Electrocatalysis of fuel cell reactions: Investigation of alternate electrolytes

Oxygen reduction and transport properties of the electrolyte in the phosphoric acid fuel cell are studied. The areas covered were: (1) development of a theoretical expression for the rotating ring disk electrode technique; (2) determination of the intermediate reaction rate constants for oxygen reduction on platinum in phosphoric acid electrolyte; (3) determination of oxygen reduction mechanism in trifluoreomethanesulfonic acid (TFMSA) which was considered as an alternate electrolyte for the acid fuel cells; and (4) the measurement of transport properties of the phosphoric acid electrolyte at high concentrations and temperatures

Electrocatalysis of fuel cell reactions: Investigation of alternate electrolytes

Oxygen reduction and transport properties of the electrolyte in the phosphoric acid fuel cell are studied. A theoretical expression for the rotating ring-disk electrode technique; the intermediate reaction rate constants for oxygen reduction on platinum in phosphoric acid electrolyte; oxygen reduction mechanism in trifluoromethanesulfonic acid (TFMSA), considered as an alternate electrolyte for the acid fuel cells; and transport properties of the phosphoric acid electrolyte at high concentrations and temperatures are covered

Remote sensing of precipitable water over the oceans from Nimbus-7 microwave measurements

Global maps of precipitable water over derived from scanning multichannel microwave radiometer (SMMR) data reveal salient features associated with ocean currents and the large scale general circulation in the atmosphere. Nimbus-7 SMMR brightness temperature measurements in the 21 and 18 GHz channels are used to sense the precipitable water in the atmospheric over oceans. The difference in the brightness temperature (T sub 21 -T sub 18), both in the horizontal and vertical polarization, is found to be essentially a function of the precipitable water in the atmosphere. An equation, based on the physical consideration of the radiative transfer in the microwave region, is developed to relate the precipitable water to (T sub 21 - T sub 18). It shows that the signal (T sub 21- T sub 18) does not suffer severely from the noise introduced by variations in the sea surface temperature, surface winds, and liquid water content in non rain clouds. The rms deviation between the estimated precipitable water from SMMR data and that given by the closely coincident ship radiosondes is about 0.25 g/ sq c

Spin correlations and velocity-scaling in color-octet NRQCD matrix elements

We compute spin-dependent decay matrix elements for S-wave charmonium and bottomonium in lattice nonrelativistic quantum chromodynamics (NRQCD). Particular emphasis is placed upon the color-octet matrix elements, since the corresponding production matrix elements are expected to appear in the dominant contributions to the production cross sections at large transverse momenta. We use three slightly different versions of the heavy-quark lattice Green's functions in order to minimize the contributions that scale as powers of the ultraviolet cutoff. The lattice matrix elements that we calculate obey the hierarchy that is suggested by the velocity-scaling rules of NRQCD.Comment: 25 pages, 2 figures, 2 tables, further discussion of effective lattice cutoffs and uncertainties, additional minor revisions, version to be published in Phys. Rev.

Experimental and theoretical investigation for the suppression of the plasma arc drop in the thermionic converter

Ion generation and recombination mechanisms in the cesium plasma as they pertain to the advanced mode thermionic energy converter were studied. The decay of highly ionized cesium plasma was studied in the near afterglow to examine the recombination processes. Very low recombination in such a plasma may prove to be of considerable importance in practical converters. The approaches of external cesium generation were vibrationally excited nitrogen as an energy source of ionization of cesium ion, and microwave power as a means of resonant sustenance of the cesium plasma. Experimental data obtained so far show that all three techniques - i.e., the non-LTE high-voltage pulsing, the energy transfer from vibrationally excited diatomic gases, and the external pumping with a microwave resonant cavity - can produce plasmas with their densities significantly higher than the Richardson density. The implication of these findings as related to Lam's theory is discussed

Kinetics of natural aging in Al-Mg-Si alloys studied by positron annihilation lifetime spectroscopy

The process of natural aging in pure ternary Al-Mg-Si alloys was studied by positron annihilation lifetime spectroscopy in real time in order to clarify the sequence and kinetics of clustering and precipitation. It was found that natural aging takes place in at least five stages in these alloys, four of which were directly observed. This is interpreted as the result of complex interactions between vacancies and solute atoms or clusters. One of the early stages of positron lifetime evolution coincides with a clustering process observed by differential scanning calorimetry (DSC) and involves the formation of a positron trap with \sim 0.200 ns lifetime. In later stages, a positron trap with a higher lifetime develops in coincidence with the DSC signal of a second clustering reaction. Mg governs both the kinetics and the lifetime change in this stage. Within the first 10 min after quenching, a period of nearly constant positron lifetime was found for those Mg-rich alloys that later show an insufficient hardness response to artificial aging, the so-called "negative effect." The various processes observed could be described by two effective activation energies that were found by varying the aging temperature from 10 to 37\degree C.Comment: arXiv admin note: same as v2, to correct mistaken v

Stable periodic waves in coupled Kuramoto-Sivashinsky - Korteweg-de Vries equations

Periodic waves are investigated in a system composed of a Kuramoto-Sivashinsky - Korteweg-de Vries (KS-KdV) equation, which is linearly coupled to an extra linear dissipative equation. The model describes, e.g., a two-layer liquid film flowing down an inclined plane. It has been recently shown that the system supports stable solitary pulses. We demonstrate that a perturbation analysis, based on the balance equation for the field momentum, predicts the existence of stable cnoidal waves (CnWs) in the same system. It is found that the mean value U of the wave field u in the main subsystem, but not the mean value of the extra field, affects the stability of the periodic waves. Three different areas can be distinguished inside the stability region in the parameter plane (L,U), where L is the wave's period. In these areas, stable are, respectively, CnWs with positive velocity, constant solutions, and CnWs with negative velocity. Multistability, i.e., the coexistence of several attractors, including the waves with several maxima per period, appears at large value of L. The analytical predictions are completely confirmed by direct simulations. Stable waves are also found numerically in the limit of vanishing dispersion, when the KS-KdV equation goes over into the KS one.Comment: a latex text file and 16 eps files with figures. Journal of the Physical Society of Japan, in pres

Studies in the use of cloud type statistics in mission simulation

A study to further improve NASA's global cloud statistics for mission simulation is reported. Regional homogeneity in cloud types was examined; most of the original region boundaries defined for cloud cover amount in previous studies were supported by the statistics on cloud types and the number of cloud layers. Conditionality in cloud statistics was also examined with special emphasis on temporal and spatial dependencies, and cloud type interdependence. Temporal conditionality was found up to 12 hours, and spatial conditionality up to 200 miles; the diurnal cycle in convective cloudiness was clearly evident. As expected, the joint occurrence of different cloud types reflected the dynamic processes which form the clouds. Other phases of the study improved the cloud type statistics for several region and proposed a mission simulation scheme combining the 4-dimensional atmospheric model, sponsored by MSFC, with the global cloud model