Fly ash-derived MCM-41 as a low-cost silica support for polyethyleneimine in post-combustion CO2 capture

The mesoporous silicate molecular sieve, MCM-41, has been synthesized from pulverized coal fly ash (PFA), where the silicate filtrate used is a by-product from hydrothermal zeolite production. Rice husk ash was also used for comparison but fusion with sodium hydroxide was used to prepare the silicate filtrate, along similar lines to earlier reports of using PFA as a precursor for MCM-41 synthesis. The MCM-41 samples are chemically and mineralogically similar to a commercially available sample, but with higher pore volumes dominated by mesopores (0.92–1.13 cf. 0.88 cm3 g−1). After polyethyleneimine (PEI) impregnation for CO2 capture, the ash derived MCM-41 samples displayed higher uptakes than the commercial sample with the maximum achievable PEI loading of 60 Wt.% PEI (dry basis) before particle agglomeration occurs, approximately 13 compared to 11 Wt.%, respectively, the latter being comparable to earlier reports in the literature. The PFA sample that displays the fastest kinetics to achieve 90% of the equilibrium uptake had the largest mesopore volume of 1.13 cm3 g−1. Given the PFA-derived MCM-41 uses a waste silicate solution for hydrothermal preparation and no prior preparation is needed, production costs are estimated to be considerable lower where silicate solutions need to be prepared by base treatment, even if ash is used, as for the RHA derived MCM-41 used here

Inflationary Cosmological Perturbations of Quantum-Mechanical Origin

This review article aims at presenting the theory of inflation. We first describe the background spacetime behavior during the slow-roll phase and analyze how inflation ends and the Universe reheats. Then, we present the theory of cosmological perturbations with special emphasis on their behavior during inflation. In particular, we discuss the quantum-mechanical nature of the fluctuations and show how the uncertainty principle fixes the amplitude of the perturbations. In a next step, we calculate the inflationary power spectra in the slow-roll approximation and compare these theoretical predictions to the recent high accuracy measurements of the Cosmic Microwave Background radiation (CMBR) anisotropy. We show how these data already constrain the underlying inflationary high energy physics. Finally, we conclude with some speculations about the trans-Planckian problem, arguing that this issue could allow us to open a window on physical phenomena which have never been probed so far.Comment: Review Article, 47 pages, 3 figures. Lectures given at the 40th Karpacz Winter School on Theoretical Physics (Poland, Feb. 2004), submitted to Lecture Notes in Physic

Generating G2G_2--cosmologies with perfect fluid in dilaton gravity

We present a method for generating exact diagonal $G_2$-cosmological solutions in dilaton gravity coupled to a radiation perfect fluid and with a cosmological potential of a special type. The method is based on the symmetry group of the system of $G_2$-field equations. Several new classes of explicit exact inhomogeneous perfect fluid scalar-tensor cosmologies are presented.Comment: 10 pages, LaTe

The No-defect Conjecture: Cosmological Implications

When the topology of the universe is non trivial, it has been shown that there are constraints on the network of domain walls, cosmic strings and monopoles. I generalize these results to textures and study the cosmological implications of such constraints. I conclude that a large class of multi-connected universes with topological defects accounting for structure formation are ruled out by observation of the cosmic microwave background.Comment: 4 pages, 1 figure, accepted for publication as a brief report in Phys. Rev.

Inflationary Perturbations: the Cosmological Schwinger Effect

This pedagogical review aims at presenting the fundamental aspects of the theory of inflationary cosmological perturbations of quantum-mechanical origin. The analogy with the well-known Schwinger effect is discussed in detail and a systematic comparison of the two physical phenomena is carried out. In particular, it is demonstrated that the two underlying formalisms differ only up to an irrelevant canonical transformation. Hence, the basic physical mechanisms at play are similar in both cases and can be reduced to the quantization of a parametric oscillator leading to particle creation due to the interaction with a classical source: pair production in vacuum is therefore equivalent to the appearance of a growing mode for the cosmological fluctuations. The only difference lies in the nature of the source: an electric field in the case of the Schwinger effect and the gravitational field in the case of inflationary perturbations. Although, in the laboratory, it is notoriously difficult to produce an electric field such that pairs extracted from the vacuum can be detected, the gravitational field in the early universe can be strong enough to lead to observable effects that ultimately reveal themselves as temperature fluctuations in the Cosmic Microwave Background. Finally, the question of how quantum cosmological perturbations can be considered as classical is discussed at the end of the article.Comment: 49 pages, 6 figures, to appear in a LNP volume "Inflationary Cosmology

A covariant and gauge-invariant analysis of cosmic microwave background anisotropies from scalar perturbations

We present a new, fully covariant and manifestly gauge-invariant expression for the temperature anisotropy in the cosmic microwave background radiation resulting from scalar perturbations. We pay particular attention to gauge issues such as the definition of the temperature perturbation and the placing of the last scattering surface. In the instantaneous recombination approximation, the expression may be integrated up to a Rees-Sciama term for arbitrary matter descriptions in flat, open and closed universes. We discuss the interpretation of our result in the baryon-dominated limit using numerical solutions for conditions on the last scattering surface, and confirm that for adiabatic perturbations the dominant contribution to the anisotropy on intermediate scales (the location of the Doppler peaks) may be understood in terms of the spatial inhomogeneity of the radiation temperature in the baryon rest frame. Finally, we show how this term enters the usual Sachs-Wolfe type calculations (it is rarely seen in such analyses) when subtle gauge effects at the last scattering surface are treated correctly.Comment: 20 pages, 2 Postscript figure

Population Dynamics and Angler Exploitation of the Unique Muskellunge Population in Shoepack Lake, Voyageurs National Park, Minnesota

A unique population of muskellunge Esox masquinongy inhabits Shoepack Lake in Voyageurs National Park, Minnesota. Little is known about its status, dynamics, and angler exploitation, and there is concern for the long-term viability of this population. We used intensive sampling and mark–recapture methods to quantify abundance, survival, growth, condition, age at maturity and fecundity and angler surveys to quantify angler pressure, catch rates, and exploitation. During our study, heavy rain washed out a dam constructed by beavers Castor canadensis which regulates the water level at the lake outlet, resulting in a nearly 50% reduction in surface area. We estimated a population size of 1,120 adult fish at the beginning of the study. No immediate reduction in population size was detected in response to the loss of lake area, although there was a gradual, but significant, decline in population size over the 2-year study. Adults grew less than 50 mm per year, and relative weight (W r) averaged roughly 80. Anglers were successful in catching, on average, two fish during a full day of angling, but harvest was negligible. Shoepack Lake muskellunge exhibit much slower growth rates and lower condition, but much higher densities and angler catch per unit effort (CPUE), than other muskellunge populations. The unique nature, limited distribution, and location of this population in a national park require special consideration for management. The results of this study provide the basis for assessing the long-term viability of the Shoepack Lake muskellunge population through simulations of long-term population dynamics and genetically effective population size

HST/STIS spectroscopy of the exposed white dwarf in the short-period dwarf nova EK TrA

We present high resolution Hubble Space Telescope ultraviolet spectroscopy of the dwarf nova EK TrA obtained in deep quiescence. The Space Telescope Imaging Spectrograph data reveal the broad Ly-alpha absorption profile typical of a moderately cool white dwarf, overlayed by numerous broad emission lines of He, C, N, and Si and by a number of narrow absorption lines, mainly of CI and SiII. Assuming a white dwarf mass in the range 0.3-1.4Msun we derive Teff=17500-23400K for the primary in EK TrA; Teff=18800K for a canonical mass of 0.6Msun. From the narrow photospheric absorption lines, we measure the white dwarf rotational velocity, v*sin i=200+-100kms. Even though the strong contamination of the photospheric white dwarf absorption spectrum by the emission lines prevents a detailed quantitative analysis of the chemical abundances of the atmosphere, the available data suggest slightly sub-solar abundances. The high time resolution of the STIS data allows us to associate the observed ultraviolet flickering with the emission lines, possibly originating in a hot optically thin corona above the cold accretion disk.Comment: 6 pages A&A-Latex, 5 Figures, accepted for publication in A&

The role of functional single nucleotide polymorphisms of the human glucocorticoid receptor gene NR3C1 in Polish patients with bronchial asthma

N363S and ER22/23EK polymorphisms observed within glucocorticoid receptor gene (NR3C1) may play an important role in the development of bronchial asthma. NR3C1 gene is associated with an altered sensitivity to GCs. The aim of the research project was to study the correlation between this NR3C1 gene polymorphisms and occurrence of asthma in the population of Polish asthmatics. Peripheral blood was obtained from 207 healthy volunteers and 221 asthma patients. Genotyping was carried out with PCR-RFLP method. In the groups of patients with uncontrolled moderate asthma and uncontrolled severe disease, the genotype distribution for the investigated polymorphisms was as follows: N363S-AA, AG, GG occurring with 0.881/0.073/0.046 frequency and ER22/23EK-GG, GA, AA occurring with 0.963/0.037/0.000 frequency. Chi-square analysis revealed a significantly different (P < 0.05) distribution between cases and controls for the N363S polymorphisms. The N363S polymorphism of NR3C1 gene is significantly associated with bronchial asthma, susceptibility to the development of moderate to severe form of uncontrolled bronchial asthma