or different) may be magnetically nonequivalent and display AB rather than A2-type spectra (3). We now wish to report several examples of this type of behavior with ethyl groups, particularly ethoxy groups, knowledge of which could be important to anyone using n.m.r. for organic qualitative analysis

Ventricular metastasis resulting in disseminated intravascular coagulation

BACKGROUND: Disseminated Intravascular Coagulation (DIC) complicates up to 7% of malignancies, the commonest solid organ association being adenocarcinoma. Transitional Cell Carcinoma (TCC) has rarely been associated with DIC. CASE PRESENTATION: A 74-year-old woman with TCC bladder and DIC was found to have a cardiac lesion suspicious for metastatic disease. The DIC improved with infusion of plasma and administration of Vitamin K, however the cardiac lesion was deemed inoperable and chemotherapy inappropriate; given the patients functional status. We postulate that direct activation of the coagulation cascade by the intraventricular metastasis probably triggered the coagulopathy in this patient. CONCLUSION: Cardiac metastases should be considered in cancer patients with otherwise unexplained DIC. This may influence treatment choices

EPICYSTIC SURGICAL FISTULA, FOR THE RELIEF OF VESICAL CATARRH.: Read by Title in the Section of Surgery and Anatomy, at the Fortieth Annual Meeting of the American Medical Association, June, 1889.

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Lower Extremity Strength and Mechanics During Jumping in Women With Patellofemoral Pain

Context: Lower extremity (LE) weakness might be associated with altered mechanics during weight bearing in subjects with patellofemoral pain syndrome (PFPS). Objective: To analyze LE strength, mechanics, and the association between these variables among women with and without PFPS during a simulated athletic task. Design: Case control. Setting: Motion-analysis laboratory. Subjects: 20 women with PFPS and 20 healthy women. Main Outcome Measures: Peak isometric lateral trunk-flexion, hipabduction, hip external-rotation, knee-flexion, and knee-extension strength, as well as hip- and knee-joint excursions and angular impulses during single-leg jumps. Results: PFPS subjects produced less hip-abduction, hip external-rotation, and trunk lateral- flexion force than the control group. The PFPS group also demonstrated greater hipadduction excursion and hip-abduction impulses. The association between the strength measurements and LE mechanics was low. Conclusions: Women with PFPS demonstrate specific weaknesses and altered LE mechanics. Weakness is not, however, highly correlated with observed differences in mechanics. ABSTRACT FROM AUTHO

Shoot dieback during prolonged drought in Ceanothus (Rhamnaceae) chaparral of California: a possible case of hydraulic failure

Journal ArticleProgressive diebacks of outer canopy branchlets of Ceanothus crassifolius were repeatedly observed after rainless periods up to 9 mo in duration in the Santa Monica Mountains of southern California. Mean xylem pressures of branchlets near the end of drought were as low as -11.2 MPa (N = 22) with a mean of about 60 dead branchlets per shrub

FeH Absorption in the Near-Infrared Spectra of Late M and L Dwarfs

We present medium-resolution z-, J-, and H-band spectra of four late-type dwarfs with spectral types ranging from M8 to L7.5. In an attempt to determine the origin of numerous weak absorption features throughout their near-infrared spectra, and motivated by the recent tentative identification of the E 4\Pi- A ^4\Pi system of FeH near 1.6 microns in umbral and cool star spectra, we have compared the dwarf spectra to a laboratory FeH emission spectrum. We have identified nearly 100 FeH absorption features in the z-, J-, and H-band spectra of the dwarfs. In particular, we have identified 34 features which dominate the appearance of the H-band spectra of the dwarfs and which appear in the laboratory FeH spectrum. Finally, all of the features are either weaker or absent in the spectrum of the L7.5 dwarf which is consistent with the weakening of the known FeH bandheads in the spectra of the latest L dwarfs.Comment: accepted by Ap