6,098 research outputs found
MasterChem: Cooking 2D-polymers
2D-polymers are still dominated by graphene and closely related materials such as boron nitride, transition metal sulphides and oxides. However, the rational combination of molecules with suitable design is already showing the high potential of chemistry in this new research field. The aim of this feature article is to illustrate, and provide some perspectives, the current state-of-the-art in the field of synthetic 2D-polymers showing different alternatives to prepare this novel type of polymers based on the rational use of chemistry. This review comprises a brief revision of the essential concepts, the strategies of preparation following the two general approaches, bottom-up and top-down, and a revision of the promising seminal properties showed by some of these nanomaterials.Financial support from Spanish MINECO (MAT2013-46753-C2-1-P and MAT2013-46502-C2-2-P). D. R. thanks the Spanish MECD for a FPU gran
Circumstellar effects on the Rb abundances in O-rich AGB stars
For the first time we explore the circumstellar effects on the Rb (and Zr)
abundance determination in O-rich asymptotic giant branch (AGB) stars by
considering the presence of a gaseous circumstellar envelope with a radial
wind. A modified version of the spectral synthesis code Turbospectrum was used
to deal with extended atmosphere models and velocity fields. The Rb and Zr
abundances were determined from the resonant 7800A Rb I line and the 6474A ZrO
bandhead, respectively, in five representative O-rich AGB stars with different
expansion velocity and metallicity. By using our new dynamical models, the Rb I
line profile (photospheric and circumstellar components) is very well
reproduced. Interestingly, the derived Rb abundances are much lower (by 1-2
dex) in those O-rich AGB stars showing the higher circumstellar expansion
velocities. The Zr abundances, however, remain close to the solar values. The
Rb abundances and Rb/Zr ratios derived here significantly alleviate the problem
of the present mismatch between the observations of intermediate-mass (4-8
solar masses) Rb-rich AGB stars and the AGB nucleosynthesis theoretical
predictions.Comment: Accepted for publication in Astronomy & Astrophysics Letters (7
pages, 5 figures, and 2 tables); final version (language corrected
Population Ecology and Reproductive Biology of The Diamondback Watersnake, Nerodia Rhombifer (Serpentes: Colubridae), in Southernmost Texas
Nerodia rhombifer is a polytypic, semi-aquatic snake with a broad geographical distribution ranging from the American Midwest southward to Chiapas, Mexico. Although relatively abundant throughout much of its range, few ecological studies of the species have been conducted. This study provides basic population ecology information in a subtropical habitat. Population data were obtained in a mark-recapture study at Santa Ana National Wildlife Refuge, Hidalgo County, Texas, from August 1995 to December 1998. Specimens taken elsewhere in Hidalgo County provided information on the reproductive biology. This study provides the first absolute density estimates from anywhere within the species’ range. Quantitative information on seasonal activity, growth rates, size dimorphism, population structure, reproductive cycles, and lipid dynamics are presented
A first order Tsallis theory
We investigate first-order approximations to both i) Tsallis' entropy
and ii) the -MaxEnt solution (called q-exponential functions ). It is
shown that the functions arising from the procedure ii) are the MaxEnt
solutions to the entropy emerging from i). The present treatment is free of the
poles that, for classic quadratic Hamiltonians, appear in Tsallis' approach, as
demonstrated in [Europhysics Letters {\bf 104}, (2013), 60003]. Additionally,
we show that our treatment is compatible with extant date on the ozone layer.Comment: 4 figures adde
A GIT interpretration of the Harder-Narasimhan filtration
An unstable torsion free sheaf on a smooth projective variety gives a GIT
unstable point in certain Quot scheme. To a GIT unstable point, Kempf
associates a "maximally destabilizing" 1-parameter subgroup, and this induces a
filtration of the torsion free sheaf. We show that this filtration coincides
with the Harder-Narasimhan filtration.Comment: 19 pages; Comments of the referees and references added. The
construction for holomorphic pairs (Sections 6 and 7 from previous version)
will appear in a further publication. To appear in Rev. Mat Complutens
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