Stabilization of pyrolysis oils by solvent additions

Fast pyrolysis bio oils (FPBO) can consist of more than 300 substances. Because those liquids are not in thermodynamic equilibrium components tend to react with each other and change their properties (aging). The addition of different solvents like alcohols and carbon dioxide can improve their properties. For the detection of their effectiveness, reliable analytical procedures and methods are required

Stabilization of pyrolysis oils by solvent additions

FPBO (fast pyrolysis bio oil) changes its composition and thereby its properties over time. This aging process can be measured by aldehyde decrease. Usual stabilization methods of FPBO deploy modifications by the addition of alcohols or other organics. Carbon dioxide can be an alternative additive for conditioning

Aldehydes and ketones in pyrolysis oil: analytical determination and their role in the aging process

Aldehydes and ketones are known to play a role in the aging process of pyrolysis oil and generally, aldehydes are known for their high reactivity. In order to discern in pyrolysis oil the total aldehyde concentration from that of the ketones, a procedure for the quantification of aldehydes by $^{1}$H-NMR was developed. Its capability is demonstrated with a hardwood pyrolysis oil at different stages of the aging process. It was treated by the Accelerated Aging Test at 80 °C for durations of up to 48 h. The aldehyde concentration was complemented by the total concentration of carbonyls, quantified by carbonyl titration. The measurements show, that the examined hardwood pyrolysis oil contained 0.31–0.40 mmol g$^{-1}$ aldehydes and 4.36–4.45 mmol g$^{-1}$ ketones. During the first 24 h, the aldehyde concentration declined by 23–39% and the ketone concentration by 9%. The rate of decline of aldehyde concentration slows down within 24 h but is still measureable. In contrast, the total carbonyl content does not change significantly after an initial decline within the first 4 h. Changes for vinylic, acetalic, phenolic and hydroxyl protons and for protons in the α-position to hydroxy, ether, acetalic and ester groups were detected, by $^{1}$H-NMR. In the context of characterizing pyrolysis oil and monitoring the aging process, $^{1}$H-NMR is a reliable tool to assess the total concentration of aldehydes. It confirms the reactivity of aldehydes and ketones and indicates their contribution to the instability of pyrolysis oil

European sourcebook of crime and criminal justice statistics – 2021

This is the sixth edition of a data collection initiative that started in 1993 under the umbrella of the Council of Europe and has been continued since 2000 by an international group of experts that created the European Sourcebook of Criminal Justice e.V.1 and is also a Working Group of the European Society of Criminology. These experts act as regional coordinators of a network of national correspondents whose contribution has been decisive in collecting and validating data on a variety of subjects from 42 countries.2 This edition of the Sourcebook is composed of six chapters. The first five cover the current main types of national crime and criminal justice statistics – police, prosecution, conviction, prison, and probation statistics – for the years 2011 to 2016, providing detailed analysis for 2015. The sixth chapter covers national victimization surveys, providing rates for the main indicators every five years from 1990 to 2015. As with every new edition of the Sourcebook, the group has tried to improve data quality as well as comparability and, where appropriate, increase the scope of data collection. For example, offence definitions were updated to reflect the lessons learned from previous editions.peer-reviewe

Erratum to: Guidelines for the use and interpretation of assays for monitoring autophagy (3rd edition) (Autophagy, 12, 1, 1-222, 10.1080/15548627.2015.1100356

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