Privacy-Friendly Mobility Analytics using Aggregate Location Data

Location data can be extremely useful to study commuting patterns and disruptions, as well as to predict real-time traffic volumes. At the same time, however, the fine-grained collection of user locations raises serious privacy concerns, as this can reveal sensitive information about the users, such as, life style, political and religious inclinations, or even identities. In this paper, we study the feasibility of crowd-sourced mobility analytics over aggregate location information: users periodically report their location, using a privacy-preserving aggregation protocol, so that the server can only recover aggregates -- i.e., how many, but not which, users are in a region at a given time. We experiment with real-world mobility datasets obtained from the Transport For London authority and the San Francisco Cabs network, and present a novel methodology based on time series modeling that is geared to forecast traffic volumes in regions of interest and to detect mobility anomalies in them. In the presence of anomalies, we also make enhanced traffic volume predictions by feeding our model with additional information from correlated regions. Finally, we present and evaluate a mobile app prototype, called Mobility Data Donors (MDD), in terms of computation, communication, and energy overhead, demonstrating the real-world deployability of our techniques.Comment: Published at ACM SIGSPATIAL 201

Synthetic considerations in the self-assembly of coordination polymers of pyridine-functionalised hybrid Mn-Anderson polyoxometalates

The incorporation of polyoxometalates (POMs) as structural units into ordered porous constructs such as metal-organic frameworks (MOFs) is desirable for a range of applications where intrinsic properties inherited from both the MOF and POM are utilised, including catalysis and magnetic data storage. The controlled self-assembly of targeted MOF topologies containing POM units is hampered by the wide range of oxo and hydroxo units on the peripheries of POMs that can act as coordinating groups towards linking metal cations leading to a diverse range of structures, but incorporation of organic donor units into hybrid POMs offers an alternative methodology to programmably synthesise POM/MOF conjugates. Herein, we report six coordination polymers obtained serendipitously wherein Zn2+ and Cu2+ link pyridine-appended Mn-Anderson clusters into two- and three-dimensional network solids with complex connectivities and topologies. Careful inspection of their solid-state structures has allowed us to identify common structure-directing features across these coordination polymers, including a square motif where two Zn2+ cations bridge two POMs. By correlating certain structural motifs with synthetic conditions we have formulated a series of design considerations for the self-assembly of coordination polymers of hybrid POMs, encompassing the selection of reaction conditions, co-ligands and linking metal cations. We anticipate that these synthetic guidelines will inform the future assembly of hybrid POMs into functional MOF materials

On the apparent absence of broad iron lines in Seyfert galaxies

We present an analysis of XMM-Newton observations of eleven Seyfert galaxies that appear to be missing a broad iron K alpha line. These objects represent a challenge to the established paradigm for active galactic nuclei, where a relatively cold accretion disc feeds the central black hole. In that paradigm, X-ray illumination of the accretion disc should lead to continuum and fluorescence emission from iron which is broadened and shifted by relativistic effects close the hole. We extend the work of Nandra et al. (2007), who found no evidence for such a component in an earlier analysis of these objects, by testing a variety of more complex relativistic reflection models. Specifically, we consider the possibility that the disc is highly ionised, and/or that the the reflection is heavily blurred by strong relativistic effects in a Kerr geometry. We find that in 8/11 of the observations with no apparent broad iron line, the fit is significantly improved when an ionised or strongly blurred reflector is included, and that all 11 observations allow for such a component. The disc inclinations are found generally to be around 60 degrees, which when combined with a steep emissivity profile results in strong relativistic blurring of the reflection, rendering the K alpha line difficult to distinguish from the underlying continuum. Nevertheless, relativistic reflection does appear to be present, and the strength of the smeared reflection is similar to that expected from a flat disc illuminated by a point source. Such blurred reflection and the associated steep radial emissivity profiles are consistent with the gravitational light bending of the continuum photons close to the black hole.Comment: 9 pages, 2 figures. Accepted for publication in MNRA

Designing materials for electrochemical carbon dioxide recycling

Electrochemical carbon dioxide recycling provides an attractive approach to synthesizing fuels and chemical feedstocks using renewable energy. On the path to deploying this technology, basic and applied scientific hurdles remain. Integrating catalytic design with mechanistic understanding yields scientific insights and progresses the technology towards industrial relevance. Catalysts must be able to generate valuable carbon-based products with better selectivity, lower overpotentials and improved current densities with extended operation. Here, we describe progress and identify mechanistic questions and performance metrics for catalysts that can enable carbon-neutral renewable energy storage and utilization

A Synthesis of the CSLS Provincial Productivity Reports, 1997-2007

This report, based on the CSLS Provincial Productivity Database, provides a portrait of the productivity performance of the ten Canadian provinces over the 1997-2007 period. Level and growth rate estimates of labour and multifactor productivity are presented and discussed, with an emphasis on the provinces’ market sector. Two-digit NAICS industry level estimates are also presented. Capitalintensity and labour quality figures are also provided, and a standard growth accounting framework is used to determine the sources of labour productivity growth, as well as the sources of labour productivity level gaps between Canada and the provinces.labour productivity, multifactor productivity, capital intensity, labour quality, Canadian provinces, growth accounting

Rearrangement of {α-P2W15} to {PW6} moieties during the assembly of transition-metal-linked polyoxometalate clusters

We report the formation of two polyoxotungstates of the general formula [M6(PW6O26)(α-P2W15O56)2(H2O)2]23− (M = CoII or MnII), which contain {PW6} fragments generated from the [P2W15O56]12− precursor, which demonstrates for the first time the transformation of a Dawson lacunae into a Keggin lacunary building block. Solution analysis of the clusters has been conducted via electrospray ionisation mass spectrometry