Modelling the atomic structure of very high-density amorphous ice

The structure of very high-density amorphous (VHDA) ice has been modelled by positionally disordering three crystalline phases, namely ice IV, VI and XII. These phases were chosen because only they are stable or metastable in the region of the ice phase diagram where VHDA ice is formed, and their densities are comparable to that of VHDA ice. An excellent fit to the medium range of the experimentally observed pair-correlation function g(r) of VHDA ice was obtained by introducing disorder into the positions of the H2O molecules, as well as small amounts of molecular rotational disorder, disorder in the O--H bond lengths and disorder in the H--O--H bond angles. The low-k behaviour of the experimental structure factor, S(k), is also very well reproduced by this disordered-crystal model. The fraction of each phase present in the best-fit disordered model is very close to that observed in the probable crystallization products of VHDA ice. In particular, only negligible amounts of ice IV are predicted, in accordance with experimental observation.Comment: 4 pages, 3 figures, 1 table, v2: changes made in response to referees' comments, the justification for using certain ice phases is improved, and ice IV is now disordered as wel

What factors influence healthcare professionals to refer children and families to paediatric psychology?

Objectives: This study aimed to investigate factors influencing referral of children with physical illness to paediatric psychology. Due to high rates of mental health problems within this population, studies have shown that referral to paediatric psychology should be increased. However, few studies have examined factors shaping healthcare professionals’ referral behaviour. Methods: The current study used the theory of planned behaviour to develop a questionnaire which explores factors influencing the referral of children and families to paediatric psychology. Psychometric properties of the questionnaire were examined. Results: The questionnaire was found to have good reliability and validity. The main constructs of the theory of planned behaviour were useful in predicting intention to refer to paediatric psychology. Specific beliefs about referral were shown to influence intention to refer. Conclusions: Findings suggest that individual attitudes and beliefs can impact healthcare professionals’ referral behaviour, indicating that multidisciplinary interventions and inter-professional education relating to the psychological aspects of illness are required

Development and Validation of a Daily Habit Scale

Habits are defined as automatic behaviours triggered by cues and performed without awareness. They are difficult to control and mentally efficient, which contrasts with goal-directed behaviour, which is characterised by active thought, high computational effort, and the ability to modify this behaviour in response to a changing environment and contextual demands. Habits are not only defined by the frequency with which a behaviour is performed but represent a complex construct that also includes the strength and automaticity of the habitual behaviour. We report here the development and validation of a Daily Habit Scale (DHS) to assess the frequency, automaticity, and strength of daily habits in healthy individuals. Item reduction based on factor analysis resulted in a scale with 38 items grouped into eight factors explaining 52.91% of the variance. The DHS showed very good internal consistency (Cronbach alpha = 0.738) and test-retest reliability (Intraclass correlation coefficient = 0.892, p<0.001) as well as convergent and divergent reliability compared to other scales measuring habits. We found a significant effect of age, gender, anxiety, and depression on the DHS. Considering certain limitations of the DHS, such as not considering the context of performance of habits, and the absence of certain items, such as transportation use, the results of this study suggest that DHS is a reliable and valid measure of daily habits that can be used by both clinicians and researchers as a measure of daily habits

Transport and poverty: a review of the evidence

A report produced for the Joseph Rowntree Foundation reviewing the evidence on transport and poverty with a focus on the UK

The Impact of Squat Velocity on Force, Power, and Muscle Activity

The squat is a thoroughly examined movement pattern and commonly used in sport performance training protocols, rehabilitation programs, and recreational exercise. Previous research measuring absolute strength has shown hamstring muscle activity in a six-repetition max barbell back squats. PURPOSE: The purpose of this study is to examine the effects of varying squat velocities (25, 50, 75 deg/s) on force, power, and the activation of the quadricep and hamstring muscles. Using a single-blind randomized research design, we hypothesized that hamstring muscle activity will increase at faster squat velocities. Our secondary hypothesis is that peak power will occur at 50 deg/s and peak force will occur at 25 deg/s. Muscle activity for both the hamstring and quadriceps was measured as root mean square (RMS) electromyography (EMG) and expressed as a percentage of the maximum voluntary contraction (MVC). Muscle activity, force output, and power output were measured over five consecutive repetitions of each velocity in a randomized order. METHODS: Twelve healthy adults (10 males, 2 females) participated in this investigation. Three Delsys Trigno EMG electrodes were placed on the right leg of all participants as they performed the MVC and squat trials on the isokinetic machine. One was placed on the posterior side (biceps femoris [BF]) to measure hamstring activity and two were placed on the anterior side (vastus medialis [VM] and vastus lateralis [VL]) to measure quadricep activity. An isokinetic training machine was used to test the participant’s squat performance at pre-set velocities (Ariel Computerized Exercise System, CA). These machines have been used to measure force and power relationships. MVC was found using an adjustable bench with a padded immovable leg extension attachment. For the quadriceps, the participant sat on the bench in an upright position with the leg extended to approximately 110 degrees against the attachment. Hamstring MVC was measured in a standing position with the leg of interest flexed to approximately 110 degrees with the leg extension attachment behind the lower leg. Three trials of MVC were performed for both knee flexion and extension so results during squat trials can be expressed as a percentage of MVC. Following the MVC, participants then underwent experimental trials. The squat movement pattern was standardized to a depth of 90 degrees of knee flexion measured via goniometry and maintained during each trial using an adjustable height box, set to a predetermined height. Feet were instructed to remain at approximately shoulder width with knees tracking along the same line as the feet to avoid knee misalignment to avoid injury and potentially alter muscle activity. Five consecutive repetitions at each velocity (25, 50, and 75 deg/s) were performed with at least two minutes of rest between trials. For each trial, repetitions two, three, and four were used to determine average and peak power and force. RESULTS: To determine the magnitude of BF muscle activity, we compared it to the degree of quadricep muscle activity (VL:BF and VM:BF) for each squat velocity and analyzed using a one-way ANOVA. This relative hamstring muscle activity was highest at 75 deg/s for VL:BF at 3.84% and at 50 deg/s for VM:BF at 4.59% However, the difference in BF activity involved at each squat velocity was not statistically significant (p = 0.2973). The highest average peak power was achieved at a velocity of 50 deg/s with a value of 1538.19 ± 717.2 W. The greatest average peak force was found at a velocity of 25 deg/s with a value of 1574.08 N ± 605.8 W. When analyzing the peak force within the three velocity groups, a statistically significant difference was found with a p \u3c 0.0001. This was also seen with the average force within the three velocity groups with a p \u3c 0.0001. No statistically significant difference was found for either peak or average power among the three velocity groups. CONCLUSION: When comparing the degree of BF involved during the squat movement, the 25 deg/s had the lowest relative to the quadricep musculature, while both the 50 deg/s and 75 deg/s had higher relative BF activity. As expected, a U-trend was observed with average peak power observed at 50 deg/s, with a decrease at both 25 and 75 deg/s – further confirming the established power-velocity relationship. However, this difference was not statistically significant with our participant size. As velocity increased, force decreased – further confirming the established force-velocity relationship. These results proved to be statistically significant

Comparative Fatty Acid Composition of Eggs from White Bass Fed Live Food or Commercial Feed

We evaluated the influence of two broodstock feeding practices on fatty acid composition and viability of eggs in white bass Morone chrysops. The two dietary groups tested were (1) white bass females fed a commercially formulated feed (crude protein, 45%; crude fat, 16%) and (2) white bass females maintained on live food (fathead minnow Pimephales promelas and golden shiners Notemigonus crysoleucas). Significant differences existed between the dietary treatments in egg fatty acid levels. Eggs of white bass fed live food contained more 11-octadecenoic acid (18:1[n-7]), α-linolenic acid (18:3[n-3]), arachidonic acid (20:4[n-6]), docosahexaenoic acid (22:6[n-3]), and total n-3 fatty acids than eggs of fish fed formulated feed. Conversely, eggs of fish fed the formulated feed contained more oleic acid (18:1[n-9]), linoleic acid (18:2[n-6]), and total monoeic acids. Female white bass fed live food produced significantly more viable eggs (68.0 ± 2.0%) at 48 ± 2 h posthatch than did females fed the commercial feed (57.0 ± 2.0% [mean ± SD]). We found that the egg fatty acids of white bass are significantly affected by the diet of the female and suggest that the fatty acid composition of eggs contribute to overall reproductive success and viability of progeny. More information on the nutrient requirements of piscivorous broodstock is needed to allow feeds to be formulated to enhance the viability of eggs and fry