Preparation and Characterization of Silver Nanoparticles in Montmorillonite and Gelatin Using Physical and Chemical Methods

Metal nanoparticles in inorganic and organic materials have generated novel materials that display unique optical, catalysis, or biological properties making them attractive for using in various application areas. A big challenge in the synthesis of nanoparticles is particle aggregation or precipitation. This phenomenon can be inhibited with stabilization of nanoparticles by suitable polymers or chemical species as colloidal stabilizers. This thesis describes the different preparation methods and characterization of silver nanoparticles (Ag-NPs) in organic and inorganic materials as well as their potential applications. The methods used consist of green chemical method and physical methods, e.g., UV irradiation, pulsed laser ablation (PLA), and y-irradiation. Silver nitrate, montmorillonite (MMT), gelatin, glucose, NaOH, and silver plate were used as starting materials in this work. In UV irradiation method, Ag-NPs were prepared at different irradiation times (i.e., 1, 3, 18, 48, and 96 hr) in MMT and gelatin (i.e., 1, 3, 6, 18, 24, and 48 hr) as inorganic and organic matrix, respectively. UV-vis spectra and transmission electron microscopy (TEM) images demonstrate the particles size of Ag-NPs decrease with the increase of UV irradiation time. In y-irradiation method, when the irradiation dose was increased (from 5 to 50 kGy); the mean size of particles reduced continuously (from 20.4 to 16.4 nm) due to the y-induced Ag-NPs fragmentation. In PLA technique it was found smaller particle size distributions of Ag-NPs were obtained with smaller repetition rates and longer laser ablation times. Also, the UV-vis and TEM images demonstrated that the mean diameter of Ag-NPs increased (from 8.9 to 14.7 nm) as the laser repetition rate was increased (from 10 to 40 Hz). The use of inexpensive chemicals and non-toxic solvents – environmentally friendly and renewable/biodegradable – are central to materials synthesis. The green chemistry rules were applied for preparation of Ag-NPs in gelatin using glucose as a reducing agent,where the particle diameters of Ag-NPs at different temperatures and reaction times were investigated. It was found that with increasing of reaction times (from 6 to 48 hr) the size of Ag-NPs decreased (from 9.6 to 5.3 nm). The particle size of Ag-NPs obtained in gelatin solutions (3.7 nm) is smaller than in gelatin-glucose solutions (5.3 nm) which can be related to rate of reduction reaction. The stability of prepared Ag-NPs, as shown by UV-vis spectral analysis, was significant. The obtained Ag-NPs were characterized by X-ray diffraction (XRD) and atomic force microscopy (AFM). In addition, the Ag-NPs prepared in this work may have value for the creation of antibacterial and antimicrobial paints and coatings for household materials, surgical and food storage equipments

Contributions to bluetooth low energy mesh networks

Bluetooth Low Energy (BLE) has become a popular Internet of Things (IoT) technology. However, it was originally designed to only support the star topology. This PhD thesis investigates and evaluates different Bluetooth Low Energy (BLE) mesh network approaches, including existing ones (such as the Bluetooth Mesh standard), and our own solution for IPv6-based BLE mesh networking (6BLEMesh). The thesis comprises 6 main contributions: 1.- A comprehensive survey on existing BLE mesh networking proposals and a taxonomy for BLE mesh network solutions. 2.- An energy consumption model for Bluetooth Mesh. The model allows to predict useful performance parameters, such as device average current consumption, device lifetime and energy efficiency, considering the impact of the most relevant Bluetooth Mesh parameters, i.e. PollTimeout and ReceiveWindow, as well as application parameters (e.g. the data interval for a sensor that periodically reports its readings). 3.- A new proposed IPv6-based BLE mesh networking IETF standard (in progress), called 6BLEMesh. After defining the characteristics and properties of 6BLEMesh, we evaluated it in terms of connectivity, latency, RTT, and energy consumption. 4.- For the connectivity evaluation of 6BLEMesh, we developed an analytical model that takes a set of network and scenario characteristics as inputs, and provides two main results: i) the probability of no isolation of a node, and ii) the k-connectivity of the considered network. We validated the model by simulation. 5.- An implementation, and an experimental evaluation, of 6BLEMesh. We built a three-node testbed consisting of all node types (i.e. 6LN, 6LR and 6LBR). We used three different popular commercial hardware platforms. We evaluated a number of performance parameters on the testbed, related with latency and energy consumption. Next, we characterized the current consumption patterns of the complete life cycle for different node types in the three-node testbed. We also evaluated the energy performance of a 6LN on three different platforms. We presented a 6LN current consumption model for different connInterval settings. To this end, we experimentally characterized each current consumption state in terms of its duration time and average current consumption value. We illustrated the impact of connInterval on energy performance. 6.- A comparison between Bluetooth Mesh and 6BLEMesh, in terms of protocol stack, protocol encapsulation overhead, end-toend latency, energy consumption, message transmission count, end-to-end reliability, variable topology robustness and Internet connectivity. Bluetooth Mesh and 6BLEMesh offer fundamentally different BLE mesh networking solutions. Their performance depends significantly on their parameter configuration. Nevertheless, the following conclusions can be obtained. Bluetooth Mesh exhibits slightly greater protocol encapsulation overhead than 6BLEmesh. Both Bluetooth Mesh and 6BLEMesh offer flexibility to configure per-hop latency. For a given latency target, 6BLEMesh offers lower energy consumption. In terms of message transmission count, both solutions may offer relatively similar performance for small networks; however, BLEMesh scales better with network size and density. 6BLEMesh approaches ideal packet delivery probability in the presence of bit errors for most parameter settings (at the expense of latency increase), whereas Bluetooth Mesh requires path diversity to achieve similar performance. Bluetooth Mesh does not suffer the connectivity gaps experimented by 6BLEMesh due to topology changes. Finally, 6BLEMesh naturally supports IP-based Internet connectivity, whereas Bluetooth Mesh requires a protocol translation gateway.Bluetooth Low Energy (BLE) ha esdevingut una tecnologia popular per a Internet of Things (loT). Ara bé, va ser originalment dissenyada per suportar només la topologia en estrella. Aquesta tesi doctoral investiga i avalua diferents alternatives de xarxa mesh BLE, incloent alternatives existents (com l'estandard Bluetooth Mesh), i la nostra propia solució basada en IPv6, 6BLEMesh. Aquesta tesi comprén 6 contribucions·principals: 1.- Una revisió exhaustiva de l'estat de l'art i una taxonomia de les xarxes mesh BLE. 2.- Un model de consum d'energia per Bluetooth Mesh. El model permet predir parametres de rendiment útils, tals com consum de corrent, temps de vida del dispositiu i eficiéncia energética, considerant !'impacte deis principals parametres de Bluetooth Mesh (PollTimeout i ReceiveWindow) i a nivell d'aplicació. 3.- Un nou estandard (en progrés) anomenat 6BLEMesh. Després de definir les característiques de 6BLEMesh, aquesta solució ha estat avaluada en termes de connectivitat, laténcia, RTT i consum d'energia. 4.- Per a l'avaluació de connectivitat de 6BLEMesh, hem desenvolupat un model analític que proporciona dos resultats principals: i) probabilitat de no arllament d'un node i ii) k-connectivitat de la xarxa considerada. Hem validat el model mitjani;:ant simulació. .- Una imP.lementació, i una avaluació experimental, de 6BLEMesh. S'ha construrt un testbed de tres nodes, que comprén 5tots els tipus de node principals (6LN, 6LR i 6LBR). S'han usat tres plataformes hardware diferents. S'han avaluat diversos parametres de rendiment en el testbed, relacionats amb laténcia i consum d'energia. A continuació, s'ha caracteritzat els patrons de consum de corren! d'un ciclde de vida complet per als diferents tipus de nodes en el testbed. També s'han avaluat les prestacions d'energia d'un 6LN en tres plataformes diferents. S'ha presenta! un model de consum de corren! d'un 6LN per a diferents valors de connlnterval. Per aquest fi, s'ha caracteritzat emplricament cada estat de consum de corrent en termes de la seva durada i consum de corrent. 6.- Una comparativa entre Bluetooth Mesh i 6BLEMesh, en termes de pila de protocols, overhead d'encapsulament de protocol, laténcia extrem a extrem, consum d'energia, nombre de missatges transmesos, fiabilitat extrem a extrem, robustesa davant de topologies variables, i connexió a Internet. Bluetooth Mesh i 6BLEMesh són solucions de BLE mesh networking fonamentalment diferents. Les seves prestacions depenen de la seva configuració de parametres. Ara bé, es poden extreure les següents conclusions. Bluetooth Mesh mostra un overhead d'encapsulament de protocol lleugerament superior al de 6BLEmesh. Tots dos, Bluetooth Mesh i 6BLEMesh, ofereixen flexibilitat per configurar la laténcia per cada salt. Per un target de laténcia doni¡it, 6BLEMesh ofereix un consum d'energia inferior. En termes de nombre de missatges transmesos, les dues solucions ofereixen prestacions relativament similars per a xarxes petites. Ara bé, 6BLEMesh escala millor amb la mida i la densitat de la xarxa. 6BLEMesh s'aproxima a una probabilitat d'entrega de paquets ideal en preséncia d'errors de bit (amb un increment en la laténcia), mentre que Bluetooth Mesh requereix diversitat de caml per assolir unes prestacions similars. Bluetooth Mesh no pateix els gaps de connectivitat que experimenta 6BLLEMesh a causa de canvis en la topología. Finalment, 6BLEMesh suporta de forma natural la connectivitat amb Internet basada en IP, mentre que Bluetooth Mesh requereix un gateway de traducció de protocols.Postprint (published version

Contributions to bluetooth low energy mesh networks

Bluetooth Low Energy (BLE) has become a popular Internet of Things (IoT) technology. However, it was originally designed to only support the star topology. This PhD thesis investigates and evaluates different Bluetooth Low Energy (BLE) mesh network approaches, including existing ones (such as the Bluetooth Mesh standard), and our own solution for IPv6-based BLE mesh networking (6BLEMesh). The thesis comprises 6 main contributions: 1.- A comprehensive survey on existing BLE mesh networking proposals and a taxonomy for BLE mesh network solutions. 2.- An energy consumption model for Bluetooth Mesh. The model allows to predict useful performance parameters, such as device average current consumption, device lifetime and energy efficiency, considering the impact of the most relevant Bluetooth Mesh parameters, i.e. PollTimeout and ReceiveWindow, as well as application parameters (e.g. the data interval for a sensor that periodically reports its readings). 3.- A new proposed IPv6-based BLE mesh networking IETF standard (in progress), called 6BLEMesh. After defining the characteristics and properties of 6BLEMesh, we evaluated it in terms of connectivity, latency, RTT, and energy consumption. 4.- For the connectivity evaluation of 6BLEMesh, we developed an analytical model that takes a set of network and scenario characteristics as inputs, and provides two main results: i) the probability of no isolation of a node, and ii) the k-connectivity of the considered network. We validated the model by simulation. 5.- An implementation, and an experimental evaluation, of 6BLEMesh. We built a three-node testbed consisting of all node types (i.e. 6LN, 6LR and 6LBR). We used three different popular commercial hardware platforms. We evaluated a number of performance parameters on the testbed, related with latency and energy consumption. Next, we characterized the current consumption patterns of the complete life cycle for different node types in the three-node testbed. We also evaluated the energy performance of a 6LN on three different platforms. We presented a 6LN current consumption model for different connInterval settings. To this end, we experimentally characterized each current consumption state in terms of its duration time and average current consumption value. We illustrated the impact of connInterval on energy performance. 6.- A comparison between Bluetooth Mesh and 6BLEMesh, in terms of protocol stack, protocol encapsulation overhead, end-toend latency, energy consumption, message transmission count, end-to-end reliability, variable topology robustness and Internet connectivity. Bluetooth Mesh and 6BLEMesh offer fundamentally different BLE mesh networking solutions. Their performance depends significantly on their parameter configuration. Nevertheless, the following conclusions can be obtained. Bluetooth Mesh exhibits slightly greater protocol encapsulation overhead than 6BLEmesh. Both Bluetooth Mesh and 6BLEMesh offer flexibility to configure per-hop latency. For a given latency target, 6BLEMesh offers lower energy consumption. In terms of message transmission count, both solutions may offer relatively similar performance for small networks; however, BLEMesh scales better with network size and density. 6BLEMesh approaches ideal packet delivery probability in the presence of bit errors for most parameter settings (at the expense of latency increase), whereas Bluetooth Mesh requires path diversity to achieve similar performance. Bluetooth Mesh does not suffer the connectivity gaps experimented by 6BLEMesh due to topology changes. Finally, 6BLEMesh naturally supports IP-based Internet connectivity, whereas Bluetooth Mesh requires a protocol translation gateway.Bluetooth Low Energy (BLE) ha esdevingut una tecnologia popular per a Internet of Things (loT). Ara bé, va ser originalment dissenyada per suportar només la topologia en estrella. Aquesta tesi doctoral investiga i avalua diferents alternatives de xarxa mesh BLE, incloent alternatives existents (com l'estandard Bluetooth Mesh), i la nostra propia solució basada en IPv6, 6BLEMesh. Aquesta tesi comprén 6 contribucions·principals: 1.- Una revisió exhaustiva de l'estat de l'art i una taxonomia de les xarxes mesh BLE. 2.- Un model de consum d'energia per Bluetooth Mesh. El model permet predir parametres de rendiment útils, tals com consum de corrent, temps de vida del dispositiu i eficiéncia energética, considerant !'impacte deis principals parametres de Bluetooth Mesh (PollTimeout i ReceiveWindow) i a nivell d'aplicació. 3.- Un nou estandard (en progrés) anomenat 6BLEMesh. Després de definir les característiques de 6BLEMesh, aquesta solució ha estat avaluada en termes de connectivitat, laténcia, RTT i consum d'energia. 4.- Per a l'avaluació de connectivitat de 6BLEMesh, hem desenvolupat un model analític que proporciona dos resultats principals: i) probabilitat de no arllament d'un node i ii) k-connectivitat de la xarxa considerada. Hem validat el model mitjani;:ant simulació. .- Una imP.lementació, i una avaluació experimental, de 6BLEMesh. S'ha construrt un testbed de tres nodes, que comprén 5tots els tipus de node principals (6LN, 6LR i 6LBR). S'han usat tres plataformes hardware diferents. S'han avaluat diversos parametres de rendiment en el testbed, relacionats amb laténcia i consum d'energia. A continuació, s'ha caracteritzat els patrons de consum de corren! d'un ciclde de vida complet per als diferents tipus de nodes en el testbed. També s'han avaluat les prestacions d'energia d'un 6LN en tres plataformes diferents. S'ha presenta! un model de consum de corren! d'un 6LN per a diferents valors de connlnterval. Per aquest fi, s'ha caracteritzat emplricament cada estat de consum de corrent en termes de la seva durada i consum de corrent. 6.- Una comparativa entre Bluetooth Mesh i 6BLEMesh, en termes de pila de protocols, overhead d'encapsulament de protocol, laténcia extrem a extrem, consum d'energia, nombre de missatges transmesos, fiabilitat extrem a extrem, robustesa davant de topologies variables, i connexió a Internet. Bluetooth Mesh i 6BLEMesh són solucions de BLE mesh networking fonamentalment diferents. Les seves prestacions depenen de la seva configuració de parametres. Ara bé, es poden extreure les següents conclusions. Bluetooth Mesh mostra un overhead d'encapsulament de protocol lleugerament superior al de 6BLEmesh. Tots dos, Bluetooth Mesh i 6BLEMesh, ofereixen flexibilitat per configurar la laténcia per cada salt. Per un target de laténcia doni¡it, 6BLEMesh ofereix un consum d'energia inferior. En termes de nombre de missatges transmesos, les dues solucions ofereixen prestacions relativament similars per a xarxes petites. Ara bé, 6BLEMesh escala millor amb la mida i la densitat de la xarxa. 6BLEMesh s'aproxima a una probabilitat d'entrega de paquets ideal en preséncia d'errors de bit (amb un increment en la laténcia), mentre que Bluetooth Mesh requereix diversitat de caml per assolir unes prestacions similars. Bluetooth Mesh no pateix els gaps de connectivitat que experimenta 6BLLEMesh a causa de canvis en la topología. Finalment, 6BLEMesh suporta de forma natural la connectivitat amb Internet basada en IP, mentre que Bluetooth Mesh requereix un gateway de traducció de protocols

Modeling the connectivity of Data-Channel-based Bluetooth Low Energy mesh networks

© 2018 IEEE. Personal use of this material is permitted. Permission from IEEE must be obtained for all other uses, in any current or future media, including reprinting/republishing this material for advertising or promotional purposes, creating new collective works, for resale or redistribution to servers or lists, or reuse of any copyrighted component of this work in other works.Bluetooth Low Energy (BLE) has become one of the most popular low-power wireless technologies. While BLE was originally designed for star topology networks only, recent developments have focused on enabling mesh network topology support for BLE. An emerging category of BLE mesh network initiatives is based on routing data units over BLE data channels. This letter investigates the fundamental connectivity parameters of data-channel-based BLE mesh networks, such as the probability of no isolation of a node and network K-connectivity. We provide an analytical model for both parameters which is validated by means of extensive simulations.Postprint (author's final draft

Fabrication and Characterization of Gelatin Stabilized Silver Nanoparticles under UV-Light

Silver nanoparticles (Ag-NPs) were successfully synthesized using the UV irradiation of aqueous solutions containing AgNO3 and gelatin as a silver source and stabilizer, respectively. The UV irradiation times influence the particles’ diameter of the Ag-NPs, as evidenced from surface plasmon resonance (SPR) bands and transmission electron microscopy (TEM) images. When the UV irradiation time was increased, the mean size of particles continuously decreased as a result of photoinduced Ag-NPs fragmentation. Based on X-ray diffraction (XRD), the UV-irradiated Ag-NPs were a face-centered cubic (fcc) single crystal without any impurity. This study reveals that the UV irradiation-mediated method is a green chemistry and promising route for the synthesis of stable Ag-NPs for several applications (e.g., medical and surgical devices). The important advantages of this method are that it is cheap, easy, and free of toxic materials

Variable Speed Limit Strategies to Reduce the Impacts of Traffic Flow Breakdown at Recurrent Freeway Bottlenecks

Variable Speed Limit (VSL) strategies identify and disseminate dynamic speed limits that are determined to be appropriate based on prevailing traffic conditions, road surface conditions, and weather conditions. This dissertation develops and evaluates a shockwave-based VSL system that uses a heuristic switching logic-based controller with specified thresholds of prevailing traffic flow conditions. The system aims to improve operations and mobility at critical bottlenecks. Before traffic breakdown occurrence, the proposed VSL’s goal is to prevent or postpone breakdown by decreasing the inflow and achieving uniform distribution in speed and flow. After breakdown occurrence, the VSL system aims to dampen traffic congestion by reducing the inflow traffic to the congested area and increasing the bottleneck capacity by deactivating the VSL at the head of the congested area. The shockwave-based VSL system pushes the VSL location upstream as the congested area propagates upstream. In addition to testing the system using infrastructure detector-based data, this dissertation investigates the use of Connected Vehicle trajectory data as input to the shockwave-based VSL system performance. Since the field Connected Vehicle data are not available, as part of this research, Vehicle-to-Infrastructure communication is modeled in the microscopic simulation to obtain individual vehicle trajectories. In this system, wavelet transform is used to analyze aggregated individual vehicles’ speed data to determine the locations of congestion. The currently recommended calibration procedures of simulation models are generally based on the capacity, volume and system-performance values and do not specifically examine traffic breakdown characteristics. However, since the proposed VSL strategies are countermeasures to the impacts of breakdown conditions, considering breakdown characteristics in the calibration procedure is important to have a reliable assessment. Several enhancements were proposed in this study to account for the breakdown characteristics at bottleneck locations in the calibration process. In this dissertation, performance of shockwave-based VSL is compared to VSL systems with different fixed VSL message sign locations utilizing the calibrated microscopic model. The results show that shockwave-based VSL outperforms fixed-location VSL systems, and it can considerably decrease the maximum back of queue and duration of breakdown while increasing the average speed during breakdown

Bluetooth mesh energy consumption: a model

The recent publication of the Bluetooth Mesh standard is a remarkable milestone in the evolution of Bluetooth Low Energy (BLE). As a new technology in the Internet of Things (IoT) market, it is crucial to investigate the performance of Bluetooth Mesh. However, while a fundamental feature of Bluetooth Mesh is its suitability for energy-constrained devices, this aspect has not yet been properly considered in the literature. In this paper, we model the current consumption, lifetime and energy cost per delivered bit of a battery-operated Bluetooth Mesh sensor node. The model is based on measurements performed on a real hardware platform. Evaluation results quantify the impact of crucial Bluetooth Mesh parameters. Among others, we have found that a sensor device running on a simple 235 mAh battery, and sending a data message every 10 s, can achieve a lifetime of up to 15.6 months, whereas the asymptotic lifetime is 21.4 months.Peer ReviewedPostprint (published version

Synthesis and characterization of a narrow size distribution of zinc oxide nanoparticles

Zinc oxide nanoparticles (ZnO-NPs) were synthesized via a solvothermal method in triethanolamine (TEA) media. TEA was utilized as a polymer agent to terminate the growth of ZnO-NPs. The ZnO-NPs were characterized by a number of techniques, including X-ray diffraction analysis, transition electron microscopy, and field emission electron microscopy. The ZnO-NPs prepared by the solvothermal process at 150°C for 18 hours exhibited a hexagonal (wurtzite) structure, with a crystalline size of 33 ± 2 nm, and particle size of 48 ± 7 nm. The results confirm that TEA is a suitable polymer agent to prepare homogenous ZnO-NPs

IPv6 Mesh over BLUETOOTH(R) Low Energy using IPSP

RFC 7668 describes the adaptation of 6LoWPAN techniques to enable IPv6 over Bluetooth low energy networks that follow the star topology. However, recent Bluetooth specifications allow the formation of extended topologies as well. This document specifies mechanisms that are needed to enable IPv6 mesh over Bluetooth Low Energy links established by using the Bluetooth Internet Protocol Support Profile. This document does not specify the routing protocol to be used in an IPv6 mesh over Bluetooth LE links.Preprin