Methanesulfonic acid (MSA) migration in polar ice : data synthesis and theory

© The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Cryosphere 11 (2017): 2439-2462, doi:10.5194/tc-11-2439-2017.Methanesulfonic acid (MSA; CH3SO3H) in polar ice is a unique proxy of marine primary productivity, synoptic atmospheric transport, and regional sea-ice behavior. However, MSA can be mobile within the firn and ice matrix, a post-depositional process that is well known but poorly understood and documented, leading to uncertainties in the integrity of the MSA paleoclimatic signal. Here, we use a compilation of 22 ice core MSA records from Greenland and Antarctica and a model of soluble impurity transport in order to comprehensively investigate the vertical migration of MSA from summer layers, where MSA is originally deposited, to adjacent winter layers in polar ice. We find that the shallowest depth of MSA migration in our compilation varies over a wide range (∼ 2 to 400 m) and is positively correlated with snow accumulation rate and negatively correlated with ice concentration of Na+ (typically the most abundant marine cation). Although the considered soluble impurity transport model provides a useful mechanistic framework for studying MSA migration, it remains limited by inadequate constraints on key physico-chemical parameters – most notably, the diffusion coefficient of MSA in cold ice (DMS). We derive a simplified version of the model, which includes DMS as the sole parameter, in order to illuminate aspects of the migration process. Using this model, we show that the progressive phase alignment of MSA and Na+ concentration peaks observed along a high-resolution West Antarctic core is most consistent with 10−12 m2 s−1 < DMS < 10−11 m2 s−1, which is 1 order of magnitude greater than the DMS values previously estimated from laboratory studies. More generally, our data synthesis and model results suggest that (i) MSA migration may be fairly ubiquitous, particularly at coastal and (or) high-accumulation regions across Greenland and Antarctica; and (ii) can significantly change annual and multiyear MSA concentration averages. Thus, in most cases, caution should be exercised when interpreting polar ice core MSA records, although records that have undergone severe migration could still be useful for inferring decadal and lower-frequency climate variability.Matthew Osman acknowledges government support awarded by DoD, Air Force Office of Scientific Research, National Defense Science and Engineering Graduate (NDSEG) Fellowship, 32 CFR 168a. This work was supported by the US NSF (ANT-0632031 and PLR-1205196 to Sarah B. Das, and NSF-MRI-1126217 to Matthew J. Evans) and a Woods Hole Oceanographic Institution Interdisciplinary Research award to Sarah B. Das and Olivier Marchal

Antarctic surface melting dynamics : enhanced perspectives from radar scatterometer data

Author Posting. © American Geophysical Union, 2012. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research 117 (2012): F02023, doi:10.1029/2011JF002126.Antarctic ice sheet surface melting can regionally influence ice shelf stability, mass balance, and glacier dynamics, in addition to modulating near-surface physical and chemical properties over wide areas. Here, we investigate variability in surface melting from 1999 to 2009 using radar backscatter time series from the SeaWinds scatterometer aboard the QuikSCAT satellite. These daily, continent-wide observations are explored in concert with in situ meteorological records to validate a threshold-based melt detection method. Radar backscatter decreases during melting are significantly correlated with in situ positive degree-days as well as meltwater production determined from energy balance modeling at Neumayer Station, East Antarctica. These results support the use of scatterometer data as a diagnostic indicator of melt intensity (i.e., the relative liquid water production during melting). Greater spatial and temporal melting detected relative to previous passive microwave-based studies is attributed to a higher sensitivity of the scatterometer instrument. Continental melt intensity variability can be explained in part by the dynamics of the Southern Annular Mode and the Southern Oscillation Index, and extreme melting events across the Ross Ice Shelf region may be associated with El Niño conditions. Furthermore, we find that the Antarctic Peninsula accounts for only 20% of Antarctic melt extent but greater than 50% of the total Antarctic melt intensity. Over most areas, annual melt duration and intensity are proportional. However, regional and localized distinctions exist where the melt intensity metric provides greater insight into melting dynamics than previously obtainable with other remote sensing techniques.Support for this research was provided by NASA grant NNX10AP09G and NSF grant ANT-063203.2012-11-1

Relationship between Greenland Ice Sheet surface speed and modeled effective pressure

Author Posting. © American Geophysical Union, 2018. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Earth Surface 123 (2018): 2258-2278, doi:10.1029/2017JF004581.We use a numerical subglacial hydrology model and remotely sensed observations of Greenland Ice Sheet surface motion to test whether the inverse relationship between effective pressure and regional melt season surface speeds observed at individual sites holds on a regional scale. The model is forced with daily surface runoff estimates for 2009 and 2010 across an ~8,000‐km2 region on the western margin. The overall subglacial drainage system morphology develops similarly in both years, with subglacial channel networks growing inland from the ice sheet margin and robust subglacial pathways forming over bedrock ridges. Modeled effective pressures are compared to contemporaneous regional surface speeds derived from TerraSAR‐X imagery to investigate spatial relationships. Our results show an inverse spatial relationship between effective pressure and ice speed in the mid‐melt season, when surface speeds are elevated, indicating that effective pressure is the dominant control on surface velocities in the mid‐melt season. By contrast, in the early and late melt seasons, when surface speeds are slower, effective pressure and surface speed have a positive relationship. Our results suggest that outside of the mid‐melt season, the influence of effective pressures on sliding speeds may be secondary to the influence of driving stress and spatially variable bed roughness.National Aeronautics and Space Administration (NASA). Grant Number: NXX10AI30G National Science Foundation (NSF) American Geophysical Union Horton Research Grant; National Science Foundation Graduate Research Fellowship; National Science Foundation's Office of Polar Programs (NSF‐OPP) Grant Numbers: PLR‐1418256, ARC‐1023364, ARC‐0520077; Woods Hole Oceanographic Institution's Ocean and Climate Change Institute (OCCI)2019-03-2

Characterization and formation of melt layers in polar snow : observations and experiments from West Antarctica

Author Posting. © International Glaciological Society, 2005. This article is posted here by permission of International Glaciological Society for personal use, not for redistribution. The definitive version was published in Journal of Glaciology 51 (2005): 307-312, doi:10.3189/172756505781829395.Surface melting rarely occurs across most of the Antarctic ice sheet, away from the warmer coastal regions. Nonetheless, isolated melt features are preserved in the firn and ice in response to infrequent and short-lived melting events. An understanding of the formation and occurrence of these melt layers will help us to interpret records of past melt occurrences from polar ice cores such as the Siple Dome ice-core record from West Antarctica. A search in the near-surface firn in West Antarctica found that melt features are extremely rare, and consist of horizontal, laterally continuous, one to a few millimeter thick, ice layers with few air bubbles. The melt layers found date from the 1992/93 and 1991/92 summers. Field experiments to investigate changes in stratigraphy taking place during melt events reproduced melt features as seen in the natural stratigraphy. Melting conditions of varying intensity were created by passively heating the near-surface air for varying lengths of time inside a clear plastic hotbox. Melt layers formed due entirely to preferential flow and subsequent refreezing of meltwater from the surface into near-surface, fine-grained, crust layers. Continuous melt layers were formed experimentally when positive-degree-day values exceeded 18C-day, a value corresponding well with air-temperature records from automatic weather station sites where melt layers formed in the recent past.This research was supported by NASA grant NAG5-7776 and by US National Science Foundation grant OPP-9814485 to The Pennsylvania State University, and by a NASA Earth System Science Fellowship to S.B. Das

ELMO1 has an essential role in the internalization of Salmonella Typhimurium into enteric macrophages that impacts disease outcome.

Backgrounds and aims4-6 million people die of enteric infections each year. After invading intestinal epithelial cells, enteric bacteria encounter phagocytes. However, little is known about how phagocytes internalize the bacteria to generate host responses. Previously, we have shown that BAI1 (Brain Angiogenesis Inhibitor 1) binds and internalizes Gram-negative bacteria through an ELMO1 (Engulfment and cell Motility protein 1)/Rac1-dependent mechanism. Here we delineate the role of ELMO1 in host inflammatory responses following enteric infection.MethodsELMO1-depleted murine macrophage cell lines, intestinal macrophages and ELMO1 deficient mice (total or myeloid-cell specific) was infected with Salmonella enterica serovar Typhimurium. The bacterial load, inflammatory cytokines and histopathology was evaluated in the ileum, cecum and spleen. The ELMO1 dependent host cytokines were detected by a cytokine array. ELMO1 mediated Rac1 activity was measured by pulldown assay.ResultsThe cytokine array showed reduced release of pro-inflammatory cytokines, including TNF-α and MCP-1, by ELMO1-depleted macrophages. Inhibition of ELMO1 expression in macrophages decreased Rac1 activation (~6 fold) and reduced internalization of Salmonella. ELMO1-dependent internalization was indispensable for TNF-α and MCP-1. Simultaneous inhibition of ELMO1 and Rac function virtually abrogated TNF-α responses to infection. Further, activation of NF-κB, ERK1/2 and p38 MAP kinases were impaired in ELMO1-depleted cells. Strikingly, bacterial internalization by intestinal macrophages was completely dependent on ELMO1. Salmonella infection of ELMO1-deficient mice resulted in a 90% reduction in bacterial burden and attenuated inflammatory responses in the ileum, spleen and cecum.ConclusionThese findings suggest a novel role for ELMO1 in facilitating intracellular bacterial sensing and the induction of inflammatory responses following infection with Salmonella

Self Interacting Dark Matter in the Solar System

Weakly coupled, almost massless, spin 0 particles have been predicted by many extensions of the standard model of particle physics. Recently, the PVLAS group observed a rotation of polarization of electromagnetic waves in vacuum in the presence of transverse magnetic field. This phenomenon is best explained by the existence of a weakly coupled light pseudoscalar particle. However, the coupling required by this experiment is much larger than the conventional astrophysical limits. Here we consider a hypothetical self-interacting pseudoscalar particle which couples weakly with visible matter. Assuming that these pseudoscalars pervade the galaxy, we show that the solar limits on the pseudoscalar-photon coupling can be evaded.Comment: 17 pages, 2 figure

Noble gas signatures in Greenland : tracing glacial meltwater sources

Author Posting. © American Geophysical Union, 2015. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 42 (2015): 9311–9318, doi:10.1002/2015GL065778.This study represents the first comprehensive noble gas study in glacial meltwater from the Greenland Ice Sheet. It shows that most samples are in disequilibrium with surface collection conditions. A preliminary Ne and Xe analysis suggests that about half of the samples equilibrated at a temperature of ~0°C and altitudes between 1000 m and 2000 m, with a few samples pointing to lower equilibration altitudes and temperatures between 2°C and 5°C. Two samples suggest an origin as melted ice and complete lack of equilibration with surface conditions. A helium component analysis suggests that this glacial meltwater was isolated from the atmosphere prior to the 1950s, with most samples yielding residence times ≤ 420 years. Most samples represent a mixture between a dominant atmospheric component originating as precipitation and basal meltwater or groundwater, which has accumulated crustal 4He over time.University of Michigan; Packard Foundation; Department of Earth and Environmental Sciences Turner fellowship2016-05-0

Structure and dynamics of a subglacial discharge plume in a Greenlandic fjord

Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 121 (2016): 8670–8688, doi:10.1002/2016JC011764.Discharge of surface-derived meltwater at the submerged base of Greenland's marine-terminating glaciers creates subglacial discharge plumes that rise along the glacier/ocean interface. These plumes impact submarine melting, calving, and fjord circulation. Observations of plume properties and dynamics are challenging due to their proximity to the calving edge of glaciers. Therefore, to date information on these plumes has been largely derived from models. Here we present temperature, salinity, and velocity data collected in a plume that surfaced at the edge of Saqqarliup Sermia, a midsized Greenlandic glacier. The plume is associated with a narrow core of rising waters approximately 20 m in diameter at the ice edge that spreads to a 200 m by 300 m plume pool as it reaches the surface, before descending to its equilibrium depth. Volume flux estimates indicate that the plume is primarily driven by subglacial discharge and that this has been diluted in a ratio of 1:10 by the time the plume reaches the surface. While highly uncertain, meltwater fluxes are likely 2 orders of magnitude smaller than the subglacial discharge flux. The overall plume characteristics agree with those predicted by theoretical plume models for a convection-driven plume with limited influence from submarine melting.National Science Foundation (NSF) Grant Numbers: PLR-1418256 , OCE-1434041; Woods Hole Oceanographic Institution (WHOI) Ocean and Climate Change Institute (OCCI) Arctic Research Initiative OCCI; National Aeronautics and Space Administration Grant Number: NNX10AN83H2017-06-1

Linking glacially modified waters to catchment-scale subglacial discharge using autonomous underwater vehicle observations

© The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Cryosphere 10 (2016): 417-432, doi:10.5194/tc-10-417-2016.Measurements of near-ice (<  200 m) hydrography and near-terminus subglacial hydrology are lacking, due in large part to the difficulty in working at the margin of calving glaciers. Here we pair detailed hydrographic and bathymetric measurements collected with an autonomous underwater vehicle as close as 150 m from the ice–ocean interface of the Saqqarliup sermia–Sarqardleq Fjord system, West Greenland, with modeled and observed subglacial discharge locations and magnitudes. We find evidence of two main types of subsurface glacially modified water (GMW) with distinct properties and locations. The two GMW locations also align with modeled runoff discharged at separate locations along the grounded margin corresponding with two prominent subcatchments beneath Saqqarliup sermia. Thus, near-ice observations and subglacial discharge routing indicate that runoff from this glacier occurs primarily at two discrete locations and gives rise to two distinct glacially modified waters. Furthermore, we show that the location with the largest subglacial discharge is associated with the lighter, fresher glacially modified water mass. This is qualitatively consistent with results from an idealized plume model.Support was provided by the National Science Foundation’s Office of Polar Programs (NSF-OPP) through PLR-1418256 to F. Straneo, S. B. Das and A. J. Plueddemann, PLR-1023364 to S. B. Das, and through the Woods Hole Oceanographic Institution Ocean and Climate Change Institute Arctic Research Initiative to F. Straneo, S. B. Das, and A. J. Plueddemann. L. A. Stevens was also supported by a National Science Foundation Graduate Research Fellowship. S. B. Das was also supported by the Woods Hole Oceanographic Institution James E. and Barbara V. Moltz Research Fellowship. M. Morlighem was supported by the National Aeronautics and Space Administration’s (NASA) Cryospheric Sciences Program through NNX15AD55G

Surface emergence of glacial plumes determined by fjord stratification

© The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in De Andres, E., Slater, D. A., Otero, J., Das, S., Navarro, F., & Straneo, F. Surface emergence of glacial plumes determined by fjord stratification. Cryosphere, 14(6), (2020): 1951-1969, doi:10.5194/tc-14-1951-2020.Meltwater and sediment-laden plumes at tidewater glaciers, resulting from the localized subglacial discharge of surface melt, influence submarine melting of the glacier and the delivery of nutrients to the fjord's surface waters. It is usually assumed that increased subglacial discharge will promote the surfacing of these plumes. Here, at a western Greenland tidewater glacier, we investigate the counterintuitive observation of a non-surfacing plume in July 2012 (a year of record surface melting) compared to the surfacing of the plume in July 2013 (an average melt year). We combine oceanographic observations, subglacial discharge estimates and an idealized plume model to explain the observed plumes' behavior and evaluate the relative impact of fjord stratification and subglacial discharge on plume dynamics. We find that increased fjord stratification prevented the plume from surfacing in 2012, show that the fjord was more stratified in 2012 due to increased freshwater content and speculate that this arose from an accumulation of ice sheet surface meltwater in the fjord in this record melt year. By developing theoretical scalings, we show that fjord stratification in general exerts a dominant control on plume vertical extent (and thus surface expression), so that studies using plume surface expression as a means of diagnosing variability in glacial processes should account for possible changes in stratification. We introduce the idea that, despite projections of increased surface melting over Greenland, the appearance of plumes at the fjord surface could in the future become less common if the increased freshwater acts to stratify fjords around the Greenland ice sheet. We discuss the implications of our findings for nutrient fluxes, trapping of atmospheric CO2 and the properties of water exported from Greenland's fjords.This research has been supported by the Ministerio de Educación, Cultura y Deporte (grant no. FPU14/04109), the National Science Foundation (grant no. 1418256), the Ministerio de Economía, Industria y Competitividad, Gobierno de España (grant no. CTM2017-84441-R), and the Horizon 2020 Research and Innovation Programme (grant no. 727890)