80 research outputs found
Equation of state of cubic boron nitride at high pressures and temperatures
We report accurate measurements of the equation of state (EOS) of cubic boron
nitride by x-ray diffraction up to 160 GPa at 295 K and 80 GPa in the range
500-900 K. Experiments were performed on single-crystals embedded in a
quasi-hydrostatic pressure medium (helium or neon). Comparison between the
present EOS data at 295 K and literature allows us to critically review the
recent calibrations of the ruby standard. The full P-V-T data set can be
represented by a Mie-Gr\"{u}neisen model, which enables us to extract all
relevant thermodynamic parameters: bulk modulus and its first
pressure-derivative, thermal expansion coefficient, thermal Gr\"{u}neisen
parameter and its volume dependence. This equation of state is used to
determine the isothermal Gr\"{u}neisen mode parameter of the Raman TO band. A
new formulation of the pressure scale based on this Raman mode, using
physically-constrained parameters, is deduced.Comment: 8 pages, 7 figure
A superconductor to superfluid phase transition in liquid metallic hydrogen
Although hydrogen is the simplest of atoms, it does not form the simplest of
solids or liquids. Quantum effects in these phases are considerable (a
consequence of the light proton mass) and they have a demonstrable and often
puzzling influence on many physical properties, including spatial order. To
date, the structure of dense hydrogen remains experimentally elusive. Recent
studies of the melting curve of hydrogen indicate that at high (but
experimentally accessible) pressures, compressed hydrogen will adopt a liquid
state, even at low temperatures. In reaching this phase, hydrogen is also
projected to pass through an insulator-to-metal transition. This raises the
possibility of new state of matter: a near ground-state liquid metal, and its
ordered states in the quantum domain. Ordered quantum fluids are traditionally
categorized as superconductors or superfluids; these respective systems feature
dissipationless electrical currents or mass flow. Here we report an analysis
based on topological arguments of the projected phase of liquid metallic
hydrogen, finding that it may represent a new type of ordered quantum fluid.
Specifically, we show that liquid metallic hydrogen cannot be categorized
exclusively as a superconductor or superfluid. We predict that, in the presence
of a magnetic field, liquid metallic hydrogen will exhibit several phase
transitions to ordered states, ranging from superconductors to superfluids.Comment: for a related paper see cond-mat/0410425. A correction to the front
page caption appeared in Oct 14 issue of Nature:
http://www.nature.com/nature/links/041014/041014-11.htm
Effect of nanostructuration on compressibility of cubic BN
Compressibility of high-purity nanostructured cBN has been studied under
quasi-hydrostatic conditions at 300 K up to 35 GPa using diamond anvil cell and
angle-dispersive synchrotron X-ray powder diffraction. A data fit to the Vinet
equation of state yields the values of the bulk modulus B0 of 375(4) GPa with
its first pressure derivative B0' of 2.3(3). The nanometer grain size (\sim20
nm) results in decrease of the bulk modulus by ~9%
A quantum fluid of metallic hydrogen suggested by first-principles calculations
It is generally assumed that solid hydrogen will transform into a metallic
alkali-like crystal at sufficiently high pressure. However, some theoretical
models have also suggested that compressed hydrogen may form an unusual
two-component (protons and electrons) metallic fluid at low temperature, or
possibly even a zero-temperature liquid ground state. The existence of these
new states of matter is conditional on the presence of a maximum in the melting
temperature versus pressure curve (the 'melt line'). Previous measurements of
the hydrogen melt line up to pressures of 44 GPa have led to controversial
conclusions regarding the existence of this maximum. Here we report ab initio
calculations that establish the melt line up to 200 GPa. We predict that subtle
changes in the intermolecular interactions lead to a decline of the melt line
above 90 GPa. The implication is that as solid molecular hydrogen is
compressed, it transforms into a low-temperature quantum fluid before becoming
a monatomic crystal. The emerging low-temperature phase diagram of hydrogen and
its isotopes bears analogies with the familiar phases of 3He and 4He, the only
known zero-temperature liquids, but the long-range Coulombic interactions and
the large component mass ratio present in hydrogen would ensure dramatically
different propertiesComment: See related paper: cond-mat/041040
Structural Phase Transition at High Temperatures in Solid Molecular Hydrogen and Deuterium
We study the effect of temperature up to 1000K on the structure of dense
molecular para-hydrogen and ortho-deuterium, using the path-integral Monte
Carlo method. We find a structural phase transition from orientationally
disordered hexagonal close packed (hcp) to an orthorhombic structure of Cmca
symmetry before melting. The transition is basically induced by thermal
fluctuations, but quantum fluctuations of protons (deuterons) are important in
determining the transition temperature through effectively hardening the
intermolecular interaction. We estimate the phase line between hcp and Cmca
phases as well as the melting line of the Cmca solid.Comment: 8 pages, 7 figures; accepted in Phys. Rev.
Superhard Phases of Simple Substances and Binary Compounds of the B-C-N-O System: from Diamond to the Latest Results (a Review)
The basic known and hypothetic one- and two-element phases of the B-C-N-O
system (both superhard phases having diamond and boron structures and
precursors to synthesize them) are described. The attention has been given to
the structure, basic mechanical properties, and methods to identify and
characterize the materials. For some phases that have been recently described
in the literature the synthesis conditions at high pressures and temperatures
are indicated.Comment: Review on superhard B-C-N-O phase
Molecular carbon dioxide at high pressure and high temperature
The existence of intermediate states between the molecular and non-molecular forms of carbon dioxide has been actively debated in the recent past. Here we report new experiments at pressures up to 20 GPa and in the temperature range 300950 K. They revealed the presence of a previously unobserved molecular phase, which we identified as the theoretically predicted high-temperature Cmca phase. Its relation and relative stability with respect to the other solid phases are discussed based on spectroscopic and melting data. We show that the existence of this strictly molecular phase challenges the interpretation of phases IV and II as intermediate forms between the molecular and covalent-bonded solids
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