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The effect of a new drag-law parameterization on ice shelf water plume dynamics
A drag law accounting for Ekman rotation adjacent to a flat, horizontal bou
ndary is proposed for use in
a plume model that is written in terms of the depth-mean velocity. The drag l
aw contains a variable turning
angle between the mean velocity and the drag imposed by the turbulent bound
ary layer. The effect of the
variable turning angle in the drag law is studied for a plume of ice shelf wat
er (ISW) ascending and turning
beneath an Antarctic ice shelf with draft decreasing away from the groundi
ng line. As the ISW plume
ascends the sloping ice shelf–ocean boundary, it can melt the ice shelf, wh
ich alters the buoyancy forcing
driving the plume motion. Under these conditions, the typical turning ang
le is of order
10° over most of
the plume area for a range of drag coefficients (the minus sign arises for th
e Southern Hemisphere). The
rotation of the drag with respect to the mean velocity is found to be signifi
cant if the drag coefficient exceeds
0.003; in this case the plume body propagates farther along and across the b
ase of the ice shelf than a plume
with the standard quadratic drag law with no turning angle
Efficient Red Organic Light Emitting Diodes of Nona Coordinate Europium Tris(β-diketonato) Complexes Bearing 4'-Phenyl-2,2':6',2''- terpyridine
Two novel nona-coordinated Eu(III) complexes [Eu(btfa) 3(Ph-TerPyr)] (Eu-1) and [Eu(NTA) 3(Ph-TerPyr)] (Eu-2) have been synthesized and characterized. The structure of the complexes was elucidated by density functional theory (DFT) methods. The experimental photophysical properties of the complexes were investigated and complemented with theoretical calculations. Effective energy transfer (ET) pathways for the sensitized red luminescence is discussed. The complexes were tested as emitting layers (EML) in organic light emitting diodes (OLEDs). At the optimum doping concentration of 4 wt.%, the double-EML OLEDs of Eu-1 exhibited red electroluminescence (EL) with an EQE of 4.0 % and maximum brightness (B)=1179 cd/m 2, maximum current efficiency (η c)=5.64 cd/A, and maximum power efficiency (η p)=4.78 lm/W at the current density (J) of 10 mA/cm 2. Interestingly, the double-EML OLEDs of Eu-2 at the optimum concentration of 3 wt.%, displayed an outstanding EL performance with EQE of 7.32 % and B=838 cd/m 2, η c=10.19 cd/A and η p=10.33 lm/W at J=10 mA/cm 2. The EL performance of this device is among the best reported for devices incorporating a europium complex as a red emitter.</p
Efficient Red Organic Light Emitting Diodes of Nona Coordinate Europium Tris(β-diketonato) Complexes Bearing 4'-Phenyl-2,2':6',2''- terpyridine
Two novel nona-coordinated Eu(III) complexes [Eu(btfa) 3(Ph-TerPyr)] (Eu-1) and [Eu(NTA) 3(Ph-TerPyr)] (Eu-2) have been synthesized and characterized. The structure of the complexes was elucidated by density functional theory (DFT) methods. The experimental photophysical properties of the complexes were investigated and complemented with theoretical calculations. Effective energy transfer (ET) pathways for the sensitized red luminescence is discussed. The complexes were tested as emitting layers (EML) in organic light emitting diodes (OLEDs). At the optimum doping concentration of 4 wt.%, the double-EML OLEDs of Eu-1 exhibited red electroluminescence (EL) with an EQE of 4.0 % and maximum brightness (B)=1179 cd/m 2, maximum current efficiency (η c)=5.64 cd/A, and maximum power efficiency (η p)=4.78 lm/W at the current density (J) of 10 mA/cm 2. Interestingly, the double-EML OLEDs of Eu-2 at the optimum concentration of 3 wt.%, displayed an outstanding EL performance with EQE of 7.32 % and B=838 cd/m 2, η c=10.19 cd/A and η p=10.33 lm/W at J=10 mA/cm 2. The EL performance of this device is among the best reported for devices incorporating a europium complex as a red emitter.</p
A Tris β-Diketonate Europium(III) Complex Based OLED Fabricated by Thermal Evaporation Method Displaying Efficient Bright Red Emission
202209 bcwwNot applicableRGCOthersHis Majesty’s Trust Fund for Strategic Research; Brazilian funding agencies: CAPES, CNPq,FACEPE and FAPITEC/SE; Guangdong-Hong Kong-Macao Joint Laboratory of Optoelectronic and Magnetic Functional Materials; Hong Kong Polytechnic University; Endowed Professorship in Energy from Ms Clarea Au; NSFC; outh Innovation Promotion Association of Chinese Academy of Sciences; Engineering and Physical Sciences Research Council (EPSRC)Published24 month
Coherent Manipulation of Quantum Delta-kicked Dynamics: Faster-than-classical Anomalous Diffusion
Large transporting regular islands are found in the classical phase space of
a modified kicked rotor system in which the kicking potential is reversed after
every two kicks. The corresponding quantum system, for a variety of system
parameters and over long time scales, is shown to display energy absorption
that is significantly faster than that associated with the underlying classical
anomalous diffusion. The results are of interest to both areas of quantum chaos
and quantum control.Comment: 6 pages, 4 figures, to appear in Physical Review
A window into the future? MRI for evaluation of neuromyelitis optica spectrum disorder throughout the disease course
Neuromyelitis optica spectrum disorder (NMOSD) is a relapsing, inflammatory disease of the central nervous system marked by relapses often associated with poor recovery and long-term disability. Magnetic resonance imaging (MRI) is recognized as an important tool for timely diagnosis of NMOSD as, in combination with serologic testing, it aids in distinguishing NMOSD from possible mimics. Although the role of MRI for disease monitoring after diagnosis is not as well established, MRI may provide important prognostic information and help differentiate between relapses and pseudorelapses. Increasing evidence of subclinical disease activity and the emergence of newly approved, highly effective immunotherapies for NMOSD adjure us to re-evaluate MRI as a tool to guide optimal treatment selection and escalation throughout the disease course. In this article we review the role of MRI in NMOSD diagnosis, prognostication, disease monitoring, and treatment selection
A note on the penetration of a rigid wedge into a nonisotropic brittle material
In the present note an existing wedge penetration theory for isotropic brittle materials is extended to explain some `bedding plane' effects observed in a series of experiments on Indiana limestone.The general features of the theory presented by Paul and Sikarskie [Trans. AIME 232, 372-383 (1965)] are kept here and in order to extend the analysis to the anisotropic case Jaeger's modification of the Coulomb-Mohr failure criteria is used.Two specific cases of bedding plane orientation are considered, namely those in which the bedding planes are parallel and perpendicular to the direction of penetration.The theory presented gives an insight into the anisotropic effects and predicts, in reasonable agreement with the experimental results, the observed differences in specific energies for the different penetration directions.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/32941/1/0000324.pd
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