2,106 research outputs found
Synthesis of Colloidal Mn2+:ZnO Quantum Dots and High-TC Ferromagnetic Nanocrystalline Thin Films
We report the synthesis of colloidal Mn2+-doped ZnO (Mn2+:ZnO) quantum dots
and the preparation of room-temperature ferromagnetic nanocrystalline thin
films. Mn2+:ZnO nanocrystals were prepared by a hydrolysis and condensation
reaction in DMSO under atmospheric conditions. Synthesis was monitored by
electronic absorption and electron paramagnetic resonance (EPR) spectroscopies.
Zn(OAc)2 was found to strongly inhibit oxidation of Mn2+ by O2, allowing the
synthesis of Mn2+:ZnO to be performed aerobically. Mn2+ ions were removed from
the surfaces of as-prepared nanocrystals using dodecylamine to yield
high-quality internally doped Mn2+:ZnO colloids of nearly spherical shape and
uniform diameter (6.1 +/- 0.7 nm). Simulations of the highly resolved X- and
Q-band nanocrystal EPR spectra, combined with quantitative analysis of magnetic
susceptibilities, confirmed that the manganese is substitutionally incorporated
into the ZnO nanocrystals as Mn2+ with very homogeneous speciation, differing
from bulk Mn2+:ZnO only in the magnitude of D-strain. Robust ferromagnetism was
observed in spin-coated thin films of the nanocrystals, with 300 K saturation
moments as large as 1.35 Bohr magneton/Mn2+ and TC > 350 K. A distinct
ferromagnetic resonance signal was observed in the EPR spectra of the
ferromagnetic films. The occurrence of ferromagnetism in Mn2+:ZnO and its
dependence on synthetic variables are discussed in the context of these and
previous theoretical and experimental results.Comment: To be published in the Journal of the American Chemical Society Web
on July 14, 2004 (http://dx.doi.org/10.1021/ja048427j
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Re-entrant Appearance of Phases in a Relaxed Langmuir Monolayer of Tetracosanoic Acid as Determined by X-Ray Scattering
The structure of the fully relaxed phases of a Langmuir monolayer of tetracosanoic acid is determined by x‐ray diffraction and reflection along an isotherm at ∼20.5 °C. Isotherms taken by allowing the surface pressure to stabilize between incremental compressions are seen to be qualitatively different from the constant‐rate nonrelaxed isotherms typically seen in the literature. At low densities the monolayer consists of an inhomogeneous film of islands of a crystalline (or hexatic) phase with molecular tilt ordering that is analogous to that of the smectic I liquid crystal. Small amounts of impurities (∼0.5% of the monolayer) account for the change in surface pressure with area in this region. Upon compression to the point that the free space between islands becomes negligible the film appears homogeneous. On further compression the time required for full relaxation becomes long (i.e., ∼ hours), the tilt angle of the molecular axis decreases and the x‐ray unit cell is compressed. Including this homogeneous I phase the phase sequence observed by diffraction upon compression is I‐U‐I‐U, where U refers to an untilted orthorhombic phase. The outer two phases of this sequence are pure phases which form homogeneous monolayers, but the inner two are inhomogeneous phases each coexisting with an amorphous phase that does not have an observable diffraction signal. At the boundaries demarcating the I and U phases, a phase whose tilt ordering is analogous to that of a smectic F phase is seen to coexist. The preceding phase sequence is sensitive to the degree of relaxation permitted the monolayer after an incremental compression. In particular, if the monolayer is not allowed to relax completely after each compression, the untilted U phase may never appear. The U↔I transition is shown to be reversible for a relaxed monolayer.Engineering and Applied Science
Characterization and Modeling of Local Electromechanical Response in Stress-Biased Piezoelectric Actuators
Numerous investigators have explored the factors that contribute to the high electromechanical performance of stress-biased actuators with particular attention being given to the importance of the extrinsic (domain wall translation) response mechanism. Based on the variation in lateral stress through the thickness of the piezoelectric layer within these devices, it has been suggested that the piezoelectric coefficient varies as a function of position within the layer, though no direct evidence has been previously presented. In this study, the results of Moire interferometry investigations of local strains within these devices are reviewed. The technique permits effective depth-profiling of local deformations at reasonably high (0.25 µm) resolution. A least squares regression analysis approach was used in conjunction with classical laminate theory and free edge effects to fit this experimental data to depth-dependent piezoelectric response. As expected, higher d-coefficients were predicted for the upper free surface of the device compared to the interface with the stainless steel substrate. The predicted values were in general agreement with expectation and are further considered from the perspective of recent reports in the literature regarding multi-axial loading effects on the electromechanical properties of lead zirconate titanate-based piezoelectric ceramics
The Fabrication, Testing and Simulation of Germanium Thermophotovoltaic Cells
This is the final report on NRL Contract N00173-79-C-0362. The purpose of this investigation was to fabricate germanium photovoltaic cells and to examine the feasibility of using them in a thermophotovoltaic system for the generation of electrical power in space. The energy source was to be solar. Systems aspects of the collection of solar energy and rejection of waste heat were not a part of this study. The strategy employed in this investigation was the following. 1. Fabricate germanium photodiodes. 2. Carefully characterize these photodiodes. 3. Simulate the performance of these photodiodes using a detailed numerical model of the cell and the illuminating spectra. 4. Use this simulation program to project the potential performance of germanium photodiodes in a thermophotovoltaic system under various assumptions about future improvements in diode performance and under various thermophotovoltaic spectral condition
Comparison of transcranial electric motor and somatosensory evoked potential monitoring during cervical spine surgery.
BACKGROUND: There has been little enthusiasm for somatosensory evoked potential monitoring in cervical spine surgery as a result, in part, of the increased risk of motor tract injury at this level, to which somatosensory monitoring may be insensitive. Transcranial electric motor evoked potential monitoring allows assessment of the motor tracts; therefore, we compared transcranial electric motor evoked potential and somatosensory evoked potential monitoring during cervical spine surgery to determine the temporal relationship between the changes in the potentials demonstrated by each type of monitoring and neurological sequelae and to identify patient-related and surgical factors associated with intraoperative neurophysiological changes.
METHODS: Somatosensory evoked potential and transcranial electric motor evoked potential data recorded for 427 patients undergoing anterior or posterior cervical spine surgery between January 1999 and March 2001 were analyzed. All patients who showed substantial (at least 60%) or complete unilateral or bilateral amplitude loss, for at least ten minutes, during the transcranial electric motor evoked potential and/or somatosensory evoked potential monitoring were identified.
RESULTS: Twelve of the 427 patients demonstrated substantial or complete loss of amplitude of the transcranial electric motor evoked potentials. Ten of those patients had complete reversal of the loss following prompt intraoperative intervention, whereas two awoke with a new motor deficit. Somatosensory evoked potential monitoring failed to identify any change in one of the two patients, and the change in the somatosensory evoked potentials lagged behind the change in the transcranial electric motor evoked potentials by thirty-three minutes in the other. No patient showed loss of amplitude of the somatosensory evoked potentials in the absence of changes in the transcranial electric motor evoked potentials. Transcranial electric motor evoked potential monitoring was 100% sensitive and 100% specific, whereas somatosensory evoked potential monitoring was only 25% sensitive; it was, however, 100% specific.
CONCLUSIONS: Transcranial electric motor evoked potential monitoring appears to be superior to conventional somatosensory evoked potential monitoring for identifying evolving motor tract injury during cervical spine surgery. Surgeons should strongly consider using this modality when operating on patients with cervical spondylotic myelopathy in general and on those with ossification of the posterior longitudinal ligament in particular
An In Vitro Intact Globe Expansion Method for Evaluation of Cross-linking Treatments
Purpose. To measure the tissue mechanical response to elevated
intraocular pressure (IOP) using intact globe expansion
of rabbit eyes. This method examined rabbit kit (2–3 weeks
old) eyes as a model for weakened tissue and evaluated riboflavin/
UVA and glyceraldehyde cross-linking treatments.
Methods. The ocular shape of enucleated eyes was photographed
during a 24-hour period while a controlled IOP was
imposed (either low IOP 22 mm Hg or high IOP 85 mm
Hg). Untreated controls consisted of kit eyes tested at both
low- and high IOP and adult eyes tested at high IOP. Treated kit
eyes (dextran controls, riboflavin/UVA treatment of the cornea,
and glyceraldehyde treatment of the entire globe) were tested
at high IOP.
Results. Low IOP elicited negligible creep of the sclera and
very gradual creep of the cornea. In contrast, high IOP induced
up to an 8% strain in the sclera and a 15% strain in the cornea
of rabbit kit eyes. The expansion of adult eyes was less than
one third that of kit eyes at the same, high IOP. Riboflavin/UVA
treatment of corneas reduced expansion compared with that in
both dextran-treated and untreated control corneas. Glyceraldehyde
treatment prevented expansion of the cornea and
sclera.
Conclusions. The intact globe expansion method (GEM) imposes
a loading geometry comparable to in vivo conditions and
can quantify changes in mechanical stability as a function of
testing conditions (e.g., IOP, tissue maturation, and therapeutic
cross-linking) with small sample sizes and small variability.
Rabbit kit eyes provide a model of weak tissue suitable for
screening treatments that strengthen the cornea and sclera
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Visualization of human retinal micro-capillaries with phase contrast high-speed optical coherence tomography
We present high-speed Fourier-domain optical coherence tomography (Fd-OCT) with the phase variance based motion contrast method for visualizing retinal micro-circulation in vivo. This technique allows non-invasive visualization of a two-dimensional retinal perfusion map and concurrent volumetric morphology of retinal microvasculature with high sensitivity. The high-speed acquisition rate at 125kHz A-scans enables reduction of motion artifacts with increased scanning area if compared to previously reported results. Several scanning schemes with different sampling densities and scanning areas are evaluated to find optimal parameters for in vivo imaging. In order to evaluate this technique, we compare OCT micro-capillary imaging using the phase variance technique with fundus fluorescein angiography (FA). Additionally, volumetric visualization of blood flow for a normal subject is presented
Optical imaging of the chorioretinal vasculature in the living human eye
Detailed visualization of microvascular changes in the human retina is clinically limited by the capabilities of angiography imaging, a 2D fundus photograph that requires an intravenous injection of fluorescent dye. Whereas current angiography methods enable visualization of some retinal capillary detail, they do not adequately reveal the choriocapillaris or other microvascular features beneath the retina. We have developed a noninvasive microvascular imaging technique called phase-variance optical coherence tomography (pvOCT), which identifies vasculature three dimensionally through analysis of data acquired with OCT systems. The pvOCT imaging method is not only capable of generating capillary perfusion maps for the retina, but it can also use the 3D capabilities to segment the data in depth to isolate vasculature in different layers of the retina and choroid. This paper demonstrates some of the capabilities of pvOCT imaging of the anterior layers of choroidal vasculature of a healthy normal eye as well as of eyes with geographic atrophy (GA) secondary to age-related macular degeneration. The pvOCT data presented permit digital segmentation to produce 2D depth-resolved images of the retinal vasculature, the choriocapillaris, and the vessels in Sattler’s and Haller’s layers. Comparisons are presented between en face projections of pvOCT data within the superficial choroid and clinical angiography images for regions of GA. Abnormalities and vascular dropout observed within the choriocapillaris for pvOCT are compared with regional GA progression. The capability of pvOCT imaging of the microvasculature of the choriocapillaris and the anterior choroidal vasculature has the potential to become a unique tool to evaluate therapies and understand the underlying mechanisms of age-related macular degeneration progression
Constraints on the perturbed mutual motion in Didymos due to impact-induced deformation of its primary after the DART impact
Binary near-Earth asteroid (65803) Didymos is the target of the proposed NASA
Double Asteroid Redirection Test (DART), part of the Asteroid Impact &
Deflection Assessment (AIDA) mission concept. In this mission, the DART
spacecraft is planned to impact the secondary body of Didymos, perturbing
mutual dynamics of the system. The primary body is currently rotating at a spin
period close to the spin barrier of asteroids, and materials ejected from the
secondary due to the DART impact are likely to reach the primary. These
conditions may cause the primary to reshape, due to landslides, or internal
deformation, changing the permanent gravity field. Here, we propose that if
shape deformation of the primary occurs, the mutual orbit of the system would
be perturbed due to a change in the gravity field. We use a numerical
simulation technique based on the full two-body problem to investigate the
shape effect on the mutual dynamics in Didymos after the DART impact. The
results show that under constant volume, shape deformation induces strong
perturbation in the mutual motion. We find that the deformation process always
causes the orbital period of the system to become shorter. If surface layers
with a thickness greater than ~0.4 m on the poles of the primary move down to
the equatorial region due to the DART impact, a change in the orbital period of
the system and in the spin period of the primary will be detected by
ground-based measurement.Comment: 8 pages, 7 figures, 2 tables, accepted for publication in MNRA
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