The influence of alkalinity of portland cement on the absorption characteristics of superabsorbent polymers (SAP) for use in internally cured concrete

The concrete industry increasingly emphasizes advances in novel materials that promote construction of more resilient infrastructure. Due to its potential to improve concrete durability, internal curing (IC) of concrete by means of superabsorbent polymers (SAP) has been identified as one of the most promising technologies of the 21st century. The addition of superabsorbent polymers into a cementitious system promotes further hydration of cement by providing internal moisture during the hardening and strength development periods, and thus limits self-desiccation, shrinkage, and cracking. This thesis presents the work performed on the series of cement pastes with varying alkalinity of their pore solutions to provide a better understanding of: (1) the influence of the chemistry of the pore solution (i.e. its level of alkalinity and the type of ionic species present) on the absorption capacity of SAP, and (2) the effectiveness of SAP with different absorption capacities as an internal curing agent. This research work was divided into three stages: (a) materials characterization, (b) measurement of absorption capacity of SAP in synthetic pore solutions, and (c) evaluation of the internal curing effectiveness of SAP. During the first stage (Materials Characterization), pore solutions were extracted from the fresh (5 minutes old) cement pastes prepared using cements with three different levels of alkalinity. The pH values of the extracted solutions were determined (using the pH meter) and their chemical analysis was performed by means of titration (concentration of hydroxyl), ion chromatography (sulfates and chlorides), atomic absorption (AA) and inductively coupled plasma optical emission spectrometry (ICP) (sodium, potassium and calcium). The commercial SAP adopted for this study was used with “as-supplied” gradation and with the finer gradation obtained by grinding the original polymer in the 6850 Cryomilling Freezer/Mill. The physical properties of these SAP’s, such as the shape and size of the particles, were determined by optical microscopy combined with image analysis. The second stage, the absorption capacity of SAP’s, involved determination of the swelling behavior and the absorption capacity of polymers exposed to artificial pore solutions with different levels of alkalinity. The swelling behavior was followed using the optical microscope while the absorption capacity was characterized using the tea bag method. It was found that changes in the chemical compositions of the pore solutions influence the adsorption kinetics and result in different absorption isotherms. In the third stage, the internal curing effects of inclusion of SAP in cement pastes were evaluated. Mixture proportions of pastes used in this stage of the study were selected based on the absorption capacity of the SAP determined in stage two. The testing of the pastes involved determination of their set times, heat of hydration, and autogenous shrinkage

Comment on ``Theory of Spinodal Decomposition''

I comment on a paper by S. B. Goryachev [PRL vol 72, p.1850 (1994)] that presents a theory of non-equilibrium dynamics for scalar systems quenched into an ordered phase. Goryachev incorrectly applies only a global conservation constraint to systems with local conservation laws.Comment: 2 pages LATeX (REVTeX macros), no figures. REVISIONS --- more to the point. microscopic example added, presentation streamlined, long-range interactions mentioned, to be published in Phys. Rev. Let

Non-equilibrium Phase-Ordering with a Global Conservation Law

In all dimensions, infinite-range Kawasaki spin exchange in a quenched Ising model leads to an asymptotic length-scale $L \sim (\rho t)^{1/2} \sim t^{1/3}$ at $T=0$ because the kinetic coefficient is renormalized by the broken-bond density, $\rho \sim L^{-1}$. For $T>0$, activated kinetics recovers the standard asymptotic growth-law, $L \sim t^{1/2}$. However, at all temperatures, infinite-range energy-transport is allowed by the spin-exchange dynamics. A better implementation of global conservation, the microcanonical Creutz algorithm, is well behaved and exhibits the standard non-conserved growth law, $L \sim t^{1/2}$, at all temperatures.Comment: 2 pages and 2 figures, uses epsf.st

Numerical Simulation of Nano Scanning in Intermittent-Contact Mode AFM under Q control

We investigate nano scanning in tapping mode atomic force microscopy (AFM) under quality (Q) control via numerical simulations performed in SIMULINK. We focus on the simulation of whole scan process rather than the simulation of cantilever dynamics and the force interactions between the probe tip and the surface alone, as in most of the earlier numerical studies. This enables us to quantify the scan performance under Q control for different scan settings. Using the numerical simulations, we first investigate the effect of elastic modulus of sample (relative to the substrate surface) and probe stiffness on the scan results. Our numerical simulations show that scanning in attractive regime using soft cantilevers with high Qeff results in a better image quality. We, then demonstrate the trade-off in setting the effective Q factor (Qeff) of the probe in Q control: low values of Qeff cause an increase in tapping forces while higher ones limit the maximum achievable scan speed due to the slow response of the cantilever to the rapid changes in surface profile. Finally, we show that it is possible to achieve higher scan speeds without causing an increase in the tapping forces using adaptive Q control (AQC), in which the Q factor of the probe is changed instantaneously depending on the magnitude of the error signal in oscillation amplitude. The scan performance of AQC is quantitatively compared to that of standard Q control using iso-error curves obtained from numerical simulations first and then the results are validated through scan experiments performed using a physical set-up