7,768 research outputs found

    Simple algorithm for the correction of MRI image artefacts due to random phase fluctuations

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    Grant support: This work was supported by EPSRC [grant numbers EP/E036775/1, EP/K020293/1] and received funding from the European Union's Horizon 2020 research and innovation programme [grant agreement No 668119, project “IDentIFY”]Peer reviewedPublisher PD

    Slug Damage and Control of Slugs in Horticultural Crops

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    Slugs can cause severe damage in horticultural crops. Slug activity; slug damage and control strategies differ considerably between countries or regions in Europe. The brochure summarizes recent research on novel methods of slug control

    Mineralogy and Malignant Mesothelioma: The South African Experience

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    South Africa is a uniquely mineral rich country. Of the six types of asbestiform minerals found in the country, three, namely crocidolite, amosite and chrysotile were mined and milled on a large commercial scale. Asbestos was used locally in South Africa, but the majority of its production was exported worldwide. In the 1970s, South Africa was the world’s third largest producer of asbestos, behind Canada and the USSR. About 97% of the world’s production of crocidolite and virtually all of the amosite came from South Africa. The output from the South African asbestos mining industry peaked at 380,000 tonnes in 1977 and declined thereafter as export markets declined due to restrictive legislation in countries that imported asbestos (Virta, 2006; Kielkowski et al., 2011). Legislation in South Africa banning the use of all types of asbestos came into effect in 2008, well after the last asbestos mine ceased production in 2001 and closed in 2002. Although South Africa benefitted financially from the exploitation of its asbestos mineral reserves, the revenue from asbestos never accounted for more than 3% of the value of its total minerals output (McCulloch, 2003). There is however a high price to pay in terms of a legacy of disease and environmental contamination through mining activities and the transport of asbestos and asbestos containing products

    The deposition of metal nanoparticles on carbon surfaces: the role of specific functional groups

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    The enormous complexity of a typical heterogeneous catalyst makes understanding the development and properties of any active nanoparticles present extremely challenging. In the case of carbon based catalysts that difficulty is compounded by the variability of the carbon powders used. We have previously developed a strategy that addresses these problems by mimicking the catalyst preparation conditions very closely but using highly ordered pyrolytic graphite crystals (HOPG) as a model surface. This enables us to examine the effects of specific functional groups on nanoparticle formation. We report here an extension of our work characterising functional groups on the HOPG surface, using XPS and AFM to explore the deposition of gold from aqueous solution onto HOPG surfaces treated in a variety of ways to alter the surface functionality. The structure and oxidation state of the resulting nanoparticles depend critically on the nature of the functional groups present and offers some insight into the development of catalysts based on these materials. Hydroxyls are identified as key functional species, reducing gold ions to their metallic state whilst being oxidised themselves to carbonyls. Carbonyls meanwhile promote the nucleation of Au3+, creating a network of islands at the HOPG surface. The results have relevance not only to catalysts using activated carbons but also the new generation of materials based on graphene and carbon nanotubes
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