1,369 research outputs found
Electron-vibration coupling constants in positively charged fullerene
Recent experiments have shown that C60 can be positively field-doped. In that
state, fullerene exhibits a higher resistivity and a higher superconducting
temperature than the corresponding negatively doped state. A strong
intramolecular hole-phonon coupling, connected with the Jahn-Teller effect of
the isolated positive ion, is expected to be important for both properties, but
the actual coupling strengths are so far unknown. Based on density functional
calculations, we determine the linear couplings of the two a_g, six g_g, and
eight h_g vibrational modes to the H_u HOMO level of the C60 molecule. The
couplings predict a D_5 distortion, and an H_u vibronic ground state for C60^+.
They are also used to generate the dimensionless coupling constant
which controls the superconductivity and the phonon contribution to the
electrical resistivity in the crystalline phase. We find that is 1.4
times larger in positively-charged C60 than in the negatively-doped case. These
results are discussed in the context of the available transport data and
superconducting temperatures. The role of higher orbital degeneracy in
superconductivity is also addressed.Comment: 22 pages - 3 figures. This revision includes few punctuation
corrections from proofreadin
One perception, two perspectives: measuring psychological contract dimensionality through the Psychological Contract Content Questionnaire
The present study aims to contribute to the validity strengthening of a psychological contract measure, assessing the dimensionality of the item structure of the Psychological Contract Content Questionnaire (PCCQ). According to the authors (De Vos, Buyens, & Schalk, 2003), the scale consists of two theoretical dimensions, one to measure perceived employer inducement (PEI) and the other to measure perceived employee contributions (PEC), both from the employee's perception, each divided into five content areas. Different structure models were tested in newcomers (police officers working in the Penitentiary Administration attending a one-year training) in two different stages of their entry: at their early entrance (three weeks, TI; 436 respondents) and after their encounter with the operative environment (eight months, T2; 519 respondents). Analyses were carried out using nonparametric item response theory (IRT) approach and multidimensional IRT approach. Results showed that psychological contract is a single latent construct that describes the general perception that the employee has about his/her relationship with the organization and reciprocal obligations fulfilment
An Opportunity to Grow or a Label? Performance Appraisal Justice and Performance Appraisal Satisfaction to Increase Teachers\u2019 Well-Being
Performance management is a key factor to enhance professional development and improve teaching quality. This process is successful only if teachers perceive it as fair, clear, and effective: namely, if it is satisfying. Carefully considering teachers\u2019 attributions in the performance appraisal process is fundamental to better clarify the relations between performance management and positive individual outcomes. Therefore, this study aims to investigate the effects of perceived performance appraisal justice on teachers\u2019 well-being, in terms of job performance, job satisfaction, and life satisfaction, hypothesizing the mediation role of performance appraisal satisfaction. Data from a sample of Italian teachers were analyzed through structural equation modeling. Results confirm the mediation role of performance appraisal satisfaction. In particular, perceived performance appraisal justice was positively associated to performance appraisal satisfaction, which, in turn, was positively associated with job performance, job satisfaction, life satisfaction. Consequently, performance appraisal satisfaction totally mediated the relations between performance appraisal justice and the outcomes considered. Findings are relevant for two reasons. First, they contribute to better understanding the performance management process in educational settings \u2013 an issue requiring further attention. Second, they contribute to highlighting the importance of performance management efficacy, which is essential not only to improve individual well-being but also to enhance teaching quality
Is workaholism associated with inflammatory response? The moderating role of work engagement
The aim of this study was to investigate the association between two different forms of heavy work investment, namely workaholism and work engagement, and serum levels of the proinflammatory cytokine interleukin-17 (IL-17), a possible biomarker of stress. Given the different motivational underpinnings and outcomes of workaholism and work engagement and drawing on the allostatic load and the effort-recovery models, we hypothesized that workaholism is positively associated with IL-17, and that work engagement buffers this association. Workers in an Italian healthcare organization (88 females and 31 males) completed a self-report questionnaire, and then underwent blood sample collection. Data were analysed using moderated multiple regression. Results showed that workaholism was positively associated with IL-17, controlling for the effect of gender, age, and body mass index. Work engagement buffered this association, which was nonsignificant when work engagement was high. To reduce the risk of future health complaints, interventions should be aimed at preventing workaholism and promoting work engagement
First-principles study of lattice instabilities in the ferromagnetic martensite NiMnGa
The phonon dispersion relations and elastic constants for ferromagnetic
NiMnGa in the cubic and tetragonally distorted Heusler structures are
computed using density-functional and density-functional perturbation theory
within the spin-polarized generalized-gradient approximation. For
, the TA tranverse acoustic branch along and
symmetry-related directions displays a dynamical instability at a wavevector
that depends on . Through examination of the Fermi-surface nesting and
electron-phonon coupling, this is identified as a Kohn anomaly. In the parent
cubic phase the computed tetragonal shear elastic constant,
C=(CC)/2, is close to zero, indicating a marginal
elastic instability towards a uniform tetragonal distortion. We conclude that
the cubic Heusler structure is unstable against a family of energy-lowering
distortions produced by the coupling between a uniform tetragonal distortion
and the corresponding modulation. The computed relation between the
ratio and the modulation wavevector is in excellent agreement with
structural data on the premartensitic ( = 1) and martensitic ( =
0.94) phases of NiMnGa.Comment: submitted to Phys. Rev.
Relationship between work rate and oxygen uptake in mitochondrial myopathy during ramp-incremental exercise
We determined the response characteristics and functional correlates of the dynamic relationship between the rate (Δ) of oxygen consumption ( O2) and the applied power output (work rate = WR) during ramp-incremental exercise in patients with mitochondrial myopathy (MM). Fourteen patients (7 males, age 35.4 ± 10.8 years) with biopsy-proven MM and 10 sedentary controls (6 males, age 29.0 ± 7.8 years) took a ramp-incremental cycle ergometer test for the determination of the O2 on-exercise mean response time (MRT) and the gas exchange threshold (GET). The ΔO2/ΔWR slope was calculated up to GET (S1), above GET (S2) and over the entire linear portion of the response (S T). Knee muscle endurance was measured by isokinetic dynamometry. As expected, peak O2 and muscle performance were lower in patients than controls (P O2/ΔWR than controls, especially the S2 component (6.8 ± 1.5 vs 10.3 ± 0.6 mL·min-1·W-1, respectively; P O2/ΔWR (S T) and muscle endurance, MRT-O2, GET and peak O2 in MM patients (P O2/ΔWR below 8 mL·min-1·W-1 had severely reduced peak O2 values (O2) had lower ΔO2/ΔWR (P O2/ΔWR) is typically reduced in patients with MM, being related to increased functional impairment and higher cardiopulmonary stress
The OPERA magnetic spectrometer
The OPERA neutrino oscillation experiment foresees the construction of two
magnetized iron spectrometers located after the lead-nuclear emulsion targets.
The magnet is made up of two vertical walls of rectangular cross section
connected by return yokes. The particle trajectories are measured by high
precision drift tubes located before and after the arms of the magnet.
Moreover, the magnet steel is instrumented with Resistive Plate Chambers that
ease pattern recognition and allow a calorimetric measurement of the hadronic
showers. In this paper we review the construction of the spectrometers. In
particular, we describe the results obtained from the magnet and RPC prototypes
and the installation of the final apparatus at the Gran Sasso laboratories. We
discuss the mechanical and magnetic properties of the steel and the techniques
employed to calibrate the field in the bulk of the magnet. Moreover, results of
the tests and issues concerning the mass production of the Resistive Plate
Chambers are reported. Finally, the expected physics performance of the
detector is described; estimates rely on numerical simulations and the outcome
of the tests described above.Comment: 6 pages, 10 figures, presented at the 2003 IEEE-NSS conference,
Portland, OR, USA, October 20-24, 200
β-Glucuronidase triggers extracellular MMAE release from an integrin-targeted conjugate
A non-internalizing \u3b1v\u3b23 integrin ligand was conjugated to the anticancer drug MMAE through a \u3b2-glucuronidase-responsive linker. In the presence of \u3b2-glucuronidase, only the conjugate bearing a PEG4 spacer inhibited the proliferation of integrin-expressing cancer cells at low nanomolar concentrations, indicating important structural requirements for the efficacy of these therapeutics
Non-linear optical susceptibilities, Raman efficiencies and electrooptic tensors from first-principles density functional perturbation theory
The non-linear response of infinite periodic solids to homogenous electric
fields and collective atomic displacements is discussed in the framework of
density functional perturbation theory. The approach is based on the 2n + 1
theorem applied to an electric-field-dependent energy functional. We report the
expressions for the calculation of the non-linear optical susceptibilities,
Raman scattering efficiencies and electrooptic coefficients. Different
formulations of third-order energy derivatives are examined and their
convergence with respect to the k-point sampling is discussed. We apply our
method to a few simple cases and compare our results to those obtained with
distinct techniques. Finally, we discuss the effect of a scissors correction on
the EO coefficients and non-linear optical susceptibilities
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